13.5 Polymerisation in alkenes Flashcards

(41 cards)

1
Q

Definition of polymer

A

long chain molecule made from of repeat units of smaller molecules joined together

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2
Q
A
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3
Q

Definition of monomer

A

small molecules that join together to make polymers

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4
Q

Definition of addition polymerisation

A

Formation of long chain molecules from lots of small molecules join in together with no other products
OR
Formation of a very long molecular chain, by repeated addition reactions of many unsaturated alkene molecules

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5
Q

What molecules undergo addition polymerisation?

A

alkenes

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6
Q

What is a repeat unit?

A

The specific arrangement of atoms in the polymer molecule that repeats over and over again

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7
Q

How is a repeat unit written?

A

In square brackets, with the letter n aftwr

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8
Q

What does the letter n show in addition polymerisation?

A

Shows that there is a large number of repeats

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9
Q

What is the general equation for addition polymerisation?

A
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10
Q

How are addition polymers named?

A

poly(name of molecule)

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11
Q

What conditions does addition polymerisation occur in?

A

high temperatures, high pressure

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12
Q

What are uses of poly(ethene)?

A

supermarket bags, shampoo bottles, children’s toys

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13
Q

What is the general equation for addition polymerisation of ethene?

A
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14
Q

What is the general equation for addition polymerisation of propene?

A
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15
Q

What is the monomer, polymer structure and repeating unit of poly(propene)

A
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16
Q

What is the general equation for addition polymerisation of chloroethene?

A
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17
Q

What is poly(chloroethene)?

18
Q

What are the properties and uses of poly(propene)?

A

Properties: strong
Uses: Children’s toys, crates, fibres for rope, carpet

20
Q

What are the uses of poly(phenylethe)?

A

Packing material, food trays and cups due to thermal insulting properties

21
Q

What are the uses of poly(tetrafluoroethene) or teflon?

A

Coating for non-stick pans, permeable membrane for clothing, shoes, cable insulation

22
Q

What is the monomer and polymer of propene?

23
Q

What is the monomer and polymer of phenylethene (styrene)?

24
Q

What is the monomer and polymer of tetraflurothene?

25
What are the benefits to the environment of biodegradable and photodegradable polymers?
-leave no visible or toxic residue -used to make packaging, electronics, fuel-efficient and recyclable vehicles
26
What are the ways of disposing waste polymers?
-Recycling -Combustion for energy production -Use as organic feedstock
27
Why is PVC disposable a concern?
Not sustainable, when burnt it releases hydrogen chloride (HCl) which is corrosive and other pollutants like toxic dioxins
28
Why are polymers suitable for storing food and chemicals?
Lack a reactivity
29
How does recycling polymers help the environment?
Conserves finite foil fuels, decreases amount of waste in landfill
30
How is PVC recycling been improved?
Solvents are used to dissolve the polymer and high-grade PVC is then recovered by precipitation from the solvent, solvent is then used again
31
How can polymers which are difficult to recycle be exposed of?
They are incinerated to produce heat, generating steam to drier a turbine producing electricity
32
What is an advantage of feedstock recycling?
It is bale to hand unsorted and unwashed polymers
33
What is feedstock recycling?
Chemical and thermal process that can reclaim monomers, gases or oil from waste polymers
34
How are biodegradable polymers broken down?
By micrograms into water, CO2 and biological compounds
35
How are photodegradable polymers broken down?
Polymers are weakened by absorbing light to start the degeneration
36
What are examples of biodegradable polymers?
Starch, cellulose, contain additives
37
What are photodegradable polymers?
Oil-based polymers
38
39
What is the problem with using combustion to dispose of polymers?
Produces toxic gases such as CO, HCl
40
What is an advantage of using polymers made from natural foods?
Reduces the dependency on finite resources ,Photodegradable, Biodegradable
41