Vapour Flashcards

(63 cards)

1
Q

Define systems and surroundings

A
  • Surroundings are the whole universe
  • The system is part of the universe which contains a definite quantity of matter and is confined within some closed surfaces
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2
Q

Define Controll volume

A

space into which, or from which, a substance flows

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3
Q

Define an intensive property

A

does not depend on mass

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4
Q

Define an extensive property

A

depend on mass of system

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5
Q

Define a thermodynamic property

A
  • qualities that serve to describe a system.

- have a unique value when a system is in a particular state and do not depend on the previous state

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6
Q

Define a thermo dynamic system

A

quaintly if mater contained within some closed surface

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7
Q

Define a phase

A

quantity of matter that has the same chemical composition throughout

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8
Q

Define a state

A

condition as described by giving values to its properties at particular instants

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9
Q

What is a process?

A

path of successive states through which a system passes

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10
Q

How do you work out the change in property?

A

integral of d phi between phi 2 and phi 1 = phi 2 - phi 1

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11
Q

What is the quality of a liquid-vapour system

A

ratio of mass of saturated vapour to total mass in the system

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12
Q

What is the equation for quality

A

x = mg / m

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13
Q

What does first law state?

A

during any cycle that a system undergoes, the cyclic integral of the heat quals to the cyclic integral of the work

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14
Q

Draw a TV graph and state its regions

A
  • R4
  • superheated
  • quality
  • compressibility
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15
Q

What is the alternative form of first law?

A
Q(1-2) = E2 - E1 + W(1-2)
dE = delta Q - delta W
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16
Q

What does the total heat transfer equal?

A

Q = u2- u1 +m(v2^2 - v1^2)/2 + mg (z2-z1) + w2

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17
Q

What does enthalpy equal for steam?

A

h = (1-x)hf + xhg

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18
Q

What does enthalpy equal for other gases?

A

h = cpT

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19
Q

What does the volume of steam equal?

A

V = m (xvc + (1-x)vf)

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20
Q

For constant volume and specific heat, what does the change in internal energy equal?

A

u2 - u1 = integral of Cv dt between T2 nd T 1

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21
Q

For constant pressure and specific heat, what does the change in enthalpy equal?

A

h2 - h1 = integral of cp dt between T2 nd T 1

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22
Q

From first law what does h1 equal?

A

H1 = H2

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23
Q

What does the heat transfer out equal?

A

Q out = hin - hout

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24
Q

What are the relations for a isobaric process?

A
P1 = P2 = V1/T1 = V2/T2
Q = mCv(T2 - T1)
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25
What are the relations for an isothermal process?
T1 = T2 = P1 V1 = P2 V2 Q = mCp(T2 - T1) Q - W = delta U
26
What are the relations for an adiabatic process?
P1V1 ^ y = P2V2 ^ y change in U = (P2V2 - P1V1)/(1 - k) T2/T1 = (V1/V2)^k-1 T2/T1 = (P2/P1) ^k-1/k
27
What is an adiabatic process?
occurs without transfer of heat or matter
28
What are the relations for a poly tropic process?
P1V1^n = P2V2^n
29
What does the mass flow rate equal?
row 1 A 1 V 1 = m1 = m2 for a steady state
30
What are pumps?
- devices that transfer energy to a gas flowing through them - increase pressure
31
What are compressors and blowers?
- transfer energy to a gas flowing through them | - increase pressure
32
What are turbines?
- work is down by a fluid on a set of rotating blades | - pressure decreases
33
What is a nozzle?
-increase velocity for a flowing fluid by decreasing pressure
34
What is a diffuser?
-increase pressure by decreasing velocity
35
What is the equation for net work on a compressor/turbine/pump?
W = m (h2 - h1)
36
What is a heat exchanger?
devices that transfer heat from hotter body to colder body or to surroundings
37
What are the features of heat exchangers?
- velocity doesn't change - pressure drop is small - protenial energy change is negligible - no work occurs
38
What is the heat transfer equation for heat exchangers?
Q = m (h2 - h1)
39
What does the second law state?
Processes proceed in certain directions
40
What is a heat engine?
device that operates in a thermodynamic cycle and does a certain amount of net positive work through the transfer of heat from a high temperature body to a low temperature body
41
What is a heat pump?
device that operates in a cycle that requires work and that accomplishes the transfer of heat from a low T body to a high T body
42
What is the thermal efficiency of a heat engine?
n = W/Qh = 1 - Ql/Qh
43
What is the efficiency of a heat pump?
B = Ql/ W = Ql/(Qh-Ql)
44
What is the kelvin - plank statement?
It is impossible to construct a heat engine that operates in a cycle that receives a given amount of heat and does an equal amount of work
45
What is clausis statement?
It is impossible to construct a refrigerator that operates without input of work. This implies that coefficient of performance b is less than infinity
46
What is a reversible process?
a process that once having occurred can reverse and in doing so leave in changes in either system of surroundings
47
Why is a carnot cycle the most efficient?
every process is reversible
48
What are the four stages in a carnot cycle?
1) revisable isothermal expansion 2) reversible adiabatic expansion 3) reversible isothermal compression 4) reversible adiabatic compassion
49
For all revisable heat engines what is Q equal to?
integral of delta Q/ T = 0
50
For all irreversible heat engines what is Q equal to?
integral of delt Q/T less than 0
51
What is entropy?
unavailability of a system's thermal energy for conversion into mechanical work, often interpreted as the degree of disorder or randomness in the system.
52
What is the change in entropy?
s2 - s1 = integral of delta Q / T
53
In a saturated region, what is the entropy?
s = sf + xsfg
54
What is the change in entropy of ideal gasses?
s2 - s1 = cv ln(T2/T1) + k ln(v2/v1)
55
What does T ds equal?
T ds = dH - Vdp | = du + Pdv
56
What is the efficiency of a turbine?
Wa/Ws
57
What is the efficiency of a compressor?
Ws/Wa
58
What are the 4 processes in a ranking cycle?
1-2 isentropic compression (pump) 2-3 constant pressure heat addition (boiler) 3-4 isentropic Expansion (turbine 4-1 contrant pressure heat extraction
59
What is the efficiency of a rankine cycle?
n = Wt/Qb
60
How can you improve a rankine cycle?
- increase output pressure P2 or boiler outlet temp T3 - increase boiler pressure while maintain T mad and min P - however this does lead to low quality of steam and the droplets cause damage to turbines
61
What is the rankine reheat cycle
- steam passing through turbine is reheated which raises T to state 5 - steam then passes through low P section of the turbine and enters condenser at state 6 - this then reduces moisture in the turbine
62
What is the coefficient of performance for the vapour refrigeration cycle
COP = B = Q in / W in
63
Why isn't an actual vapour refrigeration cycle ideal
- pressure drops due to friction in pipes - heat transfer through pipes - pressure drops and heat transfer in condenser - fictional effects