Week Twelve Flashcards

(29 cards)

1
Q

liquid solution - parts

A

non voliatile solute and a liquid solvent

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2
Q

non volatile solute

A

solutes that have no significant vapor pressure

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3
Q

magnitude of boiling point elevation of solution

A

depends on the amount of particles dissolved

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4
Q

colligative properties

A

properties of solutions prepared from non volatile solutes

depend on number of particles rather than chemical identities

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5
Q

non volatile solutes - evaporation

A

dont evaporate from solution

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6
Q

Molarity

A

c= n/V

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7
Q

molarity vs temp

A

molarity decreases as temp increases

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8
Q

molality

A

molar amount of solute per mass

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9
Q

molality equation

A

b = n/m

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10
Q

mole fraction

A

number of moles in a compound divided by total number of moles of material

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11
Q

mole fraction equation

A

n(A)/ n(A) + n(B) + n(C)

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12
Q

Raoult’s Law

A

boiling point of a solution containing a nonvolatile solute is higher than that of a pure solvent
solution has lower vapor pressure than a pure solvent

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13
Q

Raoult’s Law equation

A

relationship between vapor pressure, mole fraction of solvent and vapor pressure of solvent
p(solution) = x(solvent) x p*(solvent)

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14
Q

x solvent

A

mole fraction of solvent

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15
Q

p* solvent

A

vapour pressure of pure solvent

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16
Q

Ideal solution

A

obeys raoults law
only the case
- a high dilution
- when enthalpy of mixing is small

17
Q

solutions with more than one volatile component

A

all partial pressures combine to total vapor pressure of solution

18
Q

boiling point elevation

A
delta T= i x Kb x b 
where delta T = T(solution) - T(solvent) 
kb = ebullioscopic constant 
b = molality of solution 
i = van't hoff factor
19
Q

Freezing point depression

A
delta T= i x Kf x b 
where delta T = T(solvent) - T(solution) 
kb = cryoscopic constant 
b = molality of solution 
i = van't hoff factor
20
Q

dialysis

A

dialysing membrane allows both water and small solute particles through

21
Q

osmosis

A

net shift of only solvent through an osmotic membrane

22
Q

osmotic pressure

A

pressure needed to prevent any osmotic flow when one liquid is a pure solvent

23
Q

Osmotic pressure equation

A

O = i x c x R x T
where i = van’t hoff factor
R = gas constant
c = molar concentration

24
Q

osmometer

A

measures osmotic pressure

25
isotonic
same osmotic pressure as red blood cells
26
hyper tonic
solution with higher salt concentration
27
hypotonic
solution with lower osmotic pressure
28
van't hoffs factor
shows the degree of dissociation of the solute
29
solute dissociation - vant hoffs factor equation
i = theeoret x dissociation factor x (change in temp obsered)/(change in temp theorectical)