π¨π»βπ¨ Flashcards
(38 cards)
Solubility rules 1
(Li+) (Na+)(K+)(Rb+)(Cs+)(NH4)
soluble no exceptions!!!
Solubility rule 2
(No3-)(C2H3O2-)(CH3COO-) are all soluble
No exceptions!!!!
Solubility rule 3
Cl- Br- I-
Are soluble
Except when bound to
Ag+ Hg2 2+ or Pb 2+
Solubility rule 4
SO4 2- is soluble except when bound to Ca 2+ Sr 2+ Ba 2+ Hg2 2+ Pb 2+
Solubility rule 5
All other compounds are practically insoluble
Soluble trends
Heat and pressure for solids
As heat increase solublilty also increases
Pressure has no particular change
Solubility trends for gases
As temp increases solubility decreases!!!!!!
As pressure increases solubility also increases!!!!
Think CO2 in soda pop
Molarity
Moles / L of solution
Mass percent
g of solute / g of solution x 100%
Dilution or concentration formula
M1V1=M2V2
Equilibrium constant expression
Keq = [c]^c x [D]^d / [A]^a x [B]^b
Only for aqueous or gases
aA + bB <=> cC + dD
The brackets indicate concentrations molarity
If a given equation is at equilibrium at the same temperature the keq will always be the same
What is a precipitation reaction
When two aqueous compounds forma solid
It will occurs if one of the products is a solid or insoluble
Complete ionic equation
All ions and soluble things are broken apart into ions
Insoluble things are not!!!!
Spectator ions
Ions that donβt change
Net ionic equation
Does not contain the spectator ions
Energy
The ability to do work
Jules to calories ratio
Calorie to kilocalories
4.184 Jules for 1 calorie (lower case)
1 Calorie or kilocalorie = 1000 calories
System
V
Surrounding
The part of the universe being studied (generally the reaction being studied)
V
Everything else
Law of the conservation of energy
Energy can neither be created or destroyed
Heat
Is the transfer of energy from one βbodyβ to another due to a difference of temperature
^H or the change of enthalpy
Is equal to heat at a constant pressure
Endothermic
V exothermic
Endo = +^ = products have more energy then reactants
Exo = -^ = products have less energy then reactants
ColisiΓ³n theory
Desired product only forms if effective collision forms
The collisions gives the particles the energy they need to break up and form bonds
Increase concentration
More collisions
Increase rate of reactions