2.3 kinetics Flashcards

1
Q

what does the rate of a chemical reaction normally depend on

A

the concentration of the reactants

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2
Q

what are the orders of reaction used for

A

to relate the rate of a reaction to the reacting species

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3
Q

complete the sentence; if changing the concentration of reactant A has no effect on the rate of the reaction…

A

then the reaction is zero order with respect to A

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4
Q

when is a reaction zero order, with respect to A

A

if you changed the concentration of the reactant A but there was no effect on the rate of the reaction

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5
Q

complete the sentence; if doubling the concentration of a reactant A doubles the rate of the reaction…

A

the reaction is first order with respect to A

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6
Q

when is a reaction first order

A

when the doubling of a reactant doubles the rate of the reaction

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7
Q

what does rate =

A

k [A]

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8
Q

when is a reactant considered to be second order

A

if doubling the concentration quadruples the rate of the reaction

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9
Q

what does rate = in respect to second order

A

k [ A] ‘2

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10
Q

what is the order of a reaction

A

the power to which the concentration of that reactant is raised in the rate equation

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11
Q

what is the overall order of a reaction

A

the sum of the powers to which the concentrations of the reactants are raised in the rate equation

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12
Q

how can the order of a reaction be determined

A

only from experimental data

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13
Q

what is the reaction mechanism

A

the series of steps that a reaction occurs by

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14
Q

what is another name for the slowest step

A

the rate determining step

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15
Q

what can experimentally determined rate equations be used to determine

A

possible reaction mechanisms

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15
Q

what is meant by entropy

A

the measure of the degree of disorder of a system