Allotropes of Carbon (pg 118) Flashcards

1
Q

What are Allotropes?

A

they are different structural forms of the same element in the same physical state.

(carbon got lots)

see diagram on page 118

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2
Q

What is Diamond made up of?

A

Diamond has a giant covalent structure, made up of carbon atoms, made up of four covalent bonds

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3
Q

why is Diamond really hard?

A

its hard as it is made up of carbon atoms that each form four covalent bonds. This makes it very hard

The strong covalent bonds take a lot of energy to break and give diamond a very high melting point.

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4
Q

Why doesn’t diamond conduct electricity?

A

because it has no free electrons or ions

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5
Q

Graphite contains sheets of what shape?

A

Hexagons

see diagram on page 118

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6
Q

In graphite each carbon atom only forms three covalent bonds, what do this create?

A

they create sheets of carbon atoms arranged in hexagons

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7
Q

Are there any covalent bonds between the hexagon layers of Graphite?

A

No. they are held together weakly, or they’re free to move over each other.

This makes Graphite soft and slippery, so it’s ideal as a lubricating material.

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8
Q

Has Graphite got a high melting point and why?

A

Yes has a high melting point - the covalent bonds in the layers need loads of energy to break.

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9
Q

How many carbon’s four outer electrons are used in bonds, in graphite?

A

Three out of four outer electrons are used in bonds, so each carbon atom has one electron that’s delocalised (free) and can move. So graphie conducts electricity and thermal energy

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10
Q

What is Graphene?

A

it is ONE layer of Graphite

It is a sheet of carbon atoms joined together in hexagons.

The sheet is just ONE atom thick, making it a two-dimentional substance

The network of covalent bonds makes it very strong. It also incredibly light, so can be added to composite materials to improve the strength without adding much weight.

(see diagram)

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11
Q

Do Graphene contain delocalised (free) electrons, and what do this mean?

A

Yes it contains delocalised electrons, (like Graphite), so can conduct electricity through the whole structure.

This mean it has the potential to be used in electronics

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12
Q

What are Fullerenes?

A

Fullerenes are molecules of carbon, shaped like closed tubes or hollow balls.

They’re mainly made up of carbon atoms arranged in hexagons, but can also contain pentagons (rings of five carbon atoms) or heptagons (rings of seven carbon atoms).

see diagrame on page 118

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13
Q

What are Fullerenes used for?

A

they can be used to cage other molecules. The fullerene structure forms around another atom or molecule, which is then trapped inside.

This could be used to deliver a drug into the body

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14
Q

Describe how Fullerenes could help make great industrial catalysts?

A

They have a huge surface area, so they could help make great industrial catalysts -

individual catalyst molecules could be attached to the fullerenes.

Fullerenes also make great lubricants.

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15
Q

Fullerenes can form nanotubes, what are these?

A

nanotubes are tiny carbon cylinders.

the ratio between the length and the diameter of a nanotube is very high.

see diagram page 118

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16
Q

Can Nanotubes conduct both electricity and thermal energy (heat)?

A

Yes

17
Q

Nanotubes have a high tensile strength, what do this mean?

A

they don’t break when they’re stretched.

18
Q

What is nanotechnology?

A

Technology that uses very small particles

19
Q

What can nanotubes be used in?

A

electronics or to stregthen materials without adding much weight, such as in tennis racket frames.

20
Q

Give some uses of fullerenes?

A

lubricants
catalysts
drug delivery
strengthen materials

21
Q

what is the properties of diamond?

A

It is the haardest known substance known natural substance.
It also chemically resistant, and has the highest thermal conductivity of any natural material.

These properties make it suitable for use as a cutting tool, and for other uses where durability is required.

22
Q

What is the properties of Graphite?

A

High melting point and boiling points
many covalent bonds are strong and substantial energy is needed to break them
good electrical conductivitsoftness. the weak forces between graphite layers allow them to slide.

23
Q

What is Graphite used for?

A

Pencils,
lubricants (greace or oil to keep engines working),
cruibles (a ceramic or metal container in which metals or other substances may be melted or sujected to very hig temperatures)
foundry facings (a carbonaceous material applied to the surface of a sand mold to prevent the molten metal from penetrating and reacting with the sand of the mold), polishes,
arc lamps,
batteries,
brushes for electric motors
and cores of nuclear reactors

24
Q

What is Graphine and what is it used for?

A

Graphene is a material with an unprecedented hardness, is ten times stronger and six times lighter than steel. It is produced from Graphite which we find in the cenre of pencils, expect that Graphene consists of a single layer of carbon atoms.

Transport medicine, electronics, energy, defence,

It has a lot of promise for additional application; anit corrosion coatings and paints, efficient and precise sensors, faster and efficent electronics, flexible dislays, solar pannels, faster DNA sequencing, drug delivery

25
Q

What properties do Fullerenes have?

A

The fullerene structure is unique in that the molecule is borderless, uncharged, has no bundaries, no dangling bonds, and o unpaired electrons.

these characteristics distinguish fullerene from other crystal structures, such as graphite or diamond, which have edges with dangling bonds and electrical charges.

26
Q

What is fullerene used for?

A

they are used in the medical field as light-activated antimicrobial agents. It is also used in several biomedical applicaitons including the design of high performance MRI contrast agents, X-ray imaging contrasts agents, photodynamic therpy and drug gene delivery.

Fullerene molecules are made of carbon atoms, and their shapes are as hollow sphere, ellipsoid or tube, spherical fullerenes are also referred to a bucky balls, they are carbon clusters, whose surface formed by 12 pentagons and any number of hexagons.

27
Q

What is a Buckminsterfullerne?

A

Buckminsterfullerene was the first fullerene to be discovered. It’s got the molecular formlar C60 and forms a hollow sphere.

see diagram on page 118