Week 1 Flashcards

Atoms, Basics of Inorg (22 cards)

1
Q

Inorganic Chem is the study of?

A

“Everything else”

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2
Q

What is included in the “everything else”

A

geometries, coordination numbers, coordination complexes, more orbitals, more electrons, solid state chemistry

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3
Q

What does the atomic # A =?

A

protons + # neutrons

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4
Q

relative mass of proton, neutron, electron

A

p= 1837
n=1839
e=1

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5
Q

1 amu = ?

A

1.661x10^-24 g

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6
Q

Isotopes of Hydrogen

A

Hydrogen (Protium)
Deuterium
Tritium

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7
Q

Relative atomic mass (Ar) of the element (in amu)

A

– the weighted mean of the mass numbers of all the isotopes of this element.
75.77 % of 35Cl and 24.23% 37Cl
Ar= 0.7577×35 + 0.2423×37 = 35.484
Ar= 0.7577x34.97 + 0.2423x36.97 = 35.4

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8
Q

How is the periodic table arranged?

A

1) Relative weight (shared by rows)

2) Reactivities (shared by columns)

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9
Q

What is an allotrope?

A

One of two or more distinct forms of an element (oxygen & ozone)

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10
Q

What do groups and periods tell about electrons

A

Period - max n (principal quantum number)

Group - number of valence electrons for s and d

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11
Q

How many electrons, protons and neutrons does 19F have?

A

Protons - 9
Neutrons - 10
Electrons 9

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12
Q

What did Louis de Broglie do?

A

“Any moving particle or object has an associated wavelength”
Found the relation between wavelength and momentum of particles
h/p=wavlength, h being Planck’s constant

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13
Q

What was Schrodinger’s thing?

A

Energy is limited to discrete values and specific for a system; an electron cannot have energy that is not one of these values
***ONLY ONE-ELECTRON particles

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14
Q

What is the principal quantum number?

A

n

This indicates SIZE of the orbital and all positive integers only

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15
Q

What is the angular momentum quantum number?

A

L

SHAPE of orbital, represented by (n-1) to infinity

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16
Q

What is the magnetic quantum number?

A

mL

SPATIAL directions and is represented from -L to +L

17
Q

What is the spin quantum number?

A

mS
direction of the spin (up or down)
Value of +1/2 or -1/2

18
Q

What is the Aufbau principle?

A

the ground state energy config of electrons starts low energy orbitals and then progressively moves higher

19
Q

What is Hund’s Rule?

A

When electrons are placed in degenerate orbitals, the ground state has as many electrons as possible in different orbitals and with parallel spin

20
Q

What does degenerate mean in chemistry?

A

of equal energy

21
Q

What is the Pauli exclusion principle?

A

No two electrons can have the same set of 4 quantum numbers (every electron has a unique ‘address’ if you will)

22
Q

What are the coinciding quantum numbers for the l orbitals?