Unit (11) Molecules of Life: Lipids and Proteins Flashcards

1
Q

What are Lipids?

A

Biochemical compounds that contain carbon, hydrogen, and oxygen.

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2
Q

What is the solubility of Lipids?

A

Insoluble in water but soluble in organic solvents.

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3
Q

What are the two major categories for Lipid classification?

A

Fatty acid containing Lipids and Non fatty acid containing Lipids

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4
Q

Which type of Lipids are considered fatty acid?

A

Fats and oils, waxes, phospholipids

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5
Q

Which type of Lipids are considered non fatty acids?

A

Steroids

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6
Q

What is the fundamental building block of many lipids?

A

Long chain carboxylic acids called fatty acids

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7
Q

A saturated fatty acid contains?

A

Only carbon-carbon single bonds in the hydrocarbon

chain.

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8
Q

A monounsaturated fatty acid contains?

A

One C = C double bond in the hydrocarbon chain.

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9
Q

A polyunsaturated fatty acid contains?

A

Two or more C = C double bonds in the

hydrocarbon chain.

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10
Q

Animal fats and vegetable oils are lipid esters known as?

A

triglycerides

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11
Q

Glycerol (older name glycerin) is a small chain alcohol containing?

A

Three carbons with a

hydroxyl (-OH) group bound at each carbon.

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12
Q

A monoglyceride contains?

A

one fatty acid attached to glycerol

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13
Q

A diglyceride contains?

A

two fatty acids attached to glycerol

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14
Q

A triglyceride contains?

A

three fatty acids attached to glycerol

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15
Q

Fats are triglycerides containing?

A

saturated fatty acids and are solids at room temperature, i.e.: lard

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16
Q

Oils are triglycerides containing?

A

unsaturated fatty acids and are liquids at room temperature

17
Q

Triglycerides (fats or oils) can be hydrolyzed (broken down) to produce?

A

glycerol and three fatty acids. When a strong base is used (i.e.: NaOH), glycerol and the sodium salts
of the fatty acids are produced.

18
Q

The sodium salts of fatty acids are called?

A

Soaps

19
Q

Fat or oil + strong base———> ?

A

glycerol + soap

20
Q

Waxes are?

A

simple lipids that, like oils and fats, are also esters of fatty acids. However, the alcohol portion of a wax is derived from long-chain alcohols (12-32 carbons) rather than glycerol.

21
Q

Phosphoglycerides are a family of lipids that are similar to glycerides except that?

A

one –OH group of glycerol is replaced by the ester of phosphoric acid and an amino-alcohol.

22
Q

Structurally, steroids are easily recognized because they all contain a?

A

characteristic four-fused ring system; three cyclohexane rings and one cyclopentane ring.

23
Q

The most abundant steroid found in the human body, and the most important, is?

A

Cholesterol

24
Q

In humans, most steroids function as?

A

hormones, powerful chemical messengers that transport signals from one cell to another.

25
Q

There are two main classes of steroid hormones:?

A

the sex hormones and the adrenocortical hormones

26
Q

Sex hormones control?

A

reproduction and secondary sex characteristics

27
Q

Adrenocortical hormones regulate?

A

numerous biochemical processes

28
Q

Amino acids are organic molecules that contain?

A

an amino group and a carboxyl group

29
Q

The amino acids in proteins are called?

A

alpha (a)-amino acids because the amino group is

attached to the (a)-carbon.

30
Q

All amino acids (except proline) contain?

A

–H, -NH2, and –COOH bound to the -carbon. They are differentiated by the side chains (called R-groups) also bound to the a-carbon.

31
Q

Amino acids are classified into four groups:?

A

nonpolar, polar acidic, polar basic, and polar-neutral

amino acids.

32
Q

All a-amino acids, except glycine, are?

A

chiral because the a-carbon is bound to four

different groups.

33
Q

When writing Fischer projections for amino acids, the -COOH group is always written?

A

at the top and the R group at the bottom

34
Q

Amino acids contain?

A

an acidic group (-COOH) and a basic group (NH2).

35
Q

Individual amino acids in a protein molecule are linked by?

A

Peptide bonds

36
Q

A peptide bond forms when?

A

a carboxylic acid from one amino acid reacts with the amino group of another amino acid.

37
Q

All peptide chains will have?

A

an amino group at one end (a free, unbound -NH3

+) and a carboxylate at the other (a free –COO-).

38
Q

By convention, we draw peptides and proteins

with?

A

the N-terminal (unreacted or free amino group) on the left end of the peptide chain and the C-terminal (the carboxylate group) on the right end of the polypeptide.

39
Q

Peptides are named by listing?

A

the amino acid residues in order from the N- to C-terminal.