Лекции.ПлатинаПаладий Flashcards by Gabriel Vladimirov

Q

Структурный тип металлов

A

Cu для всех

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Q

Pd + O2 (1атм)

A

PdO

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Q

Pt + O2

A

реакция не идёт

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Q

Pt + F2

A

PtF6

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Q

Pd + F2

A

PdF4

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Q

M + HCl

A

реакция не идёт

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Q

M + KOH

A

реакция не идёт

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Q

Pd + HNO3 (конц)

A

Pd(NO3)2 + NO2 + H2O

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Q

Pt + HNO3 + HCl

A

H2[PtCl6] + NO + H2O

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Q

Pt + HNO3 + HCl + Cl2

A

H2[PtCl6] + NO2 + H3O

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Q

M + H2

A

растворение без реакции

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Q

PtF6 + O2

A

O2[PtF6]

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Q

PtCl4 + KOH + H2O

A

PtO2*nH2O + KCl - оранжевый

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Q

Na2[PtCl6] + Na2CO3

A

PtO2 + NaCl + CO2 -коричневый

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Q

PtO2*2H2O + NaOH

A

Na2[Pt(OH)6]

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Q

PtO2*2H2O + HCl (конц)

A

H2[PtCl6] + H2O

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Q

Pt + Cl2

A

PtCl4 (300) - красно-коричневый

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Q

PtCl4 + H2O

A

[PtCl4(H2O)2]*3H2O

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Q

[PtCl4(H2O)2]*3H2O + HCl

A

H2[PtCl6] + H2O

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Q

(NH4)2[PtCl6] + NH3 (ж)

A

[Pt(NH3)6]Cl4 + NH4Cl

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Q

H2[PtCl6] + KCl

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A

K2[PtCl6]↓ + HCl

Q

H2[PtCl6] + KI

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A

PtI4↓ + HCl + KCl

Q

h2[PdCl6] + NaI

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A

H2[PdCl4] + I2 + NaCl

Q

Pd + Cl2 (500)

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A

PdCl2 -красный

PtCl4(400)

PtCl2 + Cl2 - зелёный

PdCl2 + HCl

H2[PdCl4]

H2[PtCl6] + SO2 + H2O

H2[PtCl4] + H2SO4 + HCl

PdCl2 + CO + H2O

Pd + CO2 + HCl

H2[PdCl4] + Zn + HCl

Pd -чернь

PdCl2 + NaNO3 (600)

PdO + Na2O + NaCl + N2 + o2

PdCl2 + KOH

Pd(OH)2 + KCl

Pd(OH)2 + HClO4 + H2O

Pd(ClO4)2*4H2O

Pd(OH)2 + KOH

K2[Pd(OH)4] -квадрат

H2[PtCl4] + KOH

PtO*2H2O +KCl + H2O

комплексы Pd и Pt (2+) имеют в основном

квадратное строение

H2[PtCl6] + H2O + SO2

H2[PtCl4] + H2SO4 + HCl

Pd(NH3)4]Cl2 + K2[PdCl4]

[Pd(NH3)4][PdCl4] + KCl

K2[PtCl4] + KCN

K2[Pt(CN)4] + KCl

[PtCl4](2-) + H2O

←→[PtCl3(H2O)](-)

K2[PtCl4] + C2H4 (SnCl2)

K[PtCl3(C2H4)] + KCl -соль цейзе

H2[PtCl4] + SnCl2 + KCl

K3[Pt(SnCl3)5] + HCl

Ряд трансвлияния

CN(-) →NO→PR3→I(-) → SCN(-) → Br(-) → Cl(-)→ I(-)→F(-)→OH(-)→NH3→py→H2O

H2[PtCl4] + NH3

cis[PtCl2(NH3)2] + HCl

[Pt(NH3)4]Cl2 + HCl

trans[PtCl2(NH3)2] + NH4Cl

H2[PtCl4] + Cl2 (t)

PtCl3 + HCl - Pt(+2)Pt(+4)

PtI4 (t)

PtI3 + I2 - Pt(2+)[PtI6](2-)

K2[PtCl6] + K2[PtCl4] + KCl

K5[Pt2Cl11] -димер

[PtBr2(NH3)2] + [PtBr4(NH3)2]

PtBr3(NH3)2 - полимер

K2[Pt(CN)4] + Br2 (ж) -светло - жёлтый

k2[Pt(CN)4] Br0 3 -бронзовый

Cs + Pt (200)

Cs2Pt

Cs + CsH + Pt (400)

Cs9Pt4H