Sulfur Cycle Flashcards

1
Q

Why are sulfur transformations complex?

A
  • due to variety of oxidation states
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2
Q

How do sulfur cycle reactions occur?

A

Chemically and biologically

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3
Q

Where are sulfate mineral reservoirs?

A

Rocks and oceans, sediments

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4
Q

What is the rotten egg smell when stepping in waterlogged soil? What are the bubbles?

A

Sulfur oxide (H2S)
methane

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5
Q

Where does bacterial oxidation of sulfide occur?

A

interfaces of oxic/anoxic areas

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6
Q

Where are hyperthermophiles found?

A
  • in thermal vents (lots of sulfur)
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7
Q

Define phototrophic

A

light must be present to carry out reactions

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8
Q

Define thiobacillus, where are they found?

A
  • elemental sulfur oxidizer and sulfur transformer
  • found in acidic environments
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9
Q

Are chemolithotrophs organic or inorganic?

A
  • inorganic
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10
Q

Where does H2S get trapped and oxidized in the cycle?

A

in anoxic area, oxidized in anoxic conditions and feeds other parts of the cycle

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11
Q

What is S0?

A
  • readily oxidized by sulfur-oxidizing bacteria to form sulfate and H2
  • elemental sulfur
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12
Q

What is an example of a sulfur oxidizer?

A

Thiobacillus

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13
Q

What happens to conditions when S0 is oxidized?

A

acidification (pH drop)

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14
Q

How does S0 form H2S? What is this carried out by?

A
  • via anaerobic reduction
    = hyperthermophilic archaea
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15
Q

What causes a drop in pH during S0 oxidation?

A

accumulation of H+

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16
Q

What is an example of where S0 oxidation takes place?

A
  • hydrothermal vents - very limited O2
17
Q

Where is dimethyl sulfide found? what does it do?

A

Anoxic environments (buildup in waterlogged areas)
- snips methyl groups and creates methane

18
Q

What does dimethyl sulfide serve?

A
  • as substrate for methanogenesis
  • in CO2 fixation by phototrophic purple bacteria