VCE YEAR 12 DECK Flashcards

ALL OF YEAR 12 (110 cards)

1
Q

What is a fuel?

A

A substance that contains high energy content which can be easily be released and converted into other forms of energy.

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2
Q

What is stored energy called?

A

Enthalpy, or, H

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3
Q

what happens when bonds break/ form

A

break= energy is absorbed, endothermic i.e will feel cold
Form= Energy is released, exothermic i.e will feel hot.

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4
Q

Endothermic, products and reactants.

A

Products will have more energy than the reactants, energy has been absorbed. Enthalpy will be positive.

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5
Q

Exothermic, products and reactants.

A

Reactants will have more energy than products, energy has been released, will be negative.

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6
Q

Energy profile diagrams for endo and exo thermic (draw diagrams, check first book for answers)

A
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7
Q

How do you calculate activation energy?

A

highest point of diagram - where reactants start

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8
Q

How do you calculate enthalpy change

A

H of products- H of reactants.

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9
Q

Why do we need fuels?

A

We need fuels because they store energy that can be released for heat or power.

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10
Q

What are fossil fuels?

A

Fossil fuels are natural energy sources formed from the remains of ancient plants and animals over millions of years. The main types are coal, oil, and natural gas.

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11
Q

explain how we use coal

A

Coal is used to produce electricity by burning it to release chemical energy. When coal burns, it reacts with oxygen (C + O₂ → CO₂), releasing thermal energy. This thermal energy is used to heat water, creating steam that drives turbines connected to generators, producing electrical energy. In Australia, over 50% of electricity is generated this way. Instead of transporting coal directly, electricity is transmitted from power stations to homes and businesses through metal cables and wires

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12
Q

explain how we use petrol

A

Petrol is a fuel made from crude oil through fractional distillation, which separates different hydrocarbon mixtures. It contains compounds like octane. In a car engine, petrol burns (2C₈H₁₈ + 25O₂ → 16CO₂ + 18H₂O), releasing energy that creates hot gases to push the pistons and move the car. Diesel is another fuel made from a different fraction of crude oil, with slightly longer hydrocarbon chains

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13
Q

explain how we use natural gas

A

Natural gas is a fossil fuel made mostly of methane, with small amounts of other hydrocarbons. It is found in underground reservoirs, petroleum deposits, or bonded to coal as coal seam gas (CSG). Natural gas is accessed by drilling, which allows it to flow to the surface. It is burned to produce heat or electricity, commonly used for cooking, heating homes, and generating power

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14
Q

Why cant we keep using fossil fuels?

A

They are burned to produce energy but release carbon dioxide, contributing to air pollution and climate change and also non-renewable meaning they are used up quicker than they are replenished.

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15
Q

What are biofuels?

A

Biofuels are renewable fuels made from plant materials like grains, sugarcane, vegetable oils, and waste. The three main types are bioethanol, biogas, and biodiesel. They can be used on their own or blended with fossil fuels, offering a more environmentally friendly alternative to traditional fuels.

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16
Q

What is biogas and what creates it and how is it made

A

Biogas is a gas made when bacteria break down organic waste without oxygen. It mostly contains methane and carbon dioxide. Biogas is created in digesters—tanks where waste like food scraps or plant material is broken down. It can be used for heating or making electricity, often at farms or sewage plants. Since it has less methane than natural gas, it produces less energy when burned

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17
Q

what other components are there of biogas?

A

CO2, Water, sulfates, nitrates etc.

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18
Q

What is biodiesel, what creates it and how is it made?

A

Biodiesel is a renewable fuel made by reacting vegetable oils or animal fats with alcohol (usually methanol) in a process called transesterification. This reaction breaks down fats into glycerol and ester molecules, which make up the biodiesel. The biodiesel can then be used in diesel engines as an eco-friendly alternative to petroleum diesel

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19
Q

What is an Esther linkage group?

A

In the context of fats and oils, the ester linkage is the bond between the fatty acid chains (acid part) and the glycerol molecule (alcohol part). This bond is what holds the triglyceride structure together. When fats or oils undergo transesterification to form biodiesel, these ester linkages are broken and reformed with alcohol (methanol or ethanol), creating biodiesel esters

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20
Q

What is bio ethanol, what creates it and how is it made

A

Bioethanol is a renewable fuel made by fermenting sugars, like glucose, found in plants such as sugar cane, wheat, or forest waste. During fermentation, glucose is converted into ethanol and carbon dioxide. The ethanol is then purified through distillation, where it’s separated from water. Although bioethanol is a cleaner fuel, its production still requires significant energy, so it’s not fully carbon-neutral.

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21
Q

What does renewability mean?

A

Means that it can be replenished as fast as it is used.

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22
Q

Advantages and disadvantages of coal

A

Advantages-* Large reserves
* Less easily transported than
liquid or gaseous fuels
* Relatively high energy content
disadvantages-* Non-renewable
* High level of emissions

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23
Q

Advantages and disadvantages of natural gas

A

Advantages-* More efficient than coal for
electricity production
* Easy to transport through pipes
* Relatively high energy content
disadvantages-* Non-renewable
* Limited reserves
* Polluting, but less than coal
and petrol

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24
Q

Advantages and disadvantages of biogas

A

Advantages-* Renewable
* Made from waste
* Reduces waste disposal
* Low running costs
* CO2 absorbed during
photosynthesis
disadvantages- * Low energy content
* Supply of waste raw materials
limited

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25
Advantages and disadvantages of petrol
Advantages- * High energy content * Ease of transport disadvantages-* Non-renewable * Polluting, but less than coal * Limited reserves
26
Advantages and disadvantages of bioethanol
Advantages-* Renewable * Can be made from waste * CO2 absorbed during photosynthesis * Burns smoothly * Fewer particulates produced than petrol disadvantages-* Limited supply of raw materials from which to produce it * Lower energy content than petrol * May require use of farmland otherwise used for food production
27
Advantages and disadvantages of biodiesel
Advantages-Environmentally Friendly: Biodiesel produces fewer harmful emissions and is biodegradable. Renewable: Made from renewable sources like vegetable oils and animal fats. Engine Compatibility: Can be used in most diesel engines without major modifications. disadvantages-Higher Cost: Biodiesel is typically more expensive than regular diesel. Cold Weather Problems: It can gel in low temperatures, affecting performance. Food vs. Fuel: Large-scale production may compete with food crops for land and resources
28
What are the fuel sources for the body?
Carbs, Fats (lipids) and proteins.
29
What is photosynthesis?
Process plants use to turn light energy into food and oxygen. Once glucose (the food) is produced its stored away.
30
What is cellular respiration?
To release the stored energy we go through cellular respiration.
31
What are the three macronutrients?
Carbs, Fats (lipids) and proteins.
32
What are carbohydrates
Large polymers often made of glucose monomers such as starch and cellulose. During digestion these carbohydrates are broken down into glucose mono which is then transported to different cells.
33
What are fats (lipids)?
Lipids are triglycerides. Any glucose that does not get used straight away is stored as fats in the body. When the body runs out of energy it starts breaking down these fats.
34
What are proteins?
Proteins have many important functions in the body and so do not often get used up in cellular respiration. However if all carbs and fats are depleted then proteins WILL get digested and used in cellular respiration for energy.
35
compare and contrast E10 to petrol
E10- lower energy density, 46 kJ g−1 cheaper cleaner combustion can be a renewable fuel absorbs CO2 during formation to negate the impact of CO2 emissions during combustion—lower net CO2 generally safer production. Petrol- higher energy density, 48 kJg−1 - more widely distributed - less CO2 produced per km when driving
36
What are the steps in stoichiometry?
1. write a balance equation 2. find no. of moles 3.find moles of 'unknown' 4. answer question.
37
What is stoichiometry?
The calculation of reactants and products in chemical reactions.
38
What types of stoichiometry calculations are involved in combustion reactions?
* Mass-mass * Mass-volume * Volume-volume
39
What standard conditions are used for stoichiometric calculations in combustion?
25 °C and 100 kPa
40
What is a limiting reagent?
The reactant that is completely consumed during a reaction.
41
What is a reagent in excess?
The reactant that is NOT completely used up and has some left over.
42
What is the first step in determining the limiting reactant?
Write a balanced chemical reaction.
43
What does specific heat capacity (c) represent?
Energy required to change the temperature of 1g of substance by 1 °C.
44
Why does water have a high specific heat capacity?
Energy goes into breaking hydrogen bonds instead of increasing kinetic energy.
45
What three pieces of information are needed to calculate heat energy released during combustion?
* Mass of water * Change in temperature of water * Mass of the fuel
46
What type of error occurs when calculating heat energy released in combustion?
Systematic error, where the experimental value is always LOWER.
47
How can heat loss errors be minimized during combustion experiments?
* Put a lid on the container * Insulate the container * Allow oxygen in while insulating the burning fuel
48
What is bomb calorimetry?
A reaction vessel filled with oxygen immersed in water to measure temperature change.
49
What are the two types of calorimeters?
* Bomb calorimeters * Solution calorimeters
50
What is the purpose of a calibration factor (CF) in calorimetry?
To account for the heat lost and determine energy needed to change the temperature of water by 1 °C.
51
What is the formula for calibrating a calorimeter chemically?
CF = number of moles of the fuel burned / heat of combustion
52
What does a calibration graph show in calorimetry?
Perfect insulation with no energy lost after current is turned off.
53
What happens to temperature in a less-than-perfectly insulated calorimeter after current is turned off?
Temperature continues to decrease due to heat loss.
54
What is the law of conservation of energy?
Energy cannot be created or destroyed, only changed from one form to another.
55
What is energy efficiency?
Percentage of total energy converted into useful and wanted form.
56
What is the energy value of food?
The amount of energy provided by foods containing carbohydrates, proteins, and fats.
57
What is a redox reaction?
The transfer of electrons.
58
What does AN OILRIG CAT stand for
ANode Oxidation Is Loss Reduction Is Gain CATHode
59
what charge is the anode and the cathode
Anode= negative Cathode= Positive
60
What is the balanced equation for photosynthesis?
6CO₂ + 6H₂O → C₆H₁₂O₆ + 6O₂
61
What is the balanced equation for the fermentation of glucose?
C₆H₁₂O₆ → 2C₂H₅OH + 2CO₂
62
What is the balanced equation for the combustion of ethanol?
C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O
63
What is the steps in making bioethanol?
1. Plant material is pulped in water to break apart the plants and cells. 2. enzymes are used to break down the carbs into glucose. 3. Fermentation. 4. Distillation.
64
What is the difference in carbohydrate breakdown between sugar cane and forest/plant waste?
Sugar cane carbohydrates are disaccharides that dissolve easily, while forest/plant waste has cellulose which requires milling and steaming.
65
Define disaccharide.
A carbohydrate composed of two sugar molecules, e.g., sucrose.
66
Define polysaccharide.
A carbohydrate composed of long chains of sugar molecules, e.g., cellulose.
67
What role do enzymes play in the production of bioethanol?
Enzymes break down carbohydrates into glucose.
68
At what temperature is the enzyme activity for bioethanol production conducted?
Approximately 35°C.
69
What happens to enzymes when exposed to high temperatures?
They denature and stop functioning.
70
What is the process that converts glucose into ethanol?
Fermentation.
71
What is the ethanol concentration after fermentation before distillation?
Approximately 10% (v/v) ethanol solution.
72
What is the purpose of distillation in bioethanol production?
To separate ethanol from water.
73
Why is bioethanol considered theoretically carbon neutral?
Because the carbon released when burning it is offset by the carbon absorbed during crop growth.
74
Is bioethanol practically carbon neutral?
No, because energy is used in growing crops, transportation, and distillation.
75
What environmental issue does bioethanol release less of compared to petrol?
Nitrates, which contribute to acid rain.
76
Why does bioethanol have a lower energy content than petrol?
Because one carbon is partially oxidized.
77
What is a downside of ethanol being polar?
It can dissolve water from the atmosphere, causing engines to rust.
78
Fill in the blank: Ethanol is _______.
polar
79
What are redox reactions?
Simultaneous oxidation and reduction processes.
80
What does OIL RIG stand for?
Oxidation Is Loss, Reduction Is Gain.
81
What is a reductant?
The element that is oxidized (causes reduction to happen).
82
What is an oxidant?
The element that is reduced (causes oxidation to happen).
83
What is the oxidation number of neutral pure elements?
0.
84
In monatomic ions, the oxidation number is equal to the _________.
charge of the ion.
85
For ionic compounds, what must the sum of oxidation numbers equal?
The overall charge on the compound.
86
What is the oxidation state of oxygen in most compounds?
-2.
87
What is the oxidation state of hydrogen in most compounds?
+1.
88
In covalent compounds, which element keeps its negative oxidation number?
The more electronegative element.
89
What happens to the oxidation number of an element that is oxidized?
It goes up.
90
What happens to the oxidation number of an element that is reduced?
It goes down.
91
What are conjugate redox pairs?
The oxidant and reductant that can act as each other after the reaction.
92
What is the first step in balancing redox reactions in acidic conditions?
Balance key elements (anything but O and H).
93
In basic conditions, what should be added to both sides to neutralize OH-?
H+ ions.
94
What is the purpose of writing half reactions in redox chemistry?
To help identify where electrons are going.
95
What is the oxidation state of sulfur in SO2?
+4.
96
What is the oxidation state of phosphorus in PO4^3-?
+5.
97
In the example MgCl2, what are the oxidation states of Mg and Cl?
Mg: +2, Cl: -1.
98
True or False: Transition metals have fixed oxidation states.
False.
99
What do you need to ensure when writing the overall redox reaction?
Electrons must be balanced.
100
Fill in the blank: The element being oxidized ______ its electrons.
loses.
101
Fill in the blank: The element being reduced ______ its electrons.
gains.
102
What is the oxidation state of iron in Fe2O3?
+3.
103
For the compound Na2O, what are the oxidation states of Na and O?
Na: +1, O: -2.
104
Describe the bonds b/w molecules
ionic, covalent and metallic ionic= B/W metal and non metal covalent= b/w non metals metallic= b/w metals
105
A calorimeter containing 200mL of water is calibrated by passing a 3.50A current for 4 minutes at 5V. The temperature increases by 1.35oC. A 3.00g chip is burned in the calorimeter causing an increase in temperature of 0.50oC. Find the energy content of the chip in J/g.
5.18.518.... 5x10^2 Check with miss
106
A calorimeter is calibrated by passing a 3.50A current for 10 minutes at 12V. The temperature increases by the temperature was 20.0oC before the current was turned on and 21.5oC after it was turned off. A 5.00g sample of methane is burned in the calorimeter causing an increase in temperature of 16oC. Find the energy content of methane in kJ/mol.
860.16kj/mol 8.6x10^2kj Check with miss
107
A calorimeter is calibrated by burning 3.00g sample of butane in the calorimeter at SLC. The temperature changed from 20.0oC to 75.2oC. A 3.00g sample of octane is burned in the calorimeter causing an increase in temperature of 51.0oC. Find the energy content of octane in kJ/mol.
3.6218kj/mol 3.62kj/mol
108
50.00ml of a 0.200M barium hydroxide solution is mixed with 50.00ml of a 0.3M nitric acid solution. identify the excess reactant and calculate the amount in grams by which it is in excess.
Ba(OH)2 +2HNO3--> Ba(NO3)2+ 2H2O Ba(OH)2 = excess of 0.01
109
butane gas undergoes complete combustion. A reaction of this has occurred at SLC. A mixture made up of 20.0L of butane gas and 100 liters of oxygen is ignited. calculate the volume of liters of product gas. what is the total volume in L of gas left over after the combustion reaction is complete?
product = 4.73L left over= 8.82L
110