more little things for unit 1 Flashcards

1
Q

what is the em spectrum in order of increasing wavelength

A

gamma, x ray, uv, visible, infrared, microwaves, radio and tv waves

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2
Q

what is the formula for calculating frequency when you know the wavelength and the speed

A

c = f lamda

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3
Q

what is meant by wave particle duality

A

em radiation can be regarded as a stream of very small particles called photons. so it can behave as both a wave and a partilcle

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4
Q

how can you calculate the energy of photons of radiation

A

e = planks constant times by frequency

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5
Q

how can you calculate energy of a wave from avogradros number, planks constant, speed and wavelength

A

e = avo times plank times speed dividied by wavelength

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6
Q

what do the dark lines on line absorption spectrum represent

A

the certain wavelengths that have been removed by absorption

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7
Q

what do the lines on line emission spectra represent

A

distinct wavelength of emitted light

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8
Q

what happens when atoms absorb energy

A

they become excited

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9
Q

what happens when energy is absorbed

A

the electrons move up to an outer shell. when they move to a lower energy level, a photon is released as a particular wavelength of light. so when electrons fall back and produce these photons, a line on emission spectra is formed from the energy difference.

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10
Q

what regions of the em spectrum does hydrogen have lines

A

uv, visible and IR

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11
Q

what is meant by ionisation energy

A

the energy difference between ground state and the convergence limit

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12
Q

how many subshells can each shell have

A

up to four.
s, p, d and f

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13
Q

what are the subshells in shell 1

A

1s

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14
Q

what are the subshells in shell 2

A

2s, 2p

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15
Q

what are the subshells in shell 3

A

3s, 3p, 3d

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16
Q

what are the subshells in shell 4+

A

4s, 4p, 4d, 4f, 5s, 5p, 5d, 5f, 6s, etc etc

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17
Q

which block does an atom with an l value of 0 belong in

A

s

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18
Q

which block does an atom with an l value of 1 belong in

A

p

19
Q

which block does an atom with an l value of 2 belong in

A

d

20
Q

which block does an aotm with an l value of 3 belong in

A

f

21
Q

which section of the periodic table is the s block

A

groups 1 and 2

22
Q

which section of the periodic table is the d block

A

transition metals

23
Q

which section of the periodic table is the p block

A

groups 3-0

24
Q

which section of the periodic table is the f block

A

lanthanides and actinides

25
Q

which block is groups 1-2

A

s

26
Q

which block is groups 3-0

A

p

27
Q

which block is transition metals

A

d

28
Q

which block is lanthanides and actinides

A

f

29
Q

what shape are s orbitals

A

spherical

30
Q

in what order do orbitals fill up

A

1s, 2s, 2p, 3s, 3p, 4s, 3d, 4p, 5s, 4d, 5p, 6s, 4f, 5d, 6p, 7s, 5f, 6d, 7p, 8s

31
Q

are 4s electrons lost before or after 3d electrons during ionisation to positive ions

A

before

32
Q

what is the oxidation number in a free or uncombined element

A

0

33
Q

what is the oxidation number in single atom ions

A

equal to the charge on the ion

34
Q

what is the oxidation number for hydrogen

A

+1

35
Q

what is the oxidation number for oxygen

A

-2

36
Q

what must the algebraic sum of all the oxidation numbers in a molecule be

A

0

37
Q

what must the algebraic sum of all the oxidation numbers in polyatomic ion be equal to

A

the charge on the ion

38
Q

how many pairs of electrons do monodentate ligands donate

A

1

39
Q

how do you name a complex

A

metal symbol first. neg ligands next. neutral ligands next. overall charge written after the square brackets

40
Q

what is a complex

A

a central metal ion surrounded by ligands

41
Q

how do you name a negative ligand

A

ide becomes ido.
ate becomes ato.
ite becomes ito.

42
Q

how do you name a neutral ligand

A

water is aqua
ammonia is amine
co is carbonyl

43
Q

why can transition metals absorb light

A

because photons excite electrons in the lower d orbitals up to a higher energy d orbital

44
Q

why do transition metals make good catalysts

A
  • they can form a variable number of bonds due to the availabliity of unoccupied and hal fiflled d orbitals
  • this allows easier formation of intermediate complexs
  • this provides reaction pathways of lower energy to proceed