Unit 6: Organic Chemistry Flashcards

(33 cards)

1
Q

What element is the backbone of organic chemistry?

A

Carbon.

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2
Q

Why is carbon special in organic compounds?

A

It can form stable bonds with many elements and itself.

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3
Q

What are hydrocarbons?

A

Compounds made entirely of carbon and hydrogen.

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4
Q

What are the three types of hydrocarbons?

A

Alkanes, alkenes, and alkynes.

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5
Q

What are aromatic compounds?

A

Cyclic hydrocarbons with delocalized pi electrons, e.g., benzene.

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6
Q

What is a functional group?

A

An atom or group of atoms that gives a molecule characteristic properties.

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7
Q

What is the general structure of an alcohol?

A

R–OH.

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8
Q

What is the general structure of an alkyl halide?

A

R–X, where X is a halogen.

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9
Q

What is the general structure of an aldehyde?

A

R–CHO.

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10
Q

What is the general structure of a ketone?

A

R–CO–R’.

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11
Q

What is the general structure of a carboxylic acid?

A

R–COOH.

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12
Q

What is the general structure of an ester?

A

R–COOR’.

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13
Q

What is a Newman projection used for?

A

Visualizing different conformations of molecules.

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14
Q

What is torsional strain?

A

Increased energy from eclipsed conformations.

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15
Q

What is steric strain?

A

Repulsion from atoms being too close in space.

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16
Q

What is a constitutional isomer?

A

Compounds with the same formula but different connectivity.

17
Q

What is chirality?

A

A property of a molecule that is not superimposable on its mirror image.

18
Q

What is a chiral center?

A

A carbon bonded to four different groups.

19
Q

What are enantiomers?

A

Non-superimposable mirror images.

20
Q

What are diastereomers?

A

Stereoisomers that are not mirror images.

21
Q

What is a meso compound?

A

A compound with chiral centers but is achiral due to symmetry.

22
Q

What system is used to name chiral centers?

23
Q

What system is used to name alkene stereoisomers?

24
Q

What is nucleophilic substitution?

A

A reaction where a nucleophile replaces a leaving group.

25
What is the SN2 mechanism?
A one-step substitution with backside attack and inversion of configuration.
26
What factors affect SN2 reactions?
Strong nucleophile, good leaving group, less hindered substrate.
27
What is the SN1 mechanism?
A two-step substitution involving a carbocation intermediate.
28
What factors favor SN1 reactions?
Stable carbocation, weak nucleophile, polar protic solvent.
29
What is the rate law of SN2?
Rate = k[substrate][nucleophile].
30
What is the rate law of SN1?
Rate = k[substrate].
31
What increases carbocation stability?
Alkyl substitution and resonance.
32
What are alkane conformations?
Different spatial arrangements due to rotation around C–C bonds.
33
What are the lowest-energy conformations of ethane and butane?
Staggered (anti for butane).