Unit 1 - Chemical Changes and Structure Flashcards

1
Q

Covalent radius

A

Half the distance
between the nuclei of 2 of its bonded atoms.

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2
Q

What happens to the covalent radius as you go
across a period?

A

It decreases due to increased atomic number.

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3
Q

What happens to the covalent radius as you go down
a group?

A

It increases due to increased electron shielding.

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4
Q

Ionization energy

A

The energy required to remove one mole of electrons
from one mole of atoms in the gaseous state

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5
Q

The strength of metallic bonding _____ as you go along a period.

A

Increases, due to increased numbers of delocalized electrons.

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6
Q

The strength of
metallic bonding
________ as you
go down a group

A

Decreases.

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7
Q

Intramolecular forces

A

The strong attraction between atoms and molecules

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8
Q

Intermolecular forces

A

The weak attraction in-between different molecules

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9
Q

Three types of Van der Vaals intramolecular forces

A
  • London dispersion forces
  • PD-PD
  • hydrogen bonding
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10
Q

What molecules create hydrogen bonding?

A

NH, OH or FH

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11
Q

Electronegativity

A

Electronegativity is a measure of the attraction an atom involved in a bond has for the electrons in a bond.

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12
Q

Elements at the top________ hand side of the periodic table e.g. F .0, N are the _______electronegative.

A

Right, most.

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13
Q

Elements at the bottom _______ hand side of the periodic table e.g. K, Rb, Cs are the ______ electronegative.

A

Left, least.

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14
Q

Electronegativity ________________ as we go along a period.

A

Increases.

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15
Q

Electronegativity ________________ as we go down a group.

A

Decreases.

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16
Q

The strength of London dispersion force _______ as the size of the atoms increase.

A

Increases.

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17
Q

Covalent molecular substances have ______________melting points and boiling points

A

Low.

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18
Q

Within covalent molecules there are strong _____________ bonds

A

Intramolecular.

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19
Q

Polymorphs are___

A

different crystalline forms of the same element

20
Q

Fullerenes are a large family of ‘carbon cage’ molecules each made up of rings of _____ and _____ carbon atoms.

A

5&6

21
Q

C60 is called..

A

Buckminsterfullerene

22
Q

With no ‘free’_____________ fullerenes are normally poor conductors

A

Electrons

23
Q

Nanotubes are…

A

fullerenes made from ‘tubes’ of 6-carbon rings rather like a rolled up sheet of graphite

24
Q

polymorphs of carbon

A

diamond & graphite

25
Q

In diamond, each Carbon is joined to ____ others in a ______

A

4 & tetrahedral network structure

26
Q

In graphite, each Carbon is joined to ____ others in a ______

A

3 & layers with a hexagonal arrangement of atoms

27
Q

The noble gases exist as …………………… atoms with ……………………………. between the atoms.

A

monatomic & LDFs

28
Q

Covalent molecular compounds are…

A

made of discrete particles with a definite formula

29
Q

Covalent network compounds are…

A

made of a giant lattice of atoms covalently bonded

30
Q

Covalent bonding is…

A

the attraction of the shared electrons for the nuclei of both the bonded atoms

31
Q

Water molecules are _____________ in shape.

A

angular

32
Q

Hydrogen bonding is _______ than LDFs

A

stronger

33
Q

Types of Van Der Waals’ forces

A

London dispersion forces, PD-PD interactions and hydrogen bonding

34
Q

Elements which can hydrogen bond

A

FON

35
Q

Because it is polar water is useful as a ______ for ionic compounds.

A

solvent

36
Q

like dissolves like

A

like dissolves like

37
Q

______ is an excellent oxidising agent.

A

Acidified dichromate

38
Q

The elements with low electronegativities (_____) tend to form ions by losing electrons (_____). They can be called _____________ agents.

A

metals, oxidation & reducing

39
Q

The strongest reducing agents are found in…

A

group 1

40
Q

The elements with high electronegativities (_____) tend to form ions by gaining electrons (______). They can be called ____________ agents.

A

non-metals, reduction & oxidising

41
Q

The strongest oxidising agents are found in…

A

group 7

42
Q

Oxidising agents are widely employed to…

A

kill fungi and bacteria, bleaching stuff

43
Q

Apart from electronegativity, how can you determine the ionic character of a compound

A

Ionic compounds will conduct, have higher mps and be soluble in water.

44
Q

Acidified potassium dichromate use

A

Oxidising agent

45
Q

Acidified potassium dichromate colour change

A

Orange > green when oxidised

(think of copper orange to green)