Ch301 Test #1 Ep 5-8 Flashcards

(58 cards)

1
Q

What is the photo electric effect

A

Shining light (usually UV) onto metal surface in vacuum could cause e- to be ejected from metal surface if it’s on or above the metals threshold frequency

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2
Q

What is the work function

A

Amount of E required to remove ONE e- from metals surface in a vacuum

always a small amount of E no matter the metal

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3
Q

If hv<Φ

A

Then there is not enough E to remove an e- from the metal

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4
Q

If hv> Φ

A

Then there is enough E to remove an e- from the metal in the vacuum

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5
Q

What happens if you increase the brightness of the light

PE

A

Ejects more electrons but they have the same KE as b4

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6
Q

What happens if you increase the freuqncy (hertz) of the light?

A

Same number of electrons are ejected but with a higher KE

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7
Q

Einstein explanation of light

A

Light acts like tiny particles or wave packets, each packet ejected one e-

Einstein is wrong and right because light doesn’t only behave like a particle

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8
Q

What’s is the relationship w E of light and frequency

A

Higher frequency means the light particle has more E

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9
Q

Which has greater E

Red or blue light

A

Blue light

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10
Q

Ephoton equation

A

Ephoton = Φ + KEelctron

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11
Q

In the PE effect high E photons can do what?

A

Remove an e- from almost anythang whether in a vacuum or not

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12
Q

Wave particle duality

A

Energy waves can also be energy particles

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13
Q

Louis Debroglie theory

A

Matter particles can also be matter waves

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14
Q

Debroglie equation

A

λ=h/mV

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15
Q

Schrödinger theory

A

Created math model that treats e- as waves instead of particles,

A standing matter wave around the nucleus

Each following subshell has higher E than before

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16
Q

What’s do Energies tell us(Schrödinger equaiton)

A

E of e-

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17
Q

What do wave functions tell us?(Schrödinger equation)

A

Tell us probability of finding the e- at a given position

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18
Q

What are the regions in space e- are found

A

Orbitals

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19
Q

Can we ever know exactly where e- are?

A

No but we can find probability of finding e- at any given distance from the nucleus

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20
Q

S orbital shape

A

One big circle

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21
Q

P orbital shape

A

2 half circles

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22
Q

D orbitals shape

A

4 quarter circles

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23
Q

Graph of likelihood of finding the e- vs the distance from the nucleus is called…

A

Radial distribution function

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24
Q

What are quantum numbers

A

The “address” of the e-

25
What’s re the 4quantum numbers
N l ml ms
26
What’s does the quantum number l tell us
The shape of each orbital for each e-
27
Pauli exclusion principle
In a given atom no 2 e- can have the same set of 4 quantum numbers An orbital can hold a max of 2 e- and they must have opp spins
28
What does n quantum number determine
Size and E of orbital
29
What does ml quantum number determine
Orientation of orbital Distinguishes between diff orbitals in same sub shell
30
What does ms quantum number determine
Spin on the e-
31
When does it take more E to remove an e-?
When its from a metal w a higher min threshold frequency
32
Altering light brightness alter
Number of e-
33
Altering light frequency alters?
KE
34
When choosing solutions for electron config we f always chose
Lowest E solutions
35
What is l for s subshell
0
36
What is l for p subshell
1
37
What is l for d subshell
2
38
What is l for f subshell
3
39
How to find the ml, magnetic quantum number?
Any Values ranging from -l to +l 0 always works
40
How to find spin magnetic, ms?
Always be consistent Make up arrow positive and down arrow negative
41
Energy level ,n,for s block?
Same as row that e- is in
41
Energy level ,n,for p block?
Same as row that e- is in
42
Energy level ,n,for d block?
1 less than row that e- is in in d block
43
Energy level ,n,for f block?
2 less than row that e- is in in f block
44
What happned if you change energy of light
Increased KE
45
What happens if you increase the intensity
Same KE but more electrons ejected
46
Zeff = ?
Z(atomic #) - number of inner shell e-
47
Formula speed of wave
Wavelength times frequency
48
What is MHz
Megahertz is 10^6 hertz
49
Define quantized
Can only have specific values, like atomic line emission spectra
50
What does low frequency mean
Hi wavelength
51
only use final and initial for??
Change in e, Otherwise smallest is first then largest
52
When electrons are removed in IE , in which order are they removed?
Highest to lowest E
53
Which has higher E d subshell or s subshell
S subshell
54
3s and 3p subshells are degenerate in E for
One electron systems
55
What is the visible light wavelength range in nm
400-700 nm
56
If a full spectrum of vis light passes thru a cloud cold hydrogen atoms before reaching earth, what would the vis spectrum from the star look to earth
Full vis spectrum w 4 wavelengths and rest of spectrum missing
57
Mole concept is important to chem because
It allows us to count atoms and molecules by weighing macroscopic amounts of material