Unit 2 Vocab Flashcards
(26 cards)
Cohesion
the attraction of molecules for other molecules of the same kind
Adhesion
the attraction between two dissimilar phases. ex.) Water is attracted to other substances than water
Properties of water
- Its polarity
- Its cohesive and adhesive properties
- It’s high specific heat
- It’s surface tension
Ionic Bonds
- Occurs between two atoms that are attracted to each others opposite charge
- Often occur between metals and nonmetals
Metallic Bonds
When a group of metal atoms share a cloud of valence electrons
Interstitial alloy
When metal atoms with two vastly different radii combine
Substitutional alloy
When metal atoms with similar radii combine
Covalent Bonds
- Two atoms share electrons
- Each atom counts the shared electrons as part of its valence shell
- Both atoms achieve complete outer shells
Sigma bond
All single, covalent bonds
Pi bonds
All covalent bonds with a double or triple bond
Internuclear distance
The distance between two nuclei in a molecule
Network solid
- Held together by a lattice of covalent bonds
- Very high melting and boiling point
- Very hard
Network (Covalent) Bonds
- Atoms are bonded by covalent bonds in a continuous network extending throughout the material
- Looks like a lattice
Lewis Dot Structures
Diagrams that show the bonding between atoms of a molecule, as well as the lone pairs of electrons that may exist in the molecule
Resonance Forms
- Used when there is more than one way to place double bonds and lone pairs on atoms
- Another way of drawing a Lewis dot structure
Incomplete Octets
Atoms that are stable with less than eight electrons in their outer shell
Expanded Octets
In molecules that have d subshells available, the central atom can have more than eight valence electrons, but never more than twelve.
Formal Charge
Used when there is more than one Lewis structure for a molecule, you must use formal change to determine the more likely structure
- Take the number of valence electrons for that atom and subtract the number of assigned electrons in the Lewis structure
- When counting assigned electrons, lone pairs count as two and bonds count as one
- The fewer number of atoms there are with an actual formal charge the more likely the structure will be
Molecular Geometry
The three-dimensional arrangement of the atoms that constitute a molecule.
Valence shell electron-pair repulsion (VSEPR)
a model used to predict 3-D molecular geometry based on the number of valence shell electron bond pairs among the atoms in a molecule or ion
Linear basic shape
If the central atom has 2 electron pairs, then it has sp hybridization and its basic shape is linear
Trigonal Planar basic shape
If the central atom has 3 electron pairs, then it has sp squared hybridization and its basic shape is trigonal planar; its bond angles are about 120 degrees
Tetrahedral basic shape
If the central atom has 4 electron pairs then it has sp to the third power hybridization and its basic shape is tetrahedral; its bond angles are about 109.5 degrees
Trigonal bipyramidal basic shape
If the central atom has 5 electron pairs, its basic shape is trigonal bipyramidal