WM Flashcards

(34 cards)

1
Q

General formula of alcohols

A

ROH

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2
Q

General formula of aldehydes

A

RCHO

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3
Q

General formula of ketones

A

RCOR

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4
Q

General formula of carboxylic acids

A

RCOOH

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5
Q

General formula of acid anhydrides

A

(RCO)2O

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6
Q

General formula of esters

A

RCOOR

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7
Q

General formula of ethers

A

ROR

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8
Q

Structural formula of aldehydes

A
O
      //
R--C
       \
        H
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9
Q

Structural formula of ketones

A
R
   \
    C == O
   /
 R
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10
Q

Structural formula of carboxylic acids

A
O
        //
R -- C
         \
        OH
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11
Q

Structural formula of acid anhydrides

A

R – C – O – C – R
|| ||
O O

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12
Q

Structural formula of esters

A

O
||
R – C – O – R

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13
Q

Structural formula of ethers

A

R – O – R

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14
Q

Suffix for alcohols

A

-ol

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15
Q

Suffix for aldehydes

A

-al

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16
Q

Suffix for ketones

17
Q

Suffix for carboxylic acids

18
Q

Suffix for acid anhydrides

A

-oic anhydride

19
Q

Suffix for esters

20
Q

Suffix for ethers

21
Q

What can primary alcohols be oxidised in to?

A

Aldehydes and then carboxylic acids

22
Q

What can secondary alcohols be oxidised to?

23
Q

What can tertiary alcohols be oxidised to?

A

Nothing. They can’t be oxidised

24
Q

How do you oxidise primary alcohols?

A

1) Gently heat ethanol with potassium(VI) diachromate solution and sulfuric acid in a flask to produce ethanal.
2) As theres lots of oxidising agent you need to remove aldehyde as soon as its formed by using a distillation apparatus.
3) To produce a carboxylic acid the alcohol has to vigorously oxidised by heating under reflux.

25
What forms when you dehydrate an alcohol?
An alkene.
26
What catalyst is used to oxidise ethanol?
Potassium(VI) diachromate solution
27
What catalyst is used to dehydrate ethanol?
Pumice stone or aluminium oxide (Al2O3)
28
How to dehydrate ethanol?
- Ethanol vapour passed over hot catalyst (pumice stone or aluminium oxide). OR - Reflux ethanol with excess concentrated sulfuric acid at 170. Ethene produced is collected over water.
29
What forms when alcohols react with carboxylic acids?
Esters
30
What forms when alcohols react with acid anhydrides?
Esters
31
How to test for phenols?
``` Use iron(II) chloride solution. Turn purple ```
32
What forms when acid anhydrides react with phenols?
Esters
33
Are phenols a strong or weak acid?
Weak
34
Do phenols and carbonate solutions react? Why?
No as sodium carbonate isn't a strong enough base to remove hydrogen ion.