πŸ‘¨πŸ»β€πŸŽ¨ Flashcards

(38 cards)

1
Q

Solubility rules 1

A

(Li+) (Na+)(K+)(Rb+)(Cs+)(NH4)

soluble no exceptions!!!

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2
Q

Solubility rule 2

A

(No3-)(C2H3O2-)(CH3COO-) are all soluble

No exceptions!!!!

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3
Q

Solubility rule 3

A

Cl- Br- I-
Are soluble
Except when bound to
Ag+ Hg2 2+ or Pb 2+

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4
Q

Solubility rule 4

A
SO4 2- is soluble except when bound to 
Ca 2+
Sr 2+
Ba 2+
Hg2 2+
Pb 2+
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5
Q

Solubility rule 5

A

All other compounds are practically insoluble

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6
Q

Soluble trends

Heat and pressure for solids

A

As heat increase solublilty also increases

Pressure has no particular change

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7
Q

Solubility trends for gases

A

As temp increases solubility decreases!!!!!!

As pressure increases solubility also increases!!!!

Think CO2 in soda pop

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8
Q

Molarity

A

Moles / L of solution

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9
Q

Mass percent

A

g of solute / g of solution x 100%

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10
Q

Dilution or concentration formula

A

M1V1=M2V2

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11
Q

Equilibrium constant expression

A

Keq = [c]^c x [D]^d / [A]^a x [B]^b

Only for aqueous or gases

aA + bB <=> cC + dD

The brackets indicate concentrations molarity

If a given equation is at equilibrium at the same temperature the keq will always be the same

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12
Q

What is a precipitation reaction

A

When two aqueous compounds forma solid

It will occurs if one of the products is a solid or insoluble

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13
Q

Complete ionic equation

A

All ions and soluble things are broken apart into ions

Insoluble things are not!!!!

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14
Q

Spectator ions

A

Ions that don’t change

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15
Q

Net ionic equation

A

Does not contain the spectator ions

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16
Q

Energy

A

The ability to do work

17
Q

Jules to calories ratio

Calorie to kilocalories

A

4.184 Jules for 1 calorie (lower case)

1 Calorie or kilocalorie = 1000 calories

18
Q

System
V
Surrounding

A

The part of the universe being studied (generally the reaction being studied)

V

Everything else

19
Q

Law of the conservation of energy

A

Energy can neither be created or destroyed

20
Q

Heat

A

Is the transfer of energy from one β€œbody” to another due to a difference of temperature

21
Q

^H or the change of enthalpy

A

Is equal to heat at a constant pressure

22
Q

Endothermic

V exothermic

A

Endo = +^ = products have more energy then reactants

Exo = -^ = products have less energy then reactants

23
Q

ColisiΓ³n theory

A

Desired product only forms if effective collision forms

The collisions gives the particles the energy they need to break up and form bonds

24
Q

Increase concentration

A

More collisions

Increase rate of reactions

25
Temp and collisions
As temp increases it will increase number of collisions and increase the energy of the reactions Right shift of the curve
26
Activation energy
E(a) The minimum kinetic energy required by a collision of reactants to create the desired products Energy of reactants to the top of the hump
27
Catalyst
Reduces the height of the hump ( Ea) which speeds up the reaction (Shifts dotted line to the right) Is not consumed instead it facilitates the reaction (HAS NO EFFECT On LE Chatliers )
28
Equilibrium
Many (not all) chemical equations are reversible - they can both forward or backwards The reaction does not stop !!!!! But when rate forward and backward are equal it has reached equilibrium Does not have to have the same amount on both sides οΏΌ
29
Le chatliers principal
Equilibrium can be shifted by changing conditions of the system If the equilibrium is stressed it will temporarily not be at equilibrium but will the shift to remove the stress so it can regain equilibrium
30
Stresses include
Change in concentrations of reactants or products (does not change keq) Change in pressure Change in temp ( exothermic written with products, endo written with reactants) Not no bad (catalyst) 😡
31
How pressure causes a shift
Only gas !!! If increased will shift from high to low to balance If decreased will shift from low to high to balance
32
Not soluble solubility rules 1 πŸ˜’
Co3 2- is not soluble except when | Bound to NA li k rb cs nh4
33
Saturated Unsaturated Supersaturate
Saturated is max amount of solute dissolved in solvent Unsat < max Super > max
34
Solute vs solvent
Solvent major Solute minor Types of mixtures Solid liquid or gas / liquid Solid / solid Liquid / liquid Polar dissolves in polar Non polar in non polar
35
Dissociation
When an ionic compound splits apart into ions in an aqueous solution
36
Hydrated
When an ion is completely surrounded by water
37
Electrolyte
Any substance that can divide into ions when placed in water
38
Not soluble rule 2
Oh is not soluble except when bound to li NA k Rb Cs NH4 Sr Ba