Unit 1 Study Flashcards

(47 cards)

1
Q

What are the four classical elements in early atomic theory?

A

Earth, fire, air, and water

These elements were believed to be in Brownian motion within a void.

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2
Q

What did Dalton’s Atomic Theory state about atoms?

A

Atoms are the tiniest substance, element’s atoms are identical, atoms vary by element, compounds consist of two or more elements, and conservation of mass

Dalton’s theory laid the foundation for modern chemistry.

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3
Q

Who discovered electrons and how?

A

JJ Thomson using a cathode ray tube

He demonstrated that electrons are negatively charged particles smaller than hydrogen atoms.

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4
Q

What is the Plum Pudding model?

A

Model where the atom is a blob with electrons scattered throughout

Proposed by Thomson after his discovery of electrons.

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5
Q

What did Rutherford discover about the atom?

A

That there is a dense area within the atom, known as the nucleus

This was discovered through the deflection of alpha particles in foil bombardment experiments.

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6
Q

What is the Planetary Model of the atom?

A

Electrons move around the nucleus like planets around the sun

This model was created despite known issues with circular orbits.

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7
Q

What is the mass of a single atom defined as?

A

1 AMU(weight of 1 carbon-12)

Defined using the mass of one atom of carbon-12 (12 amu).

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8
Q

What is the difference between mass number and atomic number?

A

Mass Number (A) = protons + neutrons; Atomic Number = number of protons

The atomic number also indicates the number of electrons in a neutral atom.

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9
Q

What are isotopes?

A

Atoms with the same number of protons and electrons but different numbers of neutrons

Only the weight changes among isotopes.

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10
Q

What does Coulomb’s Law state?

A

Opposite charges attract and like charges repel, include gravitational, electrostatic, weak nuclear, strong nuclear

This law describes the electrostatic force between charged particles.

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11
Q

What is the gravitational force?

A

A force between objects that have mass, always attractive

It is described by Newton’s Law of Universal Gravitation.

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12
Q

What is kinetic energy (KE)?

A

Energy observed in motion, calculated as KE = ½(m)(v^2)

Kinetic energy increases with the speed of the object.

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13
Q

What is potential energy (PE)?

A

Energy associated with the position of a system

It changes with the position of objects within a field.

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14
Q

What are London Dispersion Forces?

A

Attractive forces that exist within all neutral solid and liquid atomic structures due to electrons clouds focusing electrons in one area and creating electrostatic forces.

They arise from temporary dipoles created by electron movement.

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15
Q

How do London Dispersion Forces increase?

A

With the number of electrons and surface area

More electrons lead to a higher likelihood of distortion and induced dipoles.

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16
Q

What is the significance of a deeper potential energy well?

A

Indicates a higher boiling point due to the required energy to break bonds

For example, argon has a higher boiling point than neon due to more electrons.

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17
Q

What is a covalent bond?

A

A bond formed when non-noble gases share electrons

Covalent bonds lead to the formation of new compounds, such as H2.

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18
Q

What is stoichiometry?

A

The relationship between the macroscopic and molecular level

It involves balanced equations to describe chemical reactions.

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19
Q

What is the mole unit?

A

A unit for the number of atoms in 12g of C-12, equal to 6.022x10^23

It is used as a universal conversion unit.

20
Q

What is a solution in chemistry?

A

A homogeneous mixture of two or more components

The solute is the minor quantity that dissolves in a solvent, the major component.

21
Q

How are gravitational and electrostatic forces measured

A

G: M1M2/r^2 E:Q1Q2/R2 r=distance

22
Q

Dalton’s Atomic Theory

A

Atoms are tiniest subtance on earth with each element having identical atoms

23
Q

What was JJ thomsons experiment

A

He found the existence of electrons through a cathode ray tube and proved something was lighter than H

24
Q

What was JJ Thomson’s model

A

Plum Pudding Model-atoms are blobs with electrons scattered throughout it randomly

25
What was Rutherfords experiment
Alpha Particle experiment which proved existence of a nucleus
26
What was Rutherford's model
Planetary Model-nucleus with electrons orbiting despite knowing there were errors in it.
27
How were neutrons discovered
Discovered due to atoms being neutral yet having heavier weight than just electrons and protons
28
How big are electrons
1/2000 amu, 1:20k electron:atom
29
How much does an atom weigh(unit)
AMU defined as one carbon 12 atom(12 amu)
30
What are Isotopes
Same atoms with differing neutrons that occur naturally
31
How to find Isotope abundance rate
(x)+(1-x)=periodic table mass (most abundant isotope is "(1-x)"
32
How to find Isotope weight
iso-1(abundance) + iso-2(abundance)=mass
33
Coulomb's law
opposite charges attract, like charges repel dictated by particle charge
34
Universal Gravitation Equation
F=M1M2/r^2
35
Electrostatic Force Equation
F=Q1Q2/r^2
36
What is temperature
A measure of energy with the change in temp being the average kinetic energy
37
Kinetic Energy
energy in motion KE=1/2(m)(v^2)
38
Potential Energy
Energy associated within position of a system-attractive forces have negative PE
39
London Dispersion Forces
distorted electron clouds cause uneven charges and then molecules/particles to have attraction(only solids and liquids)
40
How do electrons influence LDF's
As electrons and surface area increase distortion increases
41
Dipole
Unevenly charges atoms(LDF's)
42
PE of LDF's
Potential Energy well shows where PE is lowest due to attractive forces moving atom closer and point of repulsion
43
Polarizability
ability for a cloud to be polarized(more polarization with more electrons)
44
Thermal Energy
1/2(m)(v^2) is the sum of kinetic energy and greater in larger portions due to more atom movement
45
PEW
Deeper the well the higher boiling point as more energy is needed to break force attraction
46
Covalent Bonds
Non noble gasses create these bonds by sharing electrons and creating a new compound. Stronger than LDF's=more energy to break bond.
47
Covalent bond energy
Forming bonds=releases energy, breaking bonds=absorbs energy