Unit 1 - Chemical changes and structure Flashcards

Unit 1 - Periodicity, Structure & Bonding, Oxidation & Reduction

1
Q

What are the ‘Metallic Elements’?

A

Li, Be, Na, Mg, Al, K and Ca

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2
Q

What are the ‘Covalent Molecular Elements’?

A

H2, N2, O2, F2, Cl2, P4, S8 and C40

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3
Q

What are the ‘Covalent Network Elements’?

A

Boron, Diamond, Graphite and Si

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4
Q

What are the ‘Monatomic’ elements?

A

Noble gases

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5
Q

Define, ‘Covalent Radius’?

A

The measure of the size of an atom

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6
Q

Explain the trend of the ‘Covalent Radius’ across periods?

A

The covalent radius decreases as the number of protons increases, the greater nucleus charge results in a stronger pull on the electrons

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7
Q

Explain the trend of the ‘Covalent Radius’ down groups?

A

The covalent radius increases as the electron shells increases, the outer electrons are further from the nucleus which results in a shielding effect

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8
Q

Define, ‘Ionisation Energy’?

A

The act of removing electron(s), which requires energy and is an endothermic process

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9
Q

Explain the trend of the ‘Ionisation Energy’ across periods?

A

The first I.E increases due to an increase in nuclear charge and outer electrons are more strongly attracted to the nucleus making them harder to remove

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10
Q

Explain the trend of the ‘Ionisation Energy’ down groups?

A

The first I.E decreases due to there being more occupied shells and more inner electrons cause a shielding effect making the electrons easier to use

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11
Q

Define, ‘Electronegativity’?

A

A measure of the attraction an atom involved in a bond has for the electrons in the bond

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12
Q

Explain the trend of the ‘Electronegativity’ across periods?

A

There is an increase due to an increase in nuclear charge and this causes the bonded electrons to be more attracted to the nucleus

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13
Q

Explain the trend of the ‘Electronegativity’ down groups?

A

There is an decrease due to an increase in the number of occupied electron shells causing the bonding electrons to be less attracted the positive nuclear

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14
Q

Define, ‘Ionic Bonding’?

A

The electrostatic attraction between positive and negative ions

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15
Q

Define, ‘Covalent Bonding’?

A

The attraction between two positive nuclei and their common attraction for a shared pair of electrons

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16
Q

Define, ‘Pure Covalent Bond’?

A

Where electrons are shared equally between the atoms because the atom’s electronegativity is equal

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17
Q

Define, ‘Polar Covalent Bond’?

A

Formed when the attraction of atoms for a pair of binding electrons that are different

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18
Q

“______ difference in electronegativity gives more ionic character”

A

Bigger difference in electronegativity gives more ionic character

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19
Q

What do polar molecules contain?

A

They contain polar bonds, and have a shape that gives a clear delta negative and positive

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20
Q

Define, ‘Intramolecular’?

A

Within molecules

21
Q

Define, ‘Intermolecular’?

A

Between molecules or atoms

22
Q

What are the three ‘Van Der Waal’s Forces’?

A

LDFs, Pd-Pd Interactions, and Hydrogen bonding

23
Q

Describe, ‘London Dispersion Forces’?

A

The weakest intermolecular forces, occurs between all atoms and molecules and are formed as a result of electrostatic attraction between temporary dipoles and induced dipoles that form because of the uneven distribution of electrons

24
Q

Describe, ‘Pd-Pd Interactions’?

A

Stronger than LDFs but weaker than Hydrogen bonding, occurs between polar covalent molecules, have higher melting point and boiling points due to the permanent dipoles attraction to each other

25
Describe, ‘Hydrogen Bonding’?
The strongest Van Der Waal force, occurs when polar molecules contain a strongly electronegative element bonded to hydrogen (i.e nitrogen, oxygen and fluorine)
26
What happens when you place a charged rod near a polar substance?
The polar substance will be attracted to the charged rod
27
Define, ‘Viscosity’?
The measure of ‘thickness’ of a liquid; the thicker the liquid the more viscous it is, the stronger the intermolecular forces the higher the viscosity
28
Describe, the density of ice and water?
The hydrogen bonding in water results in an expanded structure that causes the density of water (when ice) to be lower at low temperatures
29
Define, ‘Soluble’?
When a gas or solid is able to dissolve in a liquid
30
Define, ‘Miscible’?
A liquid that is able to mix/dissolve in another liquid
31
Define, ‘Solvent’?
The liquid in which the substance dissolves in
32
Why is water a useful solvent?
Its polarity can dissolve ionic substances due to its slightly negative ends of the water molecule that attract positive ions and the slightly positive ends attract negative ions
33
Explain “Like dissolves Like”?
Non polar molecules are soluble in non polar solvents, ionic substances are soluble in polar solvents, and non polar substances are immiscible in polar solvents (vise versa)
34
Define, ‘Oxidation’?
Where electrons are lost
35
Define, ‘Reduction’?
Where electrons are gained
36
Describe, ‘Oxidising Agents’?
A substance which accepts electrons in a reaction and it causes the other substance(s) in reaction to be oxidised
37
Describe, ‘Reducing Agents’?
A substance which donates electrons in a reaction and it causes the other substance(s) in the reaction to be reduced
38
Which substances make strong oxidising agents?
Substances with high electronegativity that will easily accept electrons
39
Which substances make strong reducing agents?
Substances with low electronegativity that will easily donate electrons
40
Define, ‘Spectator Ions’?
Ions that are present in REDOX reactions but do not take part in the reaction
41
Explain what happens in Displacement reactions?
A more reactive metal that will displace a less reactive metal from a solution
42
"The strongest _________ agents are at the bottom left-hand column of the electrochemical series"
"The strongest oxidising agents are at the bottom left-hand column of the electrochemical series"
43
"The strongest ________ agents are at the top right-hand column of the electrochemical series"
"The strongest reducing agents are at the top right-hand column of the electrochemical series"
44
Name Oxidising Agent(s)?
Hydrogen Peroxide, Potassium Permanganate, and Potassium Dichromate
45
Name Reducing Agent(s)?
Carbon Monoxide and Chlorine
46
Describe, ‘Potassium Permanganate’ and its uses?
An oxidising agent used to kill fungi, bacteria and inactive viruses, used in bleaches and to treat athlete’s foot
47
Describe, ‘Hydrogen Peroxide’ and its uses?
An oxidising agent used to break down coloured compounds, used for bleach for in clothes and hair
48
Describe, ‘Chlorine’ and its uses?
An reducing agent that kills bacteria by removing electrons from bacteria and when added to water it will breakdown to from hydrochloric acid