Week 1 Flashcards
(63 cards)
What are the four types of bonding?
Ionic (Metal - Non-metal),
Covalent (Non metal - Non Metal)
Metallic (Metal - Metal)
Hydrogen (Hydrogen-Element)
What is the structure of crystalline materials?
Atoms arranged in periodic 3D arrays e.g. metals, ceramics, some polymers etc.
What is the structure of non-crystalline materials?
Atoms have no periodic arrangement e.g. complex structures, rapid cooling. Sometimes called amorphous
Why are ordered structures more stable?
They tend to be nearer the minimum in bonding energy
What two components make up a crystal structure?
Crystal lattice + Basis = Crystal Structure
What is the coordination number of atoms/ions/molecules?
The number of nearest neighbour or touching atoms
What is the atomic packing factor (APF)?
The ratio of the volume of atoms in a unit cell to the volume of the unit cell.
What is a point coordinate?
A lattice position in a unit cell determined by fractional multiples of atomic edge lengths.
What are Miller Indices?
The reciprocals of the intercepts of the plane of the unit cell
What are the two types of defects?
Point defects: Vacancies, Interstitials and Substantial atoms
Large scale defects: Dislocations, Grain boundaries and Surfaces
What is a vacancy?
When an atom is missing from a crystal lattice. The number of vacancies can be determined by the Boltzmann Distribution.
What is an interstatial?
When an atom formed by a vacancy stays in the crystal but not at a lattice point.
What is a substantial impurity?
When impurity atoms substitute into the atom’s original lattice, taking the lattice site of one of the atoms from the original material. The size of the SA compared to the other atoms in the lattice determines the force exerted by the substitution.
What are n-type semiconductors?
Semiconductors with an extra electron from the donor atom
What are p-type semiconductors?
Semiconductors with a hole from the acceptor atom
What are the two types of simple dislocations?
Edge distortions and Screw distortions
What are edge distortions?
Terminations of a plane of atoms in the middle of the crystal and can be interpreted as an additional half plane of atoms between two planes. In 2D only edge dislocations are possible.
What are screw distortions?
Distortions shifted out of the plane of the material so occur in 3D
What is slip?
The movement of dislocations through a material, typically in the direction of the densest crystal plane. Since dislocations only break a few bonds at a time, it uses much less energy than if the entire lattice plane was moving
What are grains?
Regions in a material of different orientations, that were formed separately or built up from strain in different directions over time.
What are monocrystalline and polycrystalline materials?
Monocrystalline: A material with a single grain
Polycrystalline: A material with lots of crystals
What is a grain boundary?
A point where two grains meet
What is a misorientation angle?
The angle between two grains that characterise grain boundaries
What are high/low angle grain boundaries?
High: MOA of less than 15 degrees and considered a collection of isolated and distinct dislocations
Low: MOA of more than 15 degrees and have a poorer fit resulting in a disordered region at the interface