Unit 1: Section 12- Acids and Bases + RP 9 Flashcards

(29 cards)

1
Q

Define a Bronsted-Lowry acid

A

a substance that can donate a proton

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2
Q

Define a Bronsted-Lowry base

A

a substance that can accept a proton

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3
Q

What is the equation for calculating pH?

A

pH = log[H+]

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4
Q

What does [H+] represent?

A

the concentration of the hydrogen ions in the solution

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5
Q

Define strong acid

A

they fully dissociate

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6
Q

What is a monoprotic acid?

A

an acid that donates one H+ ion or proton per every molecule when it dissociates with water

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7
Q

How many d.p. values is pH given to?

A

2d.p.

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8
Q

How do you rearrange the pH equation to find [H+]?

A

[H+] = 1 x 10 ^-pH

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9
Q

What is the equilibrium equation that occurs in all aqueous solutions and pure water?

A

H2O (l) ⇌ H+ (aq) + OH- (aq)

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10
Q

Why is Kw used and not Kc?

A

because [H2O (l)] is much bigger than the concentrations of the ions, we assume its value is constant and make a new value, Kw

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11
Q

What is the Kw expression?

A

Kw = [H+ (aq)] [OH- (aq)]

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12
Q

What type of compound are weak acids usually?

A

organic

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13
Q

What type of compound are strong acids usually?

A

inorganic

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14
Q

What is a diprotic acid?

A

donates two hydrogen ions (H2SO4), the [H+] is 2x that of the acid

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15
Q

How can the Kw equation be rewritten for pure and neutral solutions?

A

Kw = ([H+])²
because [OH-] = [H+]

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16
Q

What is the Kw value of an aqueous solution at room temp (25°C)?

A

1.0 x 10^-14 mol^2 dm^-6

17
Q

define strong base

A

they completely dissociate into their ions in solution

18
Q

How to calculate pH of strong base

A

1) use pH equation
2) use Kw equation
3) pH of a base = -log√Kw

19
Q

What is Kw?

A

the ionic product of water, 1.0 x 10^-14 mol^2 dm^-6

20
Q

Define weak acid

A

only partially dissociate into their ions in solution

21
Q

What is Ka?

A

the acid dissociation constant

22
Q

What does the size of the Ka value mean?

A

larger Ka= compounds that dissociate more completely into solution, stronger acids

smaller Ka= weaker acids

23
Q

What is the Ka equation?

A

Ka = [H+]² / [HA]initial

24
Q

What are the two key assumptions when using Ka to calculate the pH of weak acids?

A
  1. that [H+] = [A-]
  2. that conc of HA at equilibrium is the same as initial conc of the acid because of small dissociation
25
What is the equation for converting pKa into Ka?
Ka = 10 ^-pKa
26
What is pKa?
the negative logarithm of Ka
27
What is the equivalence point?
the volume of one solution that exactly reacts with the volume of the other solution
28
What is the end point of a titration?
when the indicator changes colour
29
How to pick an indicator?
needs to be at the end point, in the vertical section of the curve