unit 1 Flashcards

(89 cards)

1
Q

hcooh iupac name

A

methanoic acid

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2
Q

ch3cooh ethanoic acid common name

A

acetic acid

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3
Q

ch3(ch2)14cooh

A

palmitic acid

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4
Q

18 carbon carboxylic acid

A

stearic acid

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5
Q

20 carbon carboxylic acid

A

arachidic acid

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6
Q

ends in -al

A

aldehyde r-c=0

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7
Q

a hydroxly group attached to the cyclic aromatic structure

A

phenol and catecholamine

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8
Q

a cyclic =o

A

quinone

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9
Q

ubiquinone is coQ and is a component of electron transport chain in?

A

mitochondria

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10
Q

formed by carboxylic acids and amines

A

amide

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11
Q

fromed by replacing 1 or more H of NH3 with alkyl or derivative

A

amine

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12
Q

oxygen btwn alkyl groups

A

ether

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13
Q

vesicle structures containing oxidases

A

peroxisome

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14
Q

vesicles with hydrolytic enzymes

A

lysosomes

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15
Q

glycosylation of proteins

A

golgi apparatus

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16
Q

contains enzymes for phospholipd steroid and proteoglycan synthesis

A

er

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17
Q

polymers of these carboxylic acids form amide bonds

A

amino acids, peptide bonds, proteins

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18
Q

primary functional group is aldehyde and ketone

A

carbs

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19
Q

heterogenous fxn group are in what two substances

A

lipids and vitamins

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20
Q

polymers are phosphodiesters

A

nucleic acids

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21
Q

primary functional group of amino acids, peptides and proteins is?

A

cooh

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22
Q

name 3 aliphatic side chains

A

val, leu, Ile

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23
Q

name 3 hydroxyl side groups

A

tyr, hyl, hyp

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24
Q

name 2 sulfur side groups

A

cys met

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25
name 2 carboxyl/ amide side groups
asp, glu/asn, gln
26
name 2 aromatic side groups
phe, tyr
27
what are 3 intermediates in the synthesis of ureas?
citrulline, arginosuccininc acid, and ornithine
28
most amino acids in nature are in what form?
L-alpha
29
when 4 groups on a carbon are different= chiral carbons | two of these structures are known as?
enantiomers
30
if something rotates polarized light to the right it is ?
d | its l if it rotates to left
31
a molecule with both positive and negative charges is
zwitterion
32
what r group absorbs uv light?
aromatic
33
a protein with a carb covalently attached is?
glycoprotein
34
what kind of bonds are formed btwn carbs and amino acids
glycosidic bonds
35
what are 2 enkaphalins we should know?
leu-enkaphalin and met-enkaphalin
36
what are the 2 components of heme?
fe2+ and porphyrin
37
in the synthesis of collagen, what happens to proline and lysine?
they are hydroxylated
38
the genetic mutation in which gly turns to cys, results in bone bending
osteogenesis imperfecta
39
deforemd spine, bone demineraliztion and joint dislocation due to deficiency of lysl oxidase is?
lathyrism
40
a conjugated protein contains what 2 things?
a base protein= apoprotein | conjugated pair= prostethic group
41
where are antibodies and glycophorin from?
glycoproteins
42
where are hb, and cytochromes from?
hemoproteins
43
where are chylomicrons, ldl, hdl, vldl, found
lipoproteins
44
casein is found?
phosphoproteins
45
protease and some hemoproteins (ferredoxin) are from
metalloproteins
46
a carb that is less than 6 monosaccharide units?
oligosaccharide
47
what are the names of some trioses?
glyceraldehyde, glycerose, dhidroxyacetone
48
what are the names of some tetroses
erythrose, erythrulose
49
pentoses?
ribose, xylose, deoxyribose, ribulose, xylulose
50
hexoses?
glucose, galactose, mannose, fructose
51
d-glucose+ d-galactose=
lactose
52
glucose+ fructose=
sucrose
53
dimer of d-glucose=
maltose
54
dimer of d-glucose with beta 1-4 bond=
cellobiose
55
what three compunds does starch break into?
glucose, maltose, and isomaltose
56
xylose is always the sugar present in the largest amount in this mixture of non-carbs and polysachs
hemicellulose | not as strong as cellulose
57
polymers of methoxy phenols such as vanillin are called
lignins
58
extensin is a type of ______ found in dietary fibers
glycoprotein
59
what are sugar phosphates used for in biological systems?
to store and transfer energy
60
waxes contain which functional group
esters
61
_______ is formed from the reduction of carbs?
poyols
62
dihydroxyacetone reduces into ?
glycerol
63
_______ is formed fromt eh oxidation of carbs?
sugar acids
64
what is in the vitreous humor of eyes and joint lube in synovial fluid?
hyaluronic acid
65
unbranched, repeating dissachs, polymers of carb derivatives. has a long name. whats shortened version
GAGS
66
protein backbone for GAGs is?
proteoglycans
67
glyco proteins are proteins with attached?
oligosacchs
68
name 3 types of steroisomers
epimeres (oh), D &L isomers, alpha and beta
69
50:50 of d and l isomers is?
racemic mixture
70
sugars get reduced to
polyols
71
sugars get oxidized to
sugar acids
72
16 chain safa
palmitic acid
73
18 chain safa
stearic acid
74
20 chain safa
arachidic
75
essential fatty acid PUFAs
linoleic acid and alpha linolenic acid
76
conditionally essential fattys
GLA, AA, EPA
77
CONVERSION
LA>GLA>DGLA>AA
78
CONVERSION
ALA>EPA>DHA
79
VIT A, E AND K ARE?
ISOPRENOID LIPIDS
80
hydrophobicity?
c and h bonds do not have polarity so they dont form ionic or h bonds
81
whats an amphipathic lipid?
both hydrophobic and hydrophillic, this forms micelles
82
micelles are?
particles with a hydrophobic core and hydrophillic surface
83
spoilage of lipid foods due to autooxidation
oxidative rancidity
84
due to bacterial hydrolysis
hydrolytic rancidity
85
nucleic acids are composed of what 3 things
heterocyclic nitrogen bases, pentoses, and phosphatte
86
what makes a nucleoside?
nitrogen base + pentose
87
what makes a nucleotide
nucleoside + phosphate
88
what contians the codons for directing the sequence of amino acids of a polypeptide?
mRNA
89
a cloverleaf structure with hairpin loops, transfer amino acids to ribosomal site where protein synth takes place
tRNA