unit 3 quiz Flashcards

(52 cards)

1
Q

london dispersion

A

for all molecules

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2
Q

dipole dipole

A

polar molecules
asymmetrical molecules w/ only nonmetals

includes hydrogen bonding

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3
Q

hydrogen bonding

A

strong type of dipole dipole

hydrogen itself has to bond with either F O N

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4
Q

strong but difficult to compare IMF

A

ionic and metallic

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5
Q

ionic

A

metals w nonmetal

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6
Q

metallic

A

only metals

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7
Q

covalent network

A

strongest IMF

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8
Q

dipole induced dipole

A

one substance polar and the other is non polar

the IMF increases w magnitude of dipole of polar molecule and with polarizabiity of nonpolar molecule

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9
Q

ion induced dipole

A

nonpolar substance w ion

strength increases w larger charged ions(smaller radius) and more polarizable molecules

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10
Q

ion dipole

A

polar substance w ion

stronger than dipole dipole
strength increases w large charged ions(smaller size) and more polar molecules

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11
Q

what properties increase with IMF

A
boiling/melting/freezing pt
enthalpy of fusion/vaporization 
viscosity
surface tension
lattice energy
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12
Q

what properties decrease with IMF

A

vapor pressure

solubility(depends on polarity of solvent and solute)

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13
Q

what are the 4 basic types of solids

A

ionic solids
covalent networks of solids
molecular solids
metallic solids

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14
Q

due to strong interactions between ions

A

ionic solids have high vapor pressure high melting pts and high boiling pts

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15
Q

electrostatic attraction

A

attraction between positive and negative ions

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16
Q

why are ionic solids brittle

A

due to repulsion of like charges when one layer of solids slides across the other layer

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17
Q

when do ionic solids conduct electricity

A

(when charged which is a given)

web ions are mobile
when ionic solid is melted
or dissolved in water or another solvent

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18
Q

covalent networks have atoms at their lattice pts with

A

strong directional covalent bonds

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19
Q

covalent solids are only formed of

A

nonmetal

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20
Q

how are covalent solids characterized

A

hardness
strength
high melting point

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21
Q

molecular solids are composed of

A

distinct individual units of covalent lay honded molecules attracted to each other through weak IMF

22
Q

do molecular solids conduct electricity

why or why not

A

no becuase their valence e- are tightly held w/in the covalent bonds and line pairs of each constituent molecule

23
Q

metal alloys conduct with what

A

sea of electrons

24
Q

metallic solids are packed together and bonded to each other

A

equally in all directions

25
ionic properties
``` poor conductors of heat and electricity high melting pt hard but brittle relatively dense dull surface ```
26
molecular properties
``` poor conductors of heat and electricity low melting pt soft low density dull surface ```
27
covalent network peoperties
``` poor condusctors of heat and electricity high melting point very hard and brittle low density dull surface ```
28
metallic properties
``` good conductors of heat and electricity melting points depend on e-config ductile and malleable high density usually lustrous ```
29
When deciding which compound will have a lower boiling point consider
First consider IMF then if the same consider Number of electrons, polarizability
30
Increasing IMF forces by structure diagrams
Consider surface area, more branches is less polarizable
31
Drawing sand mixed with water
Sand on bottom, water on top Sand particles close together, water particles further apart Consider particle size, atomic radius, also
32
Why do gas particles follow the ideal gas law
They don’t have IMF
33
Low pressure vs high pressure particles
Low pressure: particles far part | High: particles close together
34
Partial pressure formula
Add up the moles of the mixture of each element of gas Divide each element by the total Multiply by the total pressure stated in the problem
35
total pressure formula
PV=nRT
36
What is the n in PV=nRT
Moles
37
What is the R in PV=nRT
0.0821
38
Kinetic molecular theory
The size of a gas particle is so small domeñare w/ distance between particles that volume is ignored Gas particles are in constant random motions, bumping off walls Gas particles have no attractive or repulsive force
39
Draw a 1L vessel containing 2 moles of H2 at 200K
Since it’s about 2 moles, consider a number easily multiplied by 2 like 3 Remember more heat means faster movement which means more pressure
40
How to find higher average molecular speeds
Consider grams or mass of elements The lighter the weight, the faster it moves
41
if your doing stoic and you have O2 how would you write the fraction
32g O/ 1 mol O2 Or 1 mol O2/32g O
42
When are gases more ideal
When pressure is low and temp is high
43
Boyles law
As gas pressure increases, volume decreases P1V1 = P2V2
44
Charles law
As the temperature decreases, the volume decreases V1/T1 = V2/T2
45
Avogadros law
As the number of moles of gas increase, the volume increases | V1/N2 = V2/N2
46
What forces increase with IMF strength(3)
Melting point, surface tension, heat of vaporization
47
What forces decrease with IMF (2)
vapor pressure, volatility(cause of evaporating)
48
avogadro’s number
6.02*10^23
49
how many torr in 1 atm
760 torr
50
carbon di sulfide formula
CS2
51
fluorometham formula
CH3F
52
ammonia vs ammonium
NH3 vs NH4