1.1 EM radiation and atomic spectra Flashcards

1
Q

how can electromagnetic radiation be explained

A

in terms of waves and characterised in terms of wavelength and or frequency

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2
Q

what is the relationship between wavelength, frequency and electromagnetic radiation

A

c = f lamda

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3
Q

what is the electromagnetic spectrum

A

this is how the different types of radiation are arranged in order of wavelength

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4
Q

what are wavelengths of visible light normally expressed as

A

nanometres (nm)

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5
Q

why is electromagnetic radiation described as having a dual nature

A

it is a wave and a particle

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6
Q

why is electromagnetic radiation described as a particle

A

when it is absorbed or emitted by matter, it behaves like a stream of particles

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7
Q

what type of particles are electromagnetic radiation

A

photons

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8
Q

what are photons

A

these carry quantised energy proportional to the frequency of radiation

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9
Q

what happens when a photon is absorbed or emitted

A

energy is gained or lost by electrons within the substance

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10
Q

can the photons in high frequency radiation transfer greater or lesser amounts of energy than photons in low frequency radiation

A

greater

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11
Q

what happens when energy is transferred to atoms

A

electrons within the atoms may be promoted to higher energy levels

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12
Q

when does an atom emit a photon of light energy

A

when an excited electron moves from a higher energy level to a lower energy level

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13
Q

what does the light energy emitted by an atom produce

A

a spectrum that is made up of a series of lines at discrete (quantised) energy levels

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14
Q

what is absorption spectroscopy

A

this is when electromagnetic radiation is directed at an atomised sample

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15
Q

what is absorbed as electrons are promoted to higher energy levels

A

radiation

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16
Q

how is an absorption spectrum produced

A

by measuring how the intensity of absorbed light varies with wavelength

17
Q

what are emitted as electrons drop to lower energy levels

A

photons

18
Q

what are used to excite the electrons within atoms in emission spectroscopy

A

high temperatures

19
Q

what is an emission spectrum of a sample produced by

A

by measuring the intensity of light emitted at different wavelengths

20
Q

what is the concentration of an element related to in atomic spectroscopy

A

the intensity of light emitted or absorbed

21
Q

the energy associated with a photon of EM radiation is …

A

proportional to the frequency

22
Q

In absorption spectroscopy, as the
concentration of an ion in solution increases,
there is an increase in the

A

intensity of radiation absorbed

23
Q

In an emission spectrum of mercury, the line at 310 nm is due to

A

energy from the ultraviolet region of the electromagnetic spectrum being released

24
Q

list the electromagnetic spectrum in order of increasing wavelength

A

gamma
x ray
uv
visible
ir
microwave
radio wave