12.6 to 12.7 (Exam 1) Flashcards
(13 cards)
What is thermochemistry?
The study of heat transfers during chemical reactions
What is the sign on energy transferred out of the system?
-
What is the sign for /\H for an exothermic reaction?
-
What is the sign for /\H for an endothermic reaction?
+
What does Hess’s Law state?
If two or more chemical reactions are added to form another chemical equation, the corresponding enthalpies of reaction must be added
What is the standard state for solids and liquids?
A pressure of 1 atm at a specified temperature
What is the standard state for gases?
A pressure of 1 atm at a specified temperature and the exhibition of ideal gas behavior
What is the standard state for dissolved species?
A 1 M solution at a pressure of 1 atm and specified temperature, with the exhibition of ideal solution behavior
What is the enthalpy of a chemical element at 298.15 K (25* Celsius)?
0
If multiple forms of an element exist in the standard state, which one is assigned an enthalpy of 0?
Whichever is the most stable
What is standard enthalpy of formation (/*Hf)?
The enthalpy change for the reaction that produces one mole of the compound from its elements in their stable states
What is bond enthalpy?
The enthalpy change when a bond is broken in the gas phase
What is kept constant in an isothermal process?
Temperature