12-15 Flashcards

1
Q

hunds rule

A

electron fill in seperate orbitals before they start to share

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2
Q

aufbau

A

lowest energy

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3
Q

pauli

A

no electron has same four quantum numbers

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4
Q

principle

A

the distance of electron to nucleus

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5
Q

orbital

A

the probabaility of where an electron is found

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6
Q

electrons behave like

A

waves, they are spread out in the atom

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7
Q

orbitals can be

A

wave functions

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8
Q

what is used to denote wave function

A

psi

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9
Q

wave function

A

x, y, z psi

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10
Q

electron density

A

greek rho

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11
Q

regions where electrons are likely to be found have

A

high electron density

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12
Q

regions where electrons are unlikely to be found have

A

low electron density

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13
Q

how to calculate electron density

A

sqaure wave function

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14
Q

how to calculate finding electron in a given small volume

A

volume * square of wave function

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15
Q

orbital energy for only h atoms rely on

A

principal quantum number

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16
Q

orbital energy in H are

A

degenerate, if they have the same n number for each orbital

17
Q

as n increases

A

energy increases of orbital. this is because the nucleus is positive and the electron is negative.

Why do electrons further from the nucleus have more energy? The farther away from the nucleus an electron is, the less effect the opposite charge (from the nucleus) has on the electron, ergo increasing its electrostatic/potential energy. Electrons closer to the nucleus also shield the outer electrons from some of the effects of the nucleus.

18
Q

orbital angular momentum quantum number

A

n-1

19
Q

nodes

A

a node in an orbital is a region between opposite phases where electron density is 0.

20
Q

angular nodes

A

angular nodes are node we encounter as we go around the orbital.

21
Q

angular nodes are equal to

A

l quantum number

22
Q

magnetic quantum number

A

distingushes the orientation of the orbitals

23
Q

s, p, d, f are

A

orbital types

24
Q

alpha spin

A

0.5

25
Q

beta spin

A

-0.5

26
Q

quantum spin number

A

always equal 0.5 it can equal up and down

27
Q

principal

A

size and energy

28
Q

the shape of the orbital depends on

A

distance from nucleus

29
Q

Radial dependance graph

A

distance from radius as x against the wavefunction

30
Q

why can wavefunction go up and down

A

positive and negative phase

31
Q

the wave

A

decays to 0. may go up and down