13th Group Flashcards
(23 cards)
Which prop of 13G ⬆️ down the group?
Density, Ionic and covalent radii, stability
Which prop ⬇️ down the group?
BP
Name the 13thG elements?
B, Al, Ga, In, Tl
Atomic radius and reason
B<Ga<Al<In<Tl
Poor screening of 3d10 electron
⬆️
EN
Al<Ga<In<Tl<B
⬆️
MP
B>Al>Tl>In>Ga
B- strong crystalline lattice
⬇️
IE
B>Tl>Ga>Al>In
Trick: Bombay to goa all are indian
OS
+3, +1
Which is acidic? Amphoteric? Basic?
Acidic- B
Amphoteric- Al, Ga
Basic- In, Tl
E+ O2 gives
E2O3
E+N2 gives
EN
Which element does not react in crystalline form?
B
Which element forms thin oxide layer?
Al
Al2O3
Which Amorphous elements forms oxides and nitrides
B and Al
Which element doesn’t react with halogen?
Tl
How is B occured in nature?
H3BO3- Orthoboric acid
Na2B4O7. 10H20- borax
Na2B4O7. 4H20- Kernite
Al203. 2H20- Bauxite
Na3AlF6-Cryolite
Occurence order
O>Si>Al
Acidic strength?
F<Cl<Br<I
Isotopes of B
10B and 11B(81%)
Bcl3 and Alcl3 acts as Lewis acid because?
Incomplete octet
Complex formation is due to:
Small size, high charge density, available of d orbital
Which element have very low MP and high BP
Ga
Which element have high MP and is hard
B