Unit 2 Test Flashcards

(79 cards)

1
Q

combustion reaction

A

a reaction involving a substance (hydrocarbon) reacting w/ oxygen (O2) to produce (O2 + H2O)

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2
Q

alkali metal reaction

A

alkali metals (group 1) react with water to produce hydrogen gas (H2) and hydroxide (OH-)

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3
Q

halogen reactions

A

halogen (group 17) react w/ metals to form halides

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4
Q

molarity (M)

A

the amount of solute (in moles) divided by the volume of solution (L)

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5
Q

strong electrolyte

A

substances that completely dissociate into ions when they dissolve in water

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6
Q

nonelectrolytes

A

do not dissociate into ions when dissolved in water and do not conduct electricity

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7
Q

weak electrolyte

A

only a few solute dissolve and ions are created, conducts electricity weakly

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8
Q

acid

A

a substance that produces hydrogen ion in water

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9
Q

base

A

a substance that produces hydroxide ion in water

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10
Q

what are the weak acids?

A

CHO2 (Formic acid), HC2H3O2 (Acetic acid), HF (Hydrofluoric acid)

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11
Q

what is the weak base?

A

NH3 (ammonia)

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12
Q

sulfide

A

S^2-

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13
Q

In a gas forming reaction, what gas does sulfide (S^2-) evolve?

A

H_2S

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13
Q

In a gas forming reaction, what gas and liquid do carbonates (CO_3^2-) and bicarbonates (HCO_3^1-) give off?

A

H2O (l), CO2 (g)

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14
Q

Bicarbonate

A

HCO_3^1-

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14
Q

bisulfite

A

HSO3^1-

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14
Q

sulfite

A

SO3^2-

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15
Q

Carbonate

A

CO_3^2-

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16
Q

In a gas forming reaction, what gas and liquid do sulfites and bisulfites give off?

A

H2O (l), SO2 (g)

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17
Q

ammonia

A

NH3^-

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18
Q

In a gas forming reaction, what gas and liquid does ammonium give off?

A

H2O (l), NH3(g)

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19
Q

What is the equivalence point in an acid-base titration?

A

the amount of titrant added is enough to neutralize the analyte solution, moles of base = moles of acid and the solution only contains water and salt

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20
Q

What are the five rules for oxidation states?

A
  1. Oxidation state of a free atom is 0.
  2. Oxidation state of a monatomic ion is equal to its charge.
  3. Sum of the oxidation states of all atoms in: a neutral molecule or formula unit is 0 and an ion is equal to the charge of the ion
  4. Group 1A metrals always have a state of +1, Group 2A metals always have an oxidation state of +2
  5. Follow the nonmetals chart.
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21
Q

Oxidation state of fluorine:

A

-1

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22
Oxidation state of hydrogen:
+1
23
Oxidation state of oxygen:
-2
24
Oxidation state of Group 7A:
-1
25
Oxidation state of 6A:
-2
26
Oxidation state of 5A:
-3
27
Oxidizing agent
a substance that causes the oxidation of another substance (oxidation number lowers between the reactant and product)
28
Reducing agent
a substance that causes the reduction of another substance (oxidation number is higher between the reactant and product)
29
Combination (synthesis) reaction
2 or more substance combine to form a single product
30
Decomposition reaction
A single compound breaks down into 2 or more simpler substances
31
Combustion reaction
A substance reacts with oxygen, producing heat and light
32
Precipitation reaction
2 aqueous solutions form an insoluble solid (precipitate)
33
Acid - Base reaction
An acid reacts with a base to produce salt and water
34
Gas Forming reactions
reactions that produce a gas w one of the products
35
redox
reactions where electrons are transferred between species, resulting a change in oxidation states
36
Nitrate
NO3^1-
37
Sulfate
SO4^2-
38
Phosphate
PO4^3-
39
Acetate
C2H3O2^1-
40
Carbonate
CO3^2-
41
energy
the capacity to do work
42
work
the result of a force acting through a distance
43
heat
the flow of energy caused by a temperature difference
44
kinetic energy
the energy associated with the motion of an object
45
thermal energy
the energy associated with the temperature of an object
46
potential energy
the energy associated with the position or composition of an object
47
chemical energy
the energy associated with the relative positions of electrons and nuclei in atoms and molecules
48
law of conservation of energy
energy can neither be destroyed nor created
49
1st law of theromynamics
total energy of the universe is constant
50
internal energy
the sum of the kinetic energy and potential energy of al the particles that compose the system
51
state function
a quantity, such as internal energy, whose value depends only on the state of the system, not on how it got there
52
how many Joules in a cal?
1 cal = 4.184 J
53
how many joules in a Cal?
1 Cal = 4184 J
54
how many joules in a kwh?
3.60 * 10^6 J
55
extensive property
a property that depends on the amount of a given substance
56
intensive property
a property that is independent of an amount of a given substance
57
when heat (q) is greater than 0 ...
heat absorbed (endothermic)
58
when heat (q) is less than 0 ...
heat released (exothermic)
59
when work (w) is greater than 0 ...
work done on the system
60
when work (w) is less than 0 ...
work done by the system
61
specific heat capacity
the amount of heat required to raise the temp of 1g of a substance by 1 C or 1K (J/g C)
62
molar heat capacity
the amount of heat required to raise the temperature of 1 mole by 1 degrees Celsius
63
in calorimetry, how do you find qcal?
qcal =Ccal * change in temp
64
in calorimetry, how do you find qrxn
qrxn = -qcal
65
enthalpy
a thermodynamic property that represent the total heat content of a system the sum of the internal energy and product of pressure and volume
66
what should you know about enthalpy and its relationship with heat at constant pressure?
The heat given off or absorbed when a reaction is run at constant pressure is equal to the change in the enthalpy of the system.
67
exothermic reaction
a reaction that released heat, q is neg, change in enthalpy is neg
68
endothermic reaction
a reaction that absorbs heat, q is pos, change in enthalpy is pos
69
standard enthalpy (delta H)
enthalpy change under standard condition
70
standard enthalpy of formation(delta H_f)
enthalpy change for forming one mole of a compound from its elements in their standard states
71
how do you find delta H reaction
sum of delta Hf (products) - sum of delta H_f (reactants)
72
Hess's law
the total enthalpy change for a chemical reaction is the same regardless of the pathway by which the reaction occurs
73
what are the monoprotic acids?
Hydrochloric acid (HCl) Nitric acid (HNO₃) Acetic acid (CH₃COOH) Hydrobromic acid (HBr) Hydroiodic acid (HI)
74
what are the diprotic acids?
Sulfuric acid (H₂SO₄) Carbonic acid (H₂CO₃) Oxalic acid (H₂C₂O₄)
75
what are the tripotic acids?
Phosphoric acid (H₃PO₄) Citric acid (C₆H₈O₇) Arsenic acid (H₃AsO₄)
76
nitrite
NO2—