1. Molecular Basics Flashcards

1
Q

how many single bonds, double bonds and triple bonds can Carbon form

A

single = 4
double = 2
triple + single bond

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2
Q

how many single bonds & double bonds can oxygen form

A

single = 2
double = 1 + 2 pairs of unshared e-

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3
Q

how many bonds and what type can Hydrogen form

A

1 single bond

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4
Q

how many single bonds, double bonds and triple bonds can Nitrogen form

A

single = 3

can also form double or triple bonds depending on the compound

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5
Q

what is the valence of carbon

A

4

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6
Q

what is the valence of Oxygen

A

2

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7
Q

what is the valence of hydrogen

A

1

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8
Q

what is the valence of nitrogen

A

3

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9
Q

what is the valence of nitrogen

A

3

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10
Q

what do lewis structures show

A

all atoms and bonds in molecule

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11
Q

what does each bone represent in a lewis structure

A

represents the sharing of 2 e- between respective atoms

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12
Q

what do partially condensed structures show

A

dont show bonds between C & H, atoms are drawn beside each other

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13
Q

what do condensed structures show

A

dont show any single bonds, only shows structural arrangement of atoms

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14
Q

in 3D bond line structures what do wedges represent

A

group coming out of page towards you

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15
Q

in 3D bond line structures what do dashes represent

A
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16
Q

what does a positive charge on an oxygen atom indicate in terms of number of bonds and lone pairs

A

3 bonds and one lone pair of e-

17
Q

what does a negative charge on an oxygen atom indicate in terms of number of bonds and lone pairs

A

one bond and 3 lone pairs

18
Q

what does no charge on an oxygen atom indicate in terms of number of bonds and lone pairs

A

2 bonds and 2 lone pairs

19
Q

what does a positive charge on an nitrogen atom indicate in terms of number of bonds and lone pairs

A

4 bonds and no lone pairs

20
Q

what does a negative charge on an nitrogen atom indicate in terms of number of bonds and lone pairs

A

2 bonds and 2 lone pairs

21
Q

what does no charge on an nitrogen atom indicate in terms of number of bonds and lone pairs

A

3 bonds and one lone pair

22
Q

what are resonance structures used to show

A

the spread of positive charge, combination of different structures in a linear fashion

23
Q

what are the 3 rules for determining significance of resonance structures (full explanation)

A
  1. structures with minimal charges are more significant than structures with several charges
  2. structures that have a full octet of e- on their atoms are more significant than those that do not have a full octet
  3. if 2 carbon atoms in a structure have opposite charges, this structure is generally insignificant
24
Q

what are the 3 rules for determining significance of resonance structures (brief summary)

A

minimal charges, full octet of atoms and doesnt show carbon atoms with opposing charges = significant

25
Q

how many atoms/groups are sp3 orbital carbons connected to

A

4

26
Q

what is the angle between atoms/groups in a sp3 orbital carbon

A

109.5 degrees

27
Q

how many atoms/groups are sp2 orbital carbons connected to

A

3

28
Q

what is the angle between atoms/groups in a sp2 orbital carbon

A

120 degrees

29
Q

how many atoms/groups are sp orbital carbons connected to

A

2

30
Q

what is the angle between atoms/groups in a sp orbital carbon

A

180 degrees

31
Q

what are cis and trans isomers

A

same molecular formula and same structural formula but the atoms are arranged differently about the C=C double bond