Unit 1: Atomic Structure Flashcards

(46 cards)

1
Q

Define Element

A

A pure chemical substance composed of atoms with the same number of protons in the atomic nucleus. Cannot be broken down into a simpler substance.

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2
Q

Define an atom

A

The smallest particle of an element to show characteristic properties of that element.

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3
Q

Define a compound.

A

Compounds consist of atoms of different elements chemically bonded together into a fixed ratio.
The chemical properties of a compound are different from that of its constituent elements.

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4
Q

Define a mixture.

A

Mixtures contain more that one element or compound in no fixed ratio.
- Components of a mixture can be separated by physical methods

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5
Q

What is a homogenous mixture?

A
  • A homogenous mixture has a uniform composition and properties throughout.
  • To form a homogenous mixture the inter-particle attraction within the different components must be similar to the components within the mixture
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6
Q

What is a heterogenous mixture?

A
  • A heterogenous mixture has a non-uniform composition, and its properties are not the same thro.
    -The interactions between the components are different in nature
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7
Q

Explain the methods of separating the components of a mixture.

A
  • Filtration
    Solid is separated from a liquid or a gas through a membrane.
  • Distillation
    Used to separate a solvent and a solute. The solvent has a lower boiling point then the solute and is collected as a gas. which then passes through a condensing tube and collected into a beaker.
  • Paper chromatography.
    Small spots of solutions containing the samples are placed on a baseline on a paper suspended. The paper is the dipped in water and the solutions have different affinities for water so they travel different distances along the paper.
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8
Q

State the kinetic molecular theory

A

Matter exists in different states as determines by the temperature and the pressure, Solid, Liquid and Gas

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9
Q

What is temperature in chemistry terms?

A

The measure of the average kinetic energy of the particles of the substance.

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10
Q

What is diffusion?

A

The process by which the particles of a substance spread out more evenly as a result of their random movement.

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11
Q

Define sublimation

A

Solid to a gas without going through the liquid state

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12
Q

Define deposition.

A

When a gas turns directly into a solid

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13
Q

When does boiling happen

A

At a fixed temperature for a given pressure. When the vapour pressure is equal to the external pressure
- As liquid heats more particle enter the vapour state and add to the vapour pressure.

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14
Q

When does Evaporation occur?

A

Only at the surface of the substance and takes place over a range of temperatures.

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15
Q

When is temperature constant?

A

During changes of state

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16
Q

What did John Dalton propose in the 19th century?

A
  • All matter is composed of tiny invisible particles called atoms
  • Atoms cannot be created or destroyed
  • Atoms of the same element are alike in every way
  • Atoms
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17
Q

How did Ernest Rutherford discover there was a positively charged nucleus in the middle of the atom?

A

By firing positively charged alpha particles at a piece of gold foil the particles mostly passed through but only a few were repelled when they hit a small dense positvley charged nucleus

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18
Q

How did JJ Thompson discover the atom had electrons?

A

When a high voltage is applied across two electrodes to different metals a stream of negatively charged particles is produced.

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19
Q

What happens when positrons and electrons (anti-particles) collide?

A

They destroy each other and release energy in the form of high energy photons called gamma rays.

20
Q

What is the number of protons in an element given by?

A

The atomic number

21
Q

How do you derive the number of neutrons in an element.

A

mass number - atomic number

22
Q

Define isotope.

A

Atoms of the same element with a different number of neutrons

23
Q

Do isotopes show the same chemical properties?

A

Yes, the difference in number of neutrons makes no difference in how they react as they still occupy the same place on the periodic table.

24
Q

What happens when a nucleus has too many or few neutrons.

A

It gives off radiation to become radioactive and changing to a more stable nucleus.

25
What does a mass spectrometer measure?
The mass and abundance of isotopes.
26
How does a mass spectrometer work?
- The element is vaporized so that individual atoms can be analyzed - The atoms are then ionized by high energy electrons which knock out an electron creating a positive ion - The positive ions are attracted to a negatively charged plate and deflected at a magnetic field placed at right angles to their path. - The amount of deflection is inversely proportional to their mass/charge ratio - If compound is analyzed in a mass spectrometer the electron collisions during the first IE are so energetic they cause the molecule to break and the resulting fragmentation pattern provides useful evidence about the structure of a compound.
27
What is the relative atomic mass of an element?
The average mass of the atom taking account of all isotopes and their abundance compared to one atom of carbon-12.
28
Whats the lowest and highest energy on the emission spectrum?
Highest energy - Gamma rays Lowest energy - Radio waves
29
Do all electromagnetic waves travel at the same speed?
Yes, but they all have different wavelengths.
30
Define frequency
The number a waves that pass through a particular point in one second.
31
Whats the relationship between frequency and wavelength?
The shorter the wavelength the higher the frequency.
32
When is an emission spectrum produced?
When an atom moves from a higher to lower energy level.
33
True or false: One Photon is released for each electron transition.
True
33
What form of energy is given out when an electron falls to a lower level?
Electromagnetic radiation.
34
True or false: Photons of infrared light have more energy than ultraviolet light.
False- Photons of UV have more energy then photons of infrared
35
Transitions to the first energy level result in what region of energy?
The highest- Ultraviolet
36
When is it said an ion has been ionized?
When an electron is at its highest energy and is no longer in the atom.
36
Transitions to the third energy level or higher result in what region of energy?
The lowest- Infrared
37
Define ionization energy.
The energy needed to remove an electron for the ground state if one mole of gaseous atoms.
38
Whats are limitations of the Bohr Rutherford model of the atom?
- It was able to predict the wavelengths of lines in the emission spectrum of hydrogen with great success it fails to predict the spectral lines of atoms with more than one electron. ­- Assumes electrons are in fixed orbitals ­- Assumes orbitals are circular ­- Scale is incorrect ­- Only works for H
39
What can be explained by wave and particle models of light and the electron?
Wave model- Explains the diffraction of light that occurs when light passes through a small slit Particle Model- The scattering of electrons that occurs when light is incident on a metal surface
40
What is Heisenbergs uncertainty principle?
­ - an electron's trajectory can't be measured because it would disrupt it's motion. You can not simultaneously know the location and the velocity at the same time.
41
What is Pauli exclusion principle?
An orbital can hold two electrons of the opposite spin.
42
Name the four quantum numbers.
1. Principle quantum number (n) - Energy level n= 1, 2, 3.. 2. Angular momentum (l) - Shape of the orbital l= 0, 1, 2, 3 3. Orientation 4. Spin
43
Name each sub-level and how many electrons they can hold.
- s ­ sub-level (l=0): 1 orbital and can hold 2 electrons - p ­ sub-level(l=1): 3 orbitals and can hold 6 electrons - d ­ sub-level(l=2): 5 orbitals can hold 10 electrons - f ­ sub-level (l=3): 7 orbitals can hold 14 electrons
44
What does the energy of an orbital depend on
The attraction between electrons and the nucleus and the inter electron repulsions.