UNIT 1 Flashcards

(51 cards)

1
Q

Recognized that carbon is tetravalent?

A

Kekule (German Chemist) and Couper (Scottish Chemist)

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2
Q

an atom that can form four carbon bonds with other atoms?

A

Tetravalent

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3
Q

an example of tetravalent carbon?

A

Carbon Atom

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4
Q

atoms that carbon can bond with easily?

A

Hydrogen
Nitrogen
Oxygen
and carbon itself

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5
Q

main component of organic molecules?

A

Carbon Atom

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6
Q

Nature of Carbon?

A
  1. Can form linear, branched, and cyclic bonds with a wide array of organic substance.
    2.Can form a more diverse molecular structure if the carbon atom will have single, double, and triple bonds.
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7
Q

notioned that the chemical inertness of the noble gasses indicted a high degree of stability of the electron configuration of these elements (the noble gasses have completely filled valence shells)

A

Gilbert N. Lewis

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8
Q

deviced a model of bonding that unified many of the observations of chemical reactions of the elements

A

Gilbert N. Lewis

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9
Q

Happens when it acquires the complete (octet) eight electrons in the other most shell of the atom.

A

Chemical Bonding

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9
Q

Happens when it acquires the complete (octet) eight electrons in the other most shell of the atom.

A

Chemical Bonding

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10
Q

when an atom loses an electron

A

negatively charged

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11
Q

when an atom gains an electron

A

positively charged

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12
Q

when 2 atoms shares their electron

A

covalent bonds

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13
Q

when an atom gains/losses its electron through the bond

A

ionic bonds

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14
Q

If the electrons is shared equally?

A

non polar (covalent)

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15
Q

if the electrons are not shared equally?

A

Polar (covalent)

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16
Q

2 classification of organic compound?

A
  1. Hydrocarbons
  2. heteroatoms
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17
Q

containing hydrogen and carbon

A

Hydrocarbons

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18
Q

containing single binds

A

Heteroatoms

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19
Q

Composed of single binds?

A

saturated

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20
Q

composed of double or triple binds?

21
Q

2 types of hydrocarbons?

A

aliphatics
aromatics

22
Q

heteroatoms groups

A

with halogens
with oxygen
with nitrogen
with sulfur

23
Q

With halogens

A

organic halides
alkyl and aryl halides

24
With oxygen
alcohols, phenols, ethers, aldehydes and ketones, carboxylic acids, anhydrides, esters
25
With nitrogen
amines amides, amino acids
26
With sulfur
thiols, sulfides
27
what does green house methane made up?
HC
28
Types of organic reactions?
1. Addition 2. Elimination 3. Substitution 4. Rearrangement 5. Oxidation 6. Oxidation reduction
29
can be identified if there is an increase in the number of atoms or groups attached to a carbon(s) in the substrate. (A saturated compound contains single bonds only while an unsaturated compound contains double or triple bonds
Addition
30
, an atom or a group of atoms is removed from the substrate, thus there is a decrease in the number of atoms or groups attached to carbon. The substrate is transformed to a more unsaturated (single bond) product.
Elimination reaction
31
they involve the replacement of an atom or a group of atoms in the substrate by another atom or group of atoms.
Substitution
32
reactions involve migration of an atom or group of atoms from one atom to another
Rearrangement Reaction
33
reactions involve migration of an atom or group of atoms from one atom to another
oxidation and reduction reaction
34
occurs when there is an increase in the oxygen content and/or a decrease in the hydrogen content of the substrate
Oxidation Reaction
35
there is an increase in the hydrogen content and/or a decrease in the oxygen content of the substrate
Reduction Reaction
36
the step by step events by which a substrate is converted to products at a given set of conditions
Reaction mechanism
37
formed in a one step and then consumed in the later step of reaction mechanism
Reaction intermediate
38
slowest step in the mechanism
Rate determining/limiting step
39
formed from the transformation of reactants and reagents
product
40
Can form carbon radical
Homolytic bond
41
can be trivalent, carbon anion or carbocations or can be carbon cations
Heterolytic
42
2 classification of reactant?
substrate and reagents
43
used in an chemical reactions?
reagents
44
loves electrons. attack positively charged atoms or low electron density
Nucleophilic (nucleus loving)
45
electron deficient. capable of forming new bonds by accepting a pair of electrons attacks negatively charged electrons or high electron density
Electrophilic
46
have odd number of electrons react easily and attack high electron density atoms
Radical like
47
2 types of reactants
48
3 types of reagents
nucleophile, electrophile, radical
49
either carbocation or carbanion
heterolytic cleavage
50
can form charged carbon intermediate known as radical
homolytic cleavage