Unit 2: Section 3- Period 3 Elements (2.4) Flashcards

(42 cards)

1
Q

What subshell is the outer electron in in Mg and Na?

A

s subshell

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2
Q

What are the different reactions between magnesium and sodium with water?

A

sodium more reactive, more readily ionises
magnesium reacts slowly with cold water

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3
Q

State the reaction between sodium and cold water

A

2Na + 2H2O → 2NaOH + H2

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4
Q

State the reaction between magnesium and cold water

A

Mg + 2H2O → Mg(OH)2 + H2

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5
Q

State the reaction between magnesium and steam

A

Mg (s) + H2O (g) → MgO (s) + H2 (g)

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6
Q

How do the period 3 elements react with oxygen?

A

they all form oxides (except argon) that take up their highest oxidation state

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7
Q

What is the exception for sulphur in oxidation states when reacting with oxygen?

A

sulphur forms an oxide where the oxidation state of sulphur is +4

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8
Q

What is the oxidation state of the period 3 element in an oxide?

A

+3 (except sulphur)

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9
Q

What visible changes can you see when sodium reacts with oxygen?

A
  • white solid formed
  • yellow flame
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10
Q

State the equation of sodium reacting with oxygen

A

4Na (s) + O2 (g) → 2Na2O (s)

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11
Q

What colour flame do magnesium, aluminium, silicon and phosphorous burn with?

A

white flame

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12
Q

What colour flame does sulphur burn with?

A

blue flame

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13
Q

State the equation between sulphur and oxygen

A

S (s) + O2 (g) → SO2 (g)

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14
Q

State the equation for magnesium reacting with oxygen

A

2Mg (s) + O2 (g) → 2MgO (s)

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15
Q

State the equation for aluminium reacting with oxygen

A

4Al (s) + 3O2 (g) → 2Al2O3 (s)

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16
Q

State the equation for silicon reacting with oxygen

A

Si (s) + O2 (g) → SiO2 (s)

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17
Q

State the equation for phosphorous reacting with oxygen

A

4P (s) + 5O2 (g) → P4O10 (s)

18
Q

What are properties of sulphur dioxide (SO2)

A

acidic, choking gas

19
Q

What are the three giant ionic lattice structures of period 3 oxides?

A

Na2O, MgO, Al2O3

20
Q

Describe the structure of SiO2

A

macromolecular, giant covalent oxide

21
Q

Name the structure of P4O10 and SO2

A

simple molecular structures

22
Q

How do the structures of period 3 metal oxides effect the melting points?

A

these different structures lead to period 3 metal oxides having different melting points

23
Q

What type of melting point do ionic metal oxides have?

24
Q

Explain the trend in melting point from Na2O to Al2O3

A

melting point increases due to the increased charge of the cation, which makes the electrostatic forces even stronger

25
What happens to the trend in melting point after Al2O3?
there is an increase, as SiO2 is macromolecular, with very strong covalent bonds, and a very high MP
26
What type of melting point does SiO2 have?
very high, strong covalent bonds, high energy needed to break
27
What happens to the trend in melting point after SiO2?
it drops
28
What type of melting point does P4010 and SO2 have?
lower melting point because they are simple molecular oxides P4O10 has higher than SO2 because of more electrons, so larger van der waals.
29
What do metal ionic oxides form when they react with water?
hydroxides which are alkaline
30
State the reaction between Na2O and water, and the pH of the product
Na2O + H2O → 2NaOH pH of 13
31
State the reaction between MgO and water, and the pH of the product
MgO (s) + H2O (l) → Mg(OH)2 (s) pH of 9
32
Explain why the pH of Mg(OH)2 is lower than 2NaOH
because Mg(OH)2 is only slightly soluble, so it only slightly dissociates difference in solubility due to Mg ion being smaller, so it has a stronger lattice, so fewer OH- ions produced
33
State the reaction between phosphorous oxide and water, and give the pH of the product
P4O10 (s) + 6 H2O (l) → 4H3PO4 (aq) pH of 0
34
State the reaction between SO2 and water, and give the pH of the product
SO2(g) + H2O (l) → H2SO3 (aq) pH of 3
35
State the reaction between SO3 and water, and give the pH of the product
SO3 (g) + H2O (l) → H2SO4 (aq) pH of 0
36
What are the three types of oxides?
acidic basic amphoteric
37
What period 3 oxides are examples of basic oxides?
Na2O MgO
38
What period 3 oxides are examples of acidic oxides?
P4O10 SO2 SO3
39
What period 3 oxides are examples of amphoteric oxides?
Al2O3
40
What happens to period 3 basic oxides in reactions?
react with acids to form a salt and water
41
What happens to period 3 acidic oxides in reactions?
react with bases to form salts
42
What happens to period 3 amphoteric oxides in reactions?
react with acids or bases they can act as both an acid an an alkali