Gas Laws Flashcards

1
Q

Gas

A

a substance that has no well defines boundary but diffuses rapidly to fill the container in which it is placed

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2
Q

boyles law

A

at constant temperature the volume of a fixed mass of gas is inversely proportionate to its pressure

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3
Q

charles’ law

A

at constant pressure the volume of a fixed mass of gas is directly proportional to its temperature as measured on the Kelvin scale

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4
Q

Gay lussacs law of combining volumes

A

in a reaction between gases the volumes of the reacting gases and the volume of any gaseous products are in the ratio of small whole numbers provided the volumes are measured at the same temperature and pressure

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5
Q

avogadros law

A

equal volume of gases contain equal number of molecules under the same conditions of temperature and pressure

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6
Q

ideal gas

A

a gas that perfectly obeys all of the assumptions of the kinetic gas theory under all conditions of temperature and pressure

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7
Q

real gas

A

different from an ideal gas because forces of attraction and repulsion do exist between molecules and the volume of the molecules is not always negligible

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8
Q

How do you convert from °C to Kelvin?

A

Add 273 to the amount of °C

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9
Q

How to convert from cm^3 to m^3

A

Add x10^-6 to the end

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10
Q

How to convert from cm^3 to Litres

A

Cm^3 divide by 1000

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11
Q

How to convert from litres to m^3

A

Litres divided by 1000

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12
Q

How to convert from kPa to Pa

A

Multiply by 1000

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13
Q

What are the conditions of S.T.P

A

Temp- 273 K
Pressure- 100kPa
Molar volume- 22.4L

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14
Q

What are the conditions of R.T.P

A

Temp- 298K
Pressure- 100kPa
Molar volume-24L

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15
Q

What does STP stand for

A

Standard temperature and pressure

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16
Q

What does RTP stand for

A

Room temperature and pressure

17
Q

Explain boyles law

A
  1. Expanding the container increases volume and decreases the pressure
  2. Making the container smaller decreases the volume and increases the pressure
18
Q

What gases follow boyles law

A

For all gases

19
Q

What unit does temperature have to be in for Charles’ law to be true?

A

When temperature is in KELVIN

20
Q

What is the combined gas law formula?

A

(P1)(V1)/(T1)=(P2)(V2)/(T2)

21
Q

What are the important things to remember when using the combined gas law formula

A

Gas 1+2 have to all have the same unit
Temperature HAS to be in KELVIN

22
Q

How do you find the volume of a gas?

A

Moles x molar volume
(Molar volume is either stp or rtp)
Volume must be in L

23
Q

Give 2 assumptions of the kinetic gas theory

A
  1. No attractive or repulsive forces between molecules/point particles of the gas
  2. Gas molecules are so small and so far apart that the actual volume of the point particles is negligible compared to the space that they occupy
  3. The average Kinetic energy of the molecules in a gas is directly proportional to the temperature
24
Q

Limitations of the kinetic gas theory

A
  1. All real gases do experience tiny attractive/repulsive forces between molecules. Some molecules have permanent dipoles and form dipole dipole or hydrogen bonding forces. Or if it is non polar it will form van dear waals
  2. It is not true that the volume is negligible compared to the space particles occupy. Under high pressure when molecules are forced close together, their volumes are not negligible compared to the space they occupy
25
Q

Under what conditions do real gases behave like ideal gases

A

At low pressure when the molecules are spaced far apart
At high temperature when the molecules are moving rapidly, thus minimising intermolecular forces

26
Q

What is the ideal gas law equation

A

pV= nRT

27
Q

What do you use the ideal gas law for

A

To find the volume of a gas when we are not given at stp or rtp in a question

28
Q

What units must all the parts of the ideal gas law be in

A

P= Pa NOT kPa
V= m^3
R= 8.314 ( on exam cover)
n=moles
T= Kelvin
You have to convert to these most of the time

29
Q

Why does the temperature have the be in Kelvin for Charles law?

A

If you plot line on the Celsius scale line will not pass through the origin meaning the volume of gas would not be directly proportional to the temperature

30
Q

diffusion

A

the random spreading out of molecules from an area of high concentration to areas of low concentration to fill a container