volumetric Flashcards

(42 cards)

1
Q
A
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2
Q

What is a standard solution?

A

A solution whose strength is known

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3
Q

Name the standard solution in KMnO4 Vs Mohrs salt solution titration

A

Mohrs salt

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4
Q

Name the standard solution in KMnO4 Vs oxalic acid titration

A

Oxalic acid

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5
Q

What is a primary standard?

A

A chemical substance whose standard solution can be prepared by dissolving it in water

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6
Q

Is NaOH a primary standard?

A

No

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7
Q

Are molality and molarity the same?

A

No

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8
Q

What is titration?

A

The process of adding one solution from the burette to another in the conical flask to complete the chemical reaction

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9
Q

What is an indicator?

A

A chemical substance which changes colour at the end point

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10
Q

What is the end point?

A

The stage during titration at which the reaction is just complete

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11
Q

Why must burette and pipette be rinsed with the solution they are filled with?

A

To remove any substance sticking to their sides, which would decrease the volume of the liquids

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12
Q

What is a molar solution?

A

A solution which contains one gm mole of the solute in 1 litre of solution

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13
Q

What is permanganometry?

A

Redox titrations involving KMnO4 as the oxidizing agent

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14
Q

What is a redox reaction?

A

A reaction in which both oxidation and reduction take place simultaneously

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15
Q

Identify the oxidizing and reducing agents in the reaction between KMnO4 and Mohrs salt

A

Oxidizing agent - KMnO4, Reducing agent - Mohrs salt

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16
Q

Identify the oxidizing and reducing agents in the reaction between KMnO4 and oxalic acid

A

Oxidizing agent - KMnO4, Reducing agent - Oxalic acid

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17
Q

What happens to the oxidizing agent and reducing agent in a redox reaction?

A

Oxidizing agent undergoes reduction and reducing agent undergoes oxidation

18
Q

What is the indicator used in KMnO4 titrations?

A

No indicator is used because KMnO4 acts as a self indicator

19
Q

Why does KMnO4 act as a self indicator?

A

In the presence of dilute H2SO4, excess KMnO4 imparts a pink colour to the solution

20
Q

What is the end point in KMnO4 titrations?

A

From colourless to permanent light pink

21
Q

Why are a few drops of concentrated H2SO4 added while preparing a standard solution of Mohrs salt?

A

To prevent the hydrolysis of Mohrs salt

22
Q

Why should you not use a burette with a rubber pinch cock in KMnO4 titrations?

A

Because KMnO4 attacks rubber

23
Q

Why should oxalic acid solution be heated before titration with KMnO4?

A

To speed up the liberation of Mn2+ ions and enhance reaction rate

24
Q

Why is a brown ppt sometimes observed in KMnO4 titrations?

A

Due to insufficient quantity of dilute H2SO4 leading to incomplete oxidation

25
What is the molecular formula of Mohrs salt?
FeSO4(NH4)2SO4.6H2O
26
What are acidic and basic radicals?
Radicals carrying positive charge are basic radicals; those carrying negative charge are acidic radicals
27
What type of bond is present in an inorganic salt?
Ionic bond
28
Name the coloured basic radicals
* Cu2+ * Fe2+ * Fe3+ * Mn2+ * Cr3+ * Ni2+ * Co2+
29
What is the colour of manganese salt?
Light pink or flesh colour
30
What is the colour of iron salts?
* Ferrous salts - light green * Ferric salts - brown
31
Name the radical which produces CO2 on heating
Carbonate
32
What is the chemistry of the flame test?
Valence electron of the atom gets excited and jumps to a higher level, emitting radiation in the visible region upon returning to ground state
33
What is Nessler's reagent?
A solution of mercuric iodide in potassium iodide
34
Name the acid radicals detected by concentrated H2SO4
* Cl- * Br- * I- * NO3- * CH3COO-
35
What is lime water?
A solution of Ca(OH)2 in water
36
What will happen if CO2 is passed through lime water?
It turns lime water milky due to the formation of CaCO3
37
What will happen if excess CO2 is passed through lime water?
The white ppt of CaCO3 changes into soluble calcium bicarbonate, and the milkiness disappears
38
Is there any gas other than CO2 which turns lime water milky?
Yes, it is SO2
39
What is the function of the paper pellet when heating nitrates with concentrated H2SO4?
It reduces HNO3 to NO2
40
Name group reagents for different groups
* Group 1 – Dil HCl * Group 2 – H2S in presence of HCl * Group 3- NH4OH in presence of NH4Cl * Group 4- H2S in presence of NH4OH * Group 5- Ammonium carbonate in presence of NH4Cl and NH4OH * Group 6- No specific group reagent
41
What is blue lake?
Blue litmus absorbed on white ppt of Al(OH)3 floating in colourless solution
42
Name the chemicals used for preparing H2S gas
Ferrous sulphide and dilute H2SO4