Unit 1 - Chemical changes and structure Flashcards
Unit 1 - Periodicity, Structure & Bonding, Oxidation & Reduction
What are the ‘Metallic Elements’?
Li, Be, Na, Mg, Al, K and Ca
What are the ‘Covalent Molecular Elements’?
H2, N2, O2, F2, Cl2, P4, S8 and C40
What are the ‘Covalent Network Elements’?
Boron, Diamond, Graphite and Si
What are the ‘Monatomic’ elements?
Noble gases
Define, ‘Covalent Radius’?
The measure of the size of an atom
Explain the trend of the ‘Covalent Radius’ across periods?
The covalent radius decreases as the number of protons increases, the greater nucleus charge results in a stronger pull on the electrons
Explain the trend of the ‘Covalent Radius’ down groups?
The covalent radius increases as the electron shells increases, the outer electrons are further from the nucleus which results in a shielding effect
Define, ‘Ionisation Energy’?
The act of removing electron(s), which requires energy and is an endothermic process
Explain the trend of the ‘Ionisation Energy’ across periods?
The first I.E increases due to an increase in nuclear charge and outer electrons are more strongly attracted to the nucleus making them harder to remove
Explain the trend of the ‘Ionisation Energy’ down groups?
The first I.E decreases due to there being more occupied shells and more inner electrons cause a shielding effect making the electrons easier to use
Define, ‘Electronegativity’?
A measure of the attraction an atom involved in a bond has for the electrons in the bond
Explain the trend of the ‘Electronegativity’ across periods?
There is an increase due to an increase in nuclear charge and this causes the bonded electrons to be more attracted to the nucleus
Explain the trend of the ‘Electronegativity’ down groups?
There is an decrease due to an increase in the number of occupied electron shells causing the bonding electrons to be less attracted the positive nuclear
Define, ‘Ionic Bonding’?
The electrostatic attraction between positive and negative ions
Define, ‘Covalent Bonding’?
The attraction between two positive nuclei and their common attraction for a shared pair of electrons
Define, ‘Pure Covalent Bond’?
Where electrons are shared equally between the atoms because the atom’s electronegativity is equal
Define, ‘Polar Covalent Bond’?
Formed when the attraction of atoms for a pair of binding electrons that are different
“______ difference in electronegativity gives more ionic character”
Bigger difference in electronegativity gives more ionic character
What do polar molecules contain?
They contain polar bonds, and have a shape that gives a clear delta negative and positive
Define, ‘Intramolecular’?
Within molecules
Define, ‘Intermolecular’?
Between molecules or atoms
What are the three ‘Van Der Waal’s Forces’?
LDFs, Pd-Pd Interactions, and Hydrogen bonding
Describe, ‘London Dispersion Forces’?
The weakest intermolecular forces, occurs between all atoms and molecules and are formed as a result of electrostatic attraction between temporary dipoles and induced dipoles that form because of the uneven distribution of electrons
Describe, ‘Pd-Pd Interactions’?
Stronger than LDFs but weaker than Hydrogen bonding, occurs between polar covalent molecules, have higher melting point and boiling points due to the permanent dipoles attraction to each other