1 Organic Chemistry Flashcards
(42 cards)
organic compound
is defined as a carbon containing compound that does
not include CO,CO2, and HCN
➢ These compounds are found and obtained from living things
➢ often molecular compounds with low boiling points
➢ ex) Hydrocarbons and fuels such as fats and oils
Inorganic compounds
are compounds obtained from non-living sources
➢ CO, CO2,and HCN are inorganic compounds that contain carbon
alkanes
Saturated Hydrocarbons, non polar, fairly unreactive but combustable
Alkenes
The unsaturated hydrocarbons with double bond
Alkynes
The unsaturated hydrocarbons with triple bond
Aromatic hydrocarbons
classified on presence of a benzene ring, unsaturated hydrocarbon, bonding arrangement makes it chemically stable
Properties of Alkanes
nonpolar molecules, as there is an even arrangement of C-H bonds
throughout the molecule
ΔEN of the C-H bond is quite low and is almost nonpolar as is, while the C-C bonds are truly nonpolar
- intermolecular forces very low, relies more on London Dispersion Forces
- fairly unreactive, but are combustible
alkyl group
one or more carbon atom that forms a branch off the main chain of hydrocarbon
substituent group
an atom or group that replaces a hydrogen atom in an organic compound
Alcohols
organic compounds that contain a hydroxyl group (R-OH)
Properties of Alcohols
alcohols partially polar.
hydrogen bonding with other hydroxyl groups,
alcohols have greater boiling points
than alkanes, and can also dissolve into water,
alcohols with short carbon chains are more soluble in water than those with longer chains, as
the longer the carbon chain grows the less polar it is
❖ ability to be a solvent for both polar and nonpolar molecules, as the saturated hydrocarbon is nonpolar and the hydroxyl group is polar
hydration reaction
reaction involves an alkene and a water molecule
Dehydration
is the reverse of an addition reaction, where a water
molecule is produced but requires a catalyst to do so
ethers
product of a condensation reaction between two alcohols, Ethers are useful solvents, as they have a very polar C-O bond, and can
also dissolve nonpolar substances due to the alkyl groups
thiols
organic compounds that contain the sulfhydryl functional group
(-SH),
SH works similar to a hydroxil group becuase they have similar configurations
A property of thiols is that of smelly and strong odours (sulfur)
carbonyl group
a functional group in which a carbon is double bonded
to an oxygen atom
Aldehydes
have a carbonyl group that is bonded to at least one hydrogen atom,they have disticnt scent and odour due to carbonyl group, have dipole dipole interactiions but are less polar than alchols (since they cant form hydrogen bonds), are produced from primary alchols
Ketones
have a carbonyl group that is bonded to at least two carbon atoms on
each side of the carbonyl group
formation of aldehydes and ketones
For aldehydes and ketones to be synthesized, an alcohol must go through
controlled oxidation
Hydrogenation reactions
involve the addition of a H2
molecule to another
molecule
esters
formed by the condensation reaction between an alcohol and a carboxylic acid
properties of esters
Polarity of esters is similar to that of aldehydes and ketones as esters lack the hydroxyl group
The presence of oxygen atoms does still mean that esters have strong dipole-dipole interactions and therefore larger chains form waxy solids at room temperature but shorter chains are gases at room temperature
Less polar than carboxylic acids
Formation of carboxylic acids
is the result of further controlled oxidation of an aldehyde
Esterification
the condensation reaction in which an ester is formed from an alcohol and carboxylic acid