Week 1 Flashcards
Atoms, Basics of Inorg (22 cards)
Inorganic Chem is the study of?
“Everything else”
What is included in the “everything else”
geometries, coordination numbers, coordination complexes, more orbitals, more electrons, solid state chemistry
What does the atomic # A =?
protons + # neutrons
relative mass of proton, neutron, electron
p= 1837
n=1839
e=1
1 amu = ?
1.661x10^-24 g
Isotopes of Hydrogen
Hydrogen (Protium)
Deuterium
Tritium
Relative atomic mass (Ar) of the element (in amu)
– the weighted mean of the mass numbers of all the isotopes of this element.
75.77 % of 35Cl and 24.23% 37Cl
Ar= 0.7577×35 + 0.2423×37 = 35.484
Ar= 0.7577x34.97 + 0.2423x36.97 = 35.4
How is the periodic table arranged?
1) Relative weight (shared by rows)
2) Reactivities (shared by columns)
What is an allotrope?
One of two or more distinct forms of an element (oxygen & ozone)
What do groups and periods tell about electrons
Period - max n (principal quantum number)
Group - number of valence electrons for s and d
How many electrons, protons and neutrons does 19F have?
Protons - 9
Neutrons - 10
Electrons 9
What did Louis de Broglie do?
“Any moving particle or object has an associated wavelength”
Found the relation between wavelength and momentum of particles
h/p=wavlength, h being Planck’s constant
What was Schrodinger’s thing?
Energy is limited to discrete values and specific for a system; an electron cannot have energy that is not one of these values
***ONLY ONE-ELECTRON particles
What is the principal quantum number?
n
This indicates SIZE of the orbital and all positive integers only
What is the angular momentum quantum number?
L
SHAPE of orbital, represented by (n-1) to infinity
What is the magnetic quantum number?
mL
SPATIAL directions and is represented from -L to +L
What is the spin quantum number?
mS
direction of the spin (up or down)
Value of +1/2 or -1/2
What is the Aufbau principle?
the ground state energy config of electrons starts low energy orbitals and then progressively moves higher
What is Hund’s Rule?
When electrons are placed in degenerate orbitals, the ground state has as many electrons as possible in different orbitals and with parallel spin
What does degenerate mean in chemistry?
of equal energy
What is the Pauli exclusion principle?
No two electrons can have the same set of 4 quantum numbers (every electron has a unique ‘address’ if you will)
What are the coinciding quantum numbers for the l orbitals?
s-0
p-1
d-2
f-3