acid-base equilibrium Flashcards

1
Q

what is an arrhenius acid?

A

an acid that dissociates in water to form protons

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2
Q

what is a bronsted-lowry acid

A

a substance that donates hydrogen ions during a chemical reaction.

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3
Q

what is a bronsted-lowry base?

A

a substance that accepts protons

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4
Q

what is a lewis acid-base reaction?

A

a chemical reaction that forms at least one covalent bond between an electron pair donoR A+ + B- –> A-B

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5
Q

When does the bronsted-lowry theory not work?

A

when applying it to reactions involving gases and solids and complex ions are created

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6
Q

is water considered to be a nonelectrolyte?

A

yes

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7
Q

how do you calculate ph?

A

pH = -log[h+]

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8
Q

What are polyprotic acids?

A

an acid that can donate more than one hydrogen atom in an aqueous solution.

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9
Q

Examples of buffers?

A

citric acid, acetic acid

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10
Q

a buffer is an aqueous solution used to keep the pH of a solution ______

A

nearly constant

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11
Q

a buffer consists of a ___

A

weak acid and its conjugative base or a weak base and its conjusgative acid

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12
Q

buffer capacity is

A

the amount of acid or base that can be added before the pH of a buffer changes.

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13
Q

what acts as a buffer solution in blood

A

bicarbonate

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14
Q

titration is ___

A

a technique used in analytical chemistry to determine the concentration of an unknown base or acid

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15
Q

basic aspects of thermodynamics

A

internal energy of a substance is the total energy present in the particular quantity of that substance.

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16
Q

first law of thermodynamics?

A

the total energy of a system and its surroundings remain constant.

17
Q

second law of thermodynamics?

A

the change in enthalpy of a reaction is represented as shown below.

18
Q

at the end of the reaction, if energy has been given out the reaction is ___

A

exothermic

19
Q

change in H <0 means what kind of reaction?

A

exothermic

20
Q

in an endothermic reaction change in H is greater than zero, because the energy of the reactants is ___ than the energy of the products

A

less

21
Q

equation for change in H? enthalpy

A

Eproducts - Ereactants

22
Q

Hess’s law?

A

States that the enthalpy change for a chemical reaction is the same, whatever route is taken from reactants to products.

23
Q

How can you write the rate of the chemical reaction?

A

Rate constant (k) = Rate / ([A]a[B]a)

24
Q
A