Unit 3 Flashcards
(24 cards)
Pauli Exclusion Principle
2e- within same orbital must have opposite spins
Hounds Rule
Give each orbital 1e- before pairing (within same energy level)
Aufbow Principle
Fill lower energy orbitals first
Magnetic Quantum Number, Ml
Orientation of e- orbitals
Values: -l:+l
Spin Quantum Number Ms
Relates to the spin of e-
Values: +1/2 or -1/2
Principle Quantum Number, n
Relates to energy of e-
Values: integer
Secondary Quantum Number, L
Relates to the shape
Values: 0 to (n-1)
Ferromagnetic
Strong magnet
Less atoms = stronger magnetism
Paramagnetic
Weak magnet
Not noticed unless interacting with strong magnet
Hybridization
Atomic orbital -> molecular orbitals
- Shapes resemble combinations of atomic orbitals
- Make covalent bonds
Energy levels and their max e-
S^2, P^6, D^10, F^
How does a molecule hybridize?
Takes from s orbital
Fills p orbitals via hunds Rule
P orbitals extend and overlap tp make pi bonds
Sigma bonds
Overlap of SP orbital
Triple bond(?)
Bond Order
= (#bonding e-) - (#antibonding e-) / 2
AX2
SP hybridized
180
Linear
AX3
120
Trigonal Planar
SP2
AX4
SP3
109.5
Tetrahedral
AX5
sp3d
Trigonal bipyramidal
90
105
AX6
sp3d2
Octahedral
Determining its geometry
- # e- orbitals
- Hybridization of A
- Geometry
AX3E
SP3
Trigonal pyramidal
107
AX2E2
SP3
Bent
Lone pairs on geometry
Lone pairs take up less space and push away
VSEPR
Valence
Shell
Electron
Pair
Repulsion