Weathering Flashcards

1
Q

Types of physical weathering

A
  • fracturing
  • dissaggregation
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2
Q

types of chemical weathering

A
  • dissolution of primary and secondary minerals
  • precipitation of secondary minerals (biomineralisation)
  • direct transformation of minerals (oxidation and reduction)
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3
Q

why do minerals chemically weather

A

when they are formed under specific P and T conditions and then the conditions are changed - they are no longer in thermodynamic equilibrium
- also the presence of water, oxygen and other reactants cause weathering

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4
Q

What are the two types of mineral dissolution

A
  1. Proton promoted dissolution
  2. Ligand promoted dissolution
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5
Q

what is a ligand

A

anions or neutral molecules that associate with a cation to form a complex - they generally donate electrons to the cations during complexation

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6
Q

What is multi-dentate ligands and are more or less teeth better

A
  • chelate or chelators
  • more teech is stronger complexation
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7
Q

what is a siderophile

A

iron lover

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8
Q

siderophoresq

A
  • multidentate organic chelators
  • made by ligand-promoted dissolution
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9
Q

what are the effects of microbes on dissolution

A

biology speeds up dissolution

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10
Q

What are direct microbe-weathering interactions

A

attachment and colonization

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11
Q

what are indirect microbe-weathering interactions

A
  • change of saturation state
  • production or consumption of CO2 or ligands
  • change of redox potential or pH
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12
Q

describe attachment and colonisation of minerals

A
  • inhibit or enhance dissolution
  • preferential attachment to nutrient sources
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13
Q

what does hyphae do

A

can drill, wedge into minerals

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14
Q

what does endolithic bacteria do

A

physically live in rock pores and increase erosion rates

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15
Q

(DIRECT microbial effects on dissolution) once microbes attach to a surface what do they do

A
  • can form etch pits
  • can preferentially remove nutrients
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16
Q

how does indirect mineral dissolution occur

A

complexation of cations in solution by ligands can lower the SI of the solution with respect to a given mineral which promotes dissolution indirectly

17
Q

Is attachment to mineral surfaces required for microorganisms to contribute to mineral dissolution

A

no