Chemistry Flashcards

1
Q

anything that has mass and occupies space

A

matter

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2
Q

amount of matter contained in an object

A

mass

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3
Q

amount of space occupied by matter

A

volume

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4
Q

4th state of matter, also called liquid crystal, mesophase, supercritical fluid

A

plasma

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5
Q

this is strongly influenced by electric and magnetic fields with a hot ionized gas consisting of approximately equal numbers of positively charged ions and negatively charged electrons

A

plasma

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6
Q

5th state of matter, also called a super atom, and has many properties of a super fluid

A

bose-einstein condensate

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7
Q

m/v

A

density

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8
Q

density of water

A

1 g/ml=1 g/cm³=1000 kg/m³

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9
Q

ratio of the density of a sample and the density of a reference substance

A

specific gravity (unitless quantity)

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10
Q

specific gravity formula

A

SG=tsample/treference

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11
Q

ratio between the weights of equal volumes of a sample and water

A

apparent specific gravity

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12
Q

formula for apparent specific gravity

A

SGapparent=Wsample/Wwater

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13
Q

ratio between the weights in a vacuum of equal volumes of a sample and water

A

true specific gravity

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14
Q

formula for true specific gravity

A

SGtrue=Wvsample/Wvwater

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15
Q

Specific Volume

A

SV=1/SG

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16
Q

when H2O freezes the volume that the same mass of H2O occupies increases because

A

the molecules become more highly organized

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17
Q

highly organized molecules mean

A

increase in volume, decrease in density

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18
Q

ability to float

A

buoyancy

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19
Q

ability to be drawn out into wires

A

ductility

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20
Q

ability to be hammered into sheets

A

malleability

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21
Q

ability to return to its original shape after being deformed

A

elasticity

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22
Q

ability to resist flow

A

viscosity

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23
Q

measure of disorder of a thermodyamic system

A

entropy

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24
Q

amount of energy stored in an object

A

energy

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25
Q

the number of valence electrons is close to completing the octet rule, accepts electrons during ionic bonding, forms anions when ionized

A

non-metals

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26
Q

the number of valence electrons is small, donates electrons during ionic bonding, forms cations when ionized

A

metals

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27
Q

can act as a metal or non-metal depending on the conditions

A

metalloids

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28
Q

components are a pair of anion group and a cation group, electrons are transferred from the cation to the anion

A

ionic

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29
Q

components are both anion groups, electrons are shared within the bond

A

covalent

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30
Q

components are both metals, components are stored in a sea of electrons

A

metallic

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31
Q

commonly called solutions, where only 1 phase is discernable

A

homogenous

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32
Q

measure of the relative amounts of the components of a solution

A

concentration

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33
Q

the component that dissolves in the solution

A

solute

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34
Q

the component that dissolves other components of the solution

A

solvent

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35
Q

the maximum amount of solute that can be dissolved in a particular solvent under specific conditions, often expressed as a ratio or other measures of concentration

A

solubility [g of solute/100 g of solvent]

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36
Q

contains less solute than the maximum quantity of solute that is normally possible at a given temperature [haven’t reached the solubility of your solute]

A

unsaturated, no crystal formation

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37
Q

contains the max amount of solute that is normally possible at a given temperature

A

saturated, crystal formation

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38
Q

contains more solute than normally expected for a saturated solution (unusual amount at a specified temperature]

A

supersaturated, unstable, triggers fast crystal formation

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39
Q

molarity formula

A

M=moles of solute/liters of solution

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40
Q

molality formula

A

m=moles of solute/kg of solvent

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41
Q

mass percent

A

[mass of solute/mass of solution] x 100

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42
Q

volume percent

A

[volume of solute/volume of solvent] x 100

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43
Q

relative amount of solute in a sol’n

A

saturation

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44
Q

IMF charges occur, these IMFs can decrease volume of liquid because of strong interactions that occur in your liquids, this also accounts for changes

A

on the usage of molality

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45
Q

used to describe a certain amount of molecules

A

moles

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46
Q

1 mole = avogadro’s number

A

6.02 x10²³

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47
Q

number of equivalent weights of a solute per liter of the solution

A

normality

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48
Q

normality formula

A

N=number of equivalent weights/L of solution

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49
Q

grams of solute/gram equivalent weight of solute

A

number of equivalent weight

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50
Q

Molarity x factor

A

Normality

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51
Q

refers to the acidic hydrogen [hydronium]

A

acid factor

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52
Q

refers to the number of hydroxide

A

base factor

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53
Q

used to convert mass of substance to moles of substance

A

molecular weight

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54
Q

all alkali metals (group 1a) are

A

soluble

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55
Q

all those with ammonium ion [NH₄⁺] are

A

soluble

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56
Q

all nitrates [NO₃⁻] are

A

soluble

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57
Q

all acetates [C₂H₃O₂⁻] are

A

soluble

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58
Q

all chlorides [Cl⁻] bromides [Br⁻] iodides [I⁻] are soluble except

A

Ag⁺, Hg₂²⁺, Pb²⁺

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59
Q

most sulfates [SO₄²⁻] are soluble except

A

BaSO₄, PbSO₄, SrSO₄, Hg₂SO₄

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60
Q

all hydroxides [OH⁻] are insoluble except those of

A

Group 1A, Ba(OH)₂, Sr(OH)₂, Ca(OH)₂

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61
Q

all sulfides are insoluble except those of

A

group 1A, group 2A, NH₄⁺

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62
Q

all carbonates [CO₃²⁻] are insoluble except those of NH₄⁺ and those of

A

NH₄⁺ and those of group 1A

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63
Q

all phosphates [PO₄³⁻] are insoluble except

A

NH₄⁺ and those Group1A

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64
Q

pressure needed to prevent osmosis which is the spontaneous net movement of solvent molecules through a semi-permeable membrane into a region of higher solute concentration

A

osmotic pressure

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65
Q

osmotic pressure formula

A

πV=nRT

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66
Q

the addition of nonvolatile solute to a volatile solvent will diminish the escaping tendency of the solvent thereby lowering the vapor pressure of the solution

A

vapor pressure lowering

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67
Q

raoult’s law

A

ΔP=P°Xₛₒₗᵤₜₑ

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68
Q

is the temperature at which the vapor pressure of the liquid becomes equal to the external atmospheric pressure [1 atm=760 mmHg]

A

boiling point

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69
Q

the boiling point of a pure solvent is increased by the addition of a non-volatile solute, and the elevation can be measure by

A

ebullioscopy

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70
Q

ebullioscopy

A

ΔTբ=iKbm

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71
Q

is the temperature at which the solid and liquid phases are in equilibrium under an external pressure of 1 atm

A

freezing point

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72
Q

the freezing point of a pure solvent is lowered by the addition of a solute which is insoluble in the solid solvent, and the measurement of this difference is called cryoscopy

A

freezing point depression

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73
Q

freezing point depression formula

A

ΔTբ=iKբm

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74
Q

mixtures wherein 2 or more distinct phases are discernable

A

heterogenous

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75
Q

suspended particles are too large and too heavy to be carried by the motion of the particles in which they are suspended in causing them to settle after sometime

A

suspensions

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76
Q

suspended particles are small and light enough to be carried by the movement of the particles in which they are suspended in

A

colloids

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77
Q

solid in solid colloid

A

solid sol

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78
Q

solid in liquid colloid

A

sol

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79
Q

solid in gas colloid

A

solid aerosol

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80
Q

liquid in solid colloid

A

gel

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81
Q

liquid in liquid colloid

A

emulsion

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82
Q

liquid in gas colloid

A

aerosol

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83
Q

gas in solid colloid

A

solid foam

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84
Q

gas in liquid colloid

A

foam

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85
Q

mass of proton

A

1.67 x 10⁻²⁷ or 1 amu

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86
Q

mass of neutrons

A

1.67 x 10⁻²⁷ or 1 amu

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87
Q

mass of electrons

A

9.11 x 10⁻³¹

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88
Q

mass of the atom is concentrated on the

A

nucleus

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89
Q

atomic number [Z]

A

number of protons

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90
Q

mass number [A]

A

sum of protons and neutrons

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91
Q

charge [q]

A

difference of the protons and electrons

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92
Q

relative abundance of a certain isotope compared to all the isotopes of the same element

A

percent natural balance

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93
Q

weighted average of the mass numbers of the isotopes of that particular element

A

atomic weight

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94
Q

ISOTOPES: atoms of the same element that have the same number of protons but different number of neutrons, thus their mass numbers are

A

different

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95
Q

elements having the same number of neutrons

A

isotones

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96
Q

atomic species having the same mass number but different atomic numbers

A

isobars

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97
Q

elements having the same number of electrons

A

isoelectronic

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98
Q

who discovered atoms as the basic unit of matter

A

democritus

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99
Q

who discovered the billiard ball model

A

john dalton

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100
Q

who discovered the plum pudding model and the electron

A

j.j. thomson

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101
Q

who discovered the gold foil experiment and the proton?

A

ernest rutherford

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102
Q

who discovered the neutron

A

james chadwick

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103
Q

who discovered the planetary model

A

niels bohr

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104
Q

who discovered the quantum theory

A

erwin schrodinger

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105
Q

usually malleable and ductile, highly conductive for heat and electricity, low electronegativities and ionization energies, high melting points and densities

A

metals

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106
Q

brittle solids, poor conductors of heat and electricity, high electronegativities and ionization energies

A

non-metals

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107
Q

properties are in between metals and non-metals, reactivity depends on the elements to be reacted with

A

metalloids

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108
Q

soft metallic solids, shiny and lustrous; reacts vigorously with water to produce hydroxides

A

alkali metals [group 1A]

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109
Q

harder than 1A metals; shiny, lustrous, and oxidizes easily

A

alkaline earth metals [group 2A]

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110
Q

boron group or earth metals

A

group 3A

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111
Q

carbon group or tetrels

A

group 4A

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112
Q

nitrogen group or pnictogens

A

group 5A

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113
Q

oxygen group or chalcogens

A

group 6A

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114
Q

halogens, reactive non-metals

A

group 7A

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115
Q

unreactive under ordinary circumstances; usually found as monoatomic gases

A

group 8A [noble gases]

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116
Q

hard metallic; shiny and lustrous; dense and have high melting points, usually have high oxidation states

A

transition metals

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117
Q

Group B inclusions

A

transition metals, lanthanides, actinides

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118
Q

lightest element

A

hydrogen

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119
Q

densest element

A

osmium

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120
Q

only metal liquid at room temperture

A

mercury

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121
Q

only non metal liquid at room temperature

A

bromine

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122
Q

most abundant intracellular cation

A

potassium

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123
Q

most abundant extracellular cation

A

sodium

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124
Q

most abundant gas in the air

A

nitrogen

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125
Q

most abundant element on earth

A

oxygen

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126
Q

most abundant metal on earth

A

aluminum

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127
Q

most abundant noble gas

A

argon

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128
Q

desire for an electron, desire for negativity, near octet

A

electronegativity

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129
Q

most electronegative

A

flourine

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130
Q

tendency of an electron to bond, increases from left to right along a period, decreases from top to bottom along a column/group

A

electronegativity

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131
Q

energy needed to remove an electron form an atom, increases from left to right along a period, decreases from top to bottom along a column/group

A

ionization energy

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132
Q

energy released when an electron is added to an atom, positive when energy is released and negative when absorbed, increases from left to right along a period, decreases from top to bottom along a column/group

A

electron affinity

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133
Q

farthest extent of the presence of electron decrease from left to right a period, increases from top to bottom along a column/group

A

atomic size/radius

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134
Q

bond between a metal and non-metal [cation and anion], form crystals, high melting and boiling points, hard and brittle, poor conductors when solid, good conductors when dissolved in water

A

ionic bond

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135
Q

bond between non-metals [anions], most have relatively low melting and boiling points, soft and relatively flexible, more flammable, many are insoluble in water and those that do dissolve do not conduct electricity

A

covalent/molecular bond

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136
Q

with unequal sharing

A

polar bond

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137
Q

with equal sharing

A

nonpolar bond

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138
Q

electronegativity difference greater than 0.4 but less than 1.7

A

polar compound

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139
Q

electronegativity difference less than 0.4

A

nonpolar compound

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140
Q

electronegativity difference greater than 1.7

A

ionic compound

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141
Q

types of covalent bonds

A

pi bond and sigma bond

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142
Q

end to end overlap of orbitals; stronger type of bond

A

sigma bond

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143
Q

lateral or sideways overlap of orbitals

A

pi bond

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144
Q

bond between metals [cations] have moderately high melting points, malleable and ductile, good conductors of heat and electricity

A

metallic bond

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145
Q

occurs when orbitals combine to form a hybrid orbital during bond formation

A

hybrid orbital

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146
Q

s orbital combines with 3 p orbitals to form 4 hybridized orbitals

A

sp³

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147
Q

s orbital combines with 2 p orbitals to form 3 hybridized orbitals and 1 normal orbital

A

sp²

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148
Q

s orbital combines with 1 p orbital to form 2 hybridized orbitals and 2 normal orbitals

A

sp¹

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149
Q

[carbon chemical bonds] sp³ hybrid orbitals form sigma bonds with orbitals of other atoms

A

single bonds

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150
Q

[carbon chemical bonds] 1 sp² hybrid from each atom form a sigma bond and 1 p orbital from each atom form a pi bond

A

double bonds

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151
Q

[carbon chemical bonds] 1 sp¹ hybrid from each atom form a sigma bond and 2 p orbitals from each atom form 2 pi bonds

A

triple bonds

151
Q

presence of double or triple bonds increases

A

reactivity

152
Q

saturated hydrocarbons do not have

A

triple or double bonds

153
Q

shows the simplest ratio of the amounts of atoms of each component elements

A

empirical formula

154
Q

shows the actual amounts of each of the atoms of the component elements

A

molecular formula

155
Q

shows the approximate arrangement of the atoms within the molecule

A

structural formula

156
Q

[molecular geometry] steric number 2, no lone pairs

A

linear

157
Q

[molecular geometry] steric number 3, no lone pairs

A

trigonal planar

158
Q

[molecular geometry] steric number 3, 1 lone pair

A

bent or angular

159
Q

[molecular geometry] steric number 4, no lone pairs

A

tetrahedral

160
Q

[molecular geometry] steric number 4, 1 lone pair

A

trigonal pyramidal

161
Q

[molecular geometry] steric number 4, 2 lone pairs

A

bent or angular «109 degrees

162
Q

[molecular geometry] steric number 5, no lone pairs

A

trigonal bypiramidal

163
Q

[molecular geometry] steric number 5, 1 lone pair

A

sawhorse or seesaw

164
Q

[molecular geometry] steric number 5, 2 lone pairs

A

t-shape

165
Q

[molecular geometry] steric number 6, no lone pairs

A

octahedral

166
Q

[molecular geometry] steric number 6, 1 lone pair

A

square pyramid

167
Q

[molecular geometry] steric number 6, 2 lone pairs

A

square planar

168
Q

[molecular geometry] steric number 6, 3 lone pairs

A

t shape <90 degrees

169
Q

[molecular geometry] steric number 6, 4 lone pairs

A

linear, vertical 180 degrees

170
Q

influences the final structure of the molecule, boiling and freezing points, heat capacity, solubility

A

intermolecular forces of attraction

171
Q

attraction between the opposing poles of dipole molecules

A

electrostatic interactions

172
Q

types of electrostatic interactions

A

dipole-dipole, ion-dipole, ion-induced dipole, hydrogen bonding

173
Q

weakest electrostatic interaction, sum of all the attractive ad repulsive forces between and within the molecules

A

van der waals

174
Q

relative amount of particles present in a sample, avogadro’s sample

A

6.022 x 10²³

175
Q

[gases] an ideal gas is where all interactions between the molecules are only through collisions that are assumed to be completely elastic, gases have no volume, exists in STP of 0 degrees C and 1atm

A

ideal gas concept

176
Q

[gases] at stp, 1 mole of a gas is occupies 22.4 L

A

22.4 L

177
Q

[gases] ideal gas equation

A

PV=nRT

178
Q

in PV=nRT, n is for

A

the number of moles

179
Q

in PV=nRT, r is equal to

A

0.0821 [(Latm)/molK]

180
Q

in using gas laws the unit of temperature must be in

A

kelvin

181
Q

a particular amount of gas at constant temperature increase in volume when the pressure is decreased

A

boyle’s law

182
Q

boyle’s law equation

A

P₁V₁=P₂V₂

183
Q

a particular amount of gas in a constant pressure increases in volume when the temperature is increased

A

charles law

184
Q

charles law equation

A

V₁/T₁=V₂/T₂

185
Q

a particular amount of gas in a constant volume increase in temperature when the pressure is increased

A

gay-lussac’s law

186
Q

gay-lussac’s law equation

A

P₁/T₁=P₂/T₂

187
Q

a gas in a constant pressure and temperature increases in volume when the amount of particles is increased

A

avogadro’s law

188
Q

combined gas law equation

A

P₁V₁/V₁n₁=P₂V₂/V₂n₂

189
Q

avogadro’s law equation

A

V₁/n₁=V₂/n₂

190
Q

dalton’s law is also called

A

law of partial pressures

191
Q

the pressure of a mixture of gases is the sum of the pressures of the individual components

A

Ptotal = P₁ + P₂ +…

192
Q

the rate at which a gas diffuses is inversely proportional to the root of its density or mass

A

law of effusion

193
Q

law of effusion formula

A

R₁/R₂ = √t₁/t₂

194
Q

all chemical reactions follow the law of

A

conservation of mass

195
Q

[type of rxn] 2 or more elements or compounds combine to make a more complex substance

A

synthesis

196
Q

[type of rxn] compounds break down into simpler substances

A

decomposition/analysis

197
Q

[type of rxn] occurs when 1 element replaces another one in a compound

A

single replacement

198
Q

[type of rxn] occurs when different atoms in 2 different compounds trade places

A

double replacement

199
Q

fuel + O₂ -> CO₂ +H₂O

A

complete combustion

200
Q

fuel + O₂ -> CO₂ + H₂O + residues

A

incomplete combustion

201
Q

electron transfer from 1 atom to another

A

redox reaction

202
Q

[type of redox reaction] loss of electrons

A

oxidation

203
Q

[type of redox reaction] gain of electrons

A

reduction

204
Q

GEROA

A

gain of electrons is reduction among oxidizing agents

205
Q

LEORA

A

loss of electrons is reduction among reducing agents

206
Q

acid + base -> salt + H₂O

A

neutralization reaction

207
Q

[stoichiometry] reactant that is first to be totally consumed halting further reactions

A

limiting reagent

208
Q

[stoichiometry] reactant that is left when the limiting reagent is consumed

A

excess reagent

209
Q

[energy] the total energy of an object or system

A

enthalpy

210
Q

[energy] reactions that require addition of energy. this means that the product has higher enthalpy than the reactants

A

endothermic

211
Q

[energy] reactions that require removal of energy. this means that the product has lower enthalpy than the reactants

A

exothermic

212
Q

[energy] energy required to start a reaction

A

activation energy

213
Q

[energy] reactions that require a very small activation energy and can start without external interference

A

spontaneous reactions

214
Q

[energy] any substance that increases the rate of the reaction without being consumed

A

catalyst

215
Q

[equilibrium] reactions whose products can spontaneously react to form the original reactants thereby reversing the reaction

A

reversible reactions

216
Q

[equilibrium] state of reaction at which the rate of the forward and reverse reactions are the same producing a condition where the concentrations of the reactant and the products remain relatively constant

A

equilibrium

216
Q

equilibrium constant K can be derived as

A

kₑq = [C]ˡ[D]ᵐ/[A]ʲ[B]ᴰ

217
Q

when an equilibrium system is subjected to a change in temp., pressure, or concentration of a reacting species, the system responds by attaining a new equilibrium that partially offsets the impact of the change

A

le chatelier’s principle

218
Q

[le chatelier’s] effects of changing the amount of reacting species

A

if the concentration of 1 of the reacting species is increased, it will favor the reaction in which the species is consumed

219
Q

[le chatelier’s] effects of changing in pressure or volume of equilibrium

A

if the pressure of an equilibrium mixture of gases is increased, the volume is reduced, a net reaction occurs in the direction producing fewer moles of gases

220
Q

[le chatelier’s] effects of temperature on equilibrium

A

raising the temp. of an equilibrium mixture shifts the equilibrium condition in the direction of endothermic reaction

221
Q

[le chatelier’s] effects of catalysts on equilibrium

A

a catalyst has no effect on the condition of equilibrium in a reversible reaction

222
Q

[dissociation] ____ occurs when a compound separates into its component molecules

A

dissociation

223
Q

[acid-base def.] arrhenius acid

A

H⁺ producer

224
Q

[acid-base def.] arrhenius base

A

OH⁻ producer

225
Q

[acid-base def.] bronsted-lowry acid

A

H⁺ donor

226
Q

[acid-base def.] bronsted-lowry base

A

H⁺ acceptor

227
Q

[acid-base def.] lewis acid

A

electron pair acceptor

228
Q

[acid-base def.] lewis base

A

electron pair donor

229
Q

[acid-base] typically sour in taste and are corrosive to most metals

A

acids

230
Q

[acid-base] typically bitter in taste, and are slippery to touch

A

bases

231
Q

[conjugate acids and bases] bronsted-lowrey acid

A

protonated bronsted base

232
Q

[conjugate acids and bases] bronsted-lowrey base

A

deprotonate bronsted acid

233
Q

acids dissociate to produce

A

H+ ions and anions

234
Q

bases dissociate to form

A

OH- ions and cations

235
Q

acids/bases that have dissociation constants close to 1

A

strong acids/bases

236
Q

acids/bases that have dissociation constants far from 1

A

weak acids/bases

237
Q

[strong/weak acid] HCl

A

strong acid

238
Q

[strong/weak acid] H2SO4

A

strong acid

239
Q

[strong/weak acid] Nitric Acid (HNO3)

A

strong acid

240
Q

[strong/weak acid] Perchloric Acid (HClO4)

A

strong acid

241
Q

when acids and bases are in aqueous state, they _____ into their respective ions

A

dissociate

242
Q

acidity of a substance depend on the concentrations of its

A

dissociated ions

243
Q

process of determining the concentration of a substance by slowly adding another substance with a known concentration

A

titration

244
Q

[titration] substance with known concentration to be added

A

titrant

245
Q

[titration] substance whose unknown concentration is to be determined

A

analyte

246
Q

[titration] substances that changes property under certain conditions to signal when to stop adding the titrant

A

indicator

247
Q

[acid-base titration] added titrants neutralizes the analyte

A

equivalence point

248
Q

[acid-base titration] point when the pH changes the color of the indicator

A

end point

249
Q

pH = 7

A

strong acid-strong base

250
Q

pH < 7

A

strong acid-weak base

251
Q

pH > 7

A

weak acid-strong base

252
Q

acid + base -> salt + H2O

A

neutralization reaction

253
Q

[acid-base rxn] resist drastic change in pH contain weak acid and base pairs

A

buffers

254
Q

[thermochem] amount of heat needed to changethe temp. of 1 g of a substance by 1 degree celsius

A

C [specific heat capacity]

255
Q

amount of heat required to transform 1 g of substance from liquid to gas or gas to liquid

A

heat of vaporization [ΔHᵥ]

256
Q

amount of heat required to transform 1 g of a substance from solid to liquid or liquid to solid

A

heat of fusion [ΔHբ]

257
Q

change in temperature formula

A

Q = mCqΔT

258
Q

change in phase formula

A

Q = mΔH

259
Q

common properties of organic compounds

A

usually combustible, generally have low melting and boiling pts, usually less soluble in water, usually slow to react because they are usually covalent molecules, most have high molecular weights

260
Q

sources of organic compounds

A

nature, synthesis, fermentation

261
Q

valence electrons of carbon

A

4

262
Q

what group is carbon in in the periodic table?

A

group 4A

263
Q

carbon is capable of catenation and _____

A

hybridization

264
Q

is the ability of carbon to bond with itself and form long chains of organic compounds

A

catenation

265
Q

concept of mixing non-equivalent atomic orbitals to form equivalent or degenerate hybrid orbitals to form single, double, and triple bonds

A

hybridization

266
Q

what is the shape, bond angle, and bond type of sp3 orbital?

A

tetrahedral, 109.5, single

267
Q

what is the shape, bond angle, and bond type of sp2 orbital?

A

trigonal planar, 120, double

268
Q

what is the shape, bond angle, and bond type of sp orbital?

A

linear, 180, triple

269
Q

[org chem] different compounds that have the same molecular formula

A

isomers

270
Q

[forms of isomerism] form if isomerism in which molecules with the same molecular formula have different bonding patterns and atomic organization

A

structural isomerism

271
Q

[type of structural isomerism] differ in the arrangement of C atoms usually due to the presence of branching

A

chain isomerism

272
Q

examples of chain isomerism

A

n-butane, isobutane

273
Q

[type of structural isomerism] the isomers have the same molecular formula but differs mainly in the attached functional groups

A

functional isomerism

274
Q

examples of functional isomerism

A

ether and alcohol, aldehyde and ketone

275
Q

[type of structural isomerism] differs in the position of unsaturated bonds (double and triple bonds) or functional groups

A

positional isomerism

276
Q

examples of positional isomerism

A

meta isomer, ortho isomer, para isomer

277
Q

[forms of isomerism] isomers that have the same molecular formula and sequence of bonded atoms (constitution), but differ in the 3-dimensional orientations of their atom space

A

stereoisomerism

278
Q

[types of stereoisomerism] occurs among double bonds

A

geometric/configurational isomerism

279
Q

[type of geometric isomerism] cis-trans isomerism: the molecule in which the 2 of the same atoms are on the same side of the double bond is known as

A

cis isomer

280
Q

[type of geometric isomerism] cis-trans isomerism: molecule with the 2 of the same atoms in the opposite side of the double bond is called

A

trans isomer

281
Q

[type of geometric isomerism] E-Z isomerism: the higher priority groups are on opposite sides of the double bond

A

E isomer

282
Q

[type of geometric isomerism] E-Z isomerism: the higher priority groups are on the same sides of the double bond

A

Z isomer

283
Q

[types of stereoisomerism] results from the different ways an atom flexes and bends due to rotation along a single bond or ring flipping among cyclic structures

A

conformational isomers

284
Q

[types of stereoisomerism] isomers which differ in their ability to rotate plane polarized light

A

optical isomers

285
Q

[optical isomers] structural requirement for optical activity, carbon with 4 different functional groups or substituents

A

chiral center

286
Q

types of optical isomers

A

enantiomers, diastereomers, meso compounds

287
Q

chain or branched chain of organic compounds whose longest chain is made of carbon atoms only

A

aliphatic compounds

288
Q

aliphatic compounds made up of only hydrogen and carbon

A

hydrocarbons

289
Q

[type of hydrocarbon] hydrocarbons wherein all carbons are attached together only with single bonds

A

saturated hydrocarbons

290
Q

properties of saturated hydrocarbons

A

colorless, tasteless, odorless; boiling and melting pts increases as molecular weight increases while London Dispersion Forces increases, non-polar practically insoluble in water but soluble in organic solvents, stable due to strong c-c and c-h bonds, sigma bonded, tetrahedral

291
Q

CH4

A

methane

292
Q

C2H6

A

ethane

293
Q

C3H8

A

propane

294
Q

C4H10

A

n-butane

295
Q

(CH3)3CH

A

isobutane

296
Q

C5H12

A

n-pentane

297
Q

(CH3)CHCH2

A

isopentane

298
Q

(CH3)4C

A

neopentane

299
Q

[common rxns] CH4 + 202 -> CO2 +H2O

A

oxidation with oxygen in air

300
Q

[common rxns] CH4 +CL2 -> HCl + CH3Cl

A

halogen substitution

301
Q

[common rxns] occurs when bacteria oxidizes a hydrocarbon underaerobic conditions

A

biological oxidation

302
Q

[type of hydrocarbon] hydrocarbons containing double or triple bonds

A

unsaturated hydrocarbons

303
Q

[types & nomenclatures of unsaturated hydrocarbons] properties: non polar, stable due to strong c-c, c-h bonds, sigma and pi bonds, double bond, trigonal planar

A

alkenes

304
Q

[types & nomenclatures of unsaturated hydrocarbons] properties: triple bond, have 2 pi bonds, very reactive

A

alkyne

305
Q

[common reactions for alkenes and alkynes] produces glycol

A

oxidation

306
Q

[common reactions for alkenes and alkynes] hydrogen is bonded to replace double or triple bonds making the compound more saturated

A

reduction

307
Q

[common reactions for alkenes and alkynes] acids bond across double or triple bonds

A

addition

308
Q

[common reactions for alkenes and alkynes] unsaturated molecules combine with each other to form polymers with higher molecular weight

A

polymerization

309
Q

[types & nomenclatures of unsaturated hydrocarbons] hydrocarbons that contain the hydroxyl group OH, product of primary oxidation

A

alcohols

310
Q

classifications of alcohols

A

primary, secondary, tertiary

311
Q

properties of alcohols

A

soluble in water but solubility decreases as molecular weight increases, low boiling and melting points but increases with molecular weight

312
Q

alcohols with 2 or more OH groups

A

glycols

313
Q

[common reactions in alcohols] reaction with acids to form esters

A

glycols

314
Q

[common reactions in alcohols] primary alcohols oxidize into aldehydes, secondary alcohols oxidize into ketones

A

oxidation

315
Q

most common aldehydes

A

carbohydrates

316
Q

[types & nomenclatures of unsaturated hydrocarbons] contains a carbonyl group at the end of the chain

A

aldehydes

317
Q

properties of aldehydes

A

carbonyl group is attached to the end of the alkyl chain, and is a serious air pollutant

318
Q

example of aldehyde that is very toxic to microorganisms and is used as an embalming fluid

A

formalin

319
Q

example of aldehyde that is a common industrial manufacturing chemical

A

acetyldehyde

320
Q

[types & nomenclatures of unsaturated hydrocarbons] carbonyl group in the middle of alkyl chain, commonly used as solvents and for industrial manufacturing

A

ketones

321
Q

[type of ketone] simplest ketone produced from the oxidation of isopropyl alcohol

A

acetone [dimethyl ketone]

322
Q

[type of ketone] produced from the oxidation of 2-butanol

A

methyl ethyl ketone

323
Q

properties of ketone

A

can be oxidized to form its corresponding acid

324
Q

[types & nomenclatures of unsaturated hydrocarbons] highest oxidation state or organic compounds, contains 1 or more carboxyl group

A

carboxylic acids

325
Q

most common carboxylic acid

A

free-fatty acids

326
Q

actual source of bod energy are

A

fats

327
Q

[types of c. acids] contain 1 carboxylic group, commonly known as fatty acids

A

saturated monocarboxylic

328
Q

[types of c. acids] form metallic acids, can be reduced into saturated acids, used as food by microorganisms

A

unsaturated monocarboxylic

329
Q

principal acids of unsaturated monocarboxylic

A

acrylic, oleic, linoleic

330
Q

[types of c. acids] the most important species are the ones that have 2 carboxylic groups one on each end

A

polycarboxyllic

331
Q

[types of c. acids] contains OH other than c. acid, some species are optically active

A

hydroxy

332
Q

[types & nomenclatures of unsaturated hydrocarbons] formed by the reaction between acids and alcohols, commonly used in chemical manufacturing, solvents, flavoring extracts and perfumes

A

esters

333
Q

most common ester

A

triglycerides

334
Q

alcohol groups and fatty acids are

A

esterified

335
Q

[types & nomenclatures of unsaturated hydrocarbons] formed by treating alcohols with strong dehydrating agents, has an oxygen sandwiched between 2 organic groups, widely used as a solvent, highly flammable

A

ethers

336
Q

ethers are susceptible to forming peroxides that are highly explosive when exposed to

A

air

337
Q

ethers are resistant to

A

biological oxidation

338
Q

[types & nomenclatures of unsaturated hydrocarbons] organic compounds that contain halogens

A

alkyl halides and halogenated aliphatic compounds

339
Q

[types & nomenclatures of unsaturated hydrocarbons] nitrogen containing aliphatic compounds

A

amines, amides, nitriles

340
Q

common example of amines

A

amino acids

341
Q

[types & nomenclatures of unsaturated hydrocarbons] derived from the reaction between organic acids and ammonia

A

amides

342
Q

[type of nitrogen containing a. compounds] called naphthenes, have 2 H atoms connected to each C atom

A

cyclic aliphatic compounds

343
Q

[type of nitrogen containing a. compounds] contains sulfur

A

mercaptans and thioalcohols

344
Q

cyclic organic compounds with alternating single and double bonds

A

aromatic compounds

345
Q

parent compound of aromatic compounds

A

benzene

346
Q

[aromatic hydrocarbons] benzene examples

A

toluene, ethylbenzete

347
Q

[aromatic hydrocarbons] polyring hydrocarbon example

A

naphthalene

348
Q

types of aromatic copounds

A

aromatic hydrocarbons and phenols

349
Q

types of aromatic hydrocarbons

A

benzenes and polyring hydrocarbons

350
Q

[type of aromatic compound] contains OH

A

phenols

351
Q

types of phenols

A

monohydroxy phenols, polyhydroxy phenols

352
Q

[type of monohydroxy phenols] contains alkyl groups

A

cresols and other alkylphenols

353
Q

[type of monohydroxy phenols] contains chlorine

A

chlorinated phenols

354
Q

cyclic organic compounds with double bonds or with other elements in the ring

A

heterocyclic compounds

355
Q

[common food and related compounds] types of carbohydrates

A

monosaccharides, disaccharides, polysaccharides

356
Q

types of monosaccharides

A

glucose, fructose, galactose, mannose

357
Q

sweet monosaccharide

A

fructose

358
Q

types of disaccharides

A

sucrose [table sugar], maltose

359
Q

fructose is also a

A

ketohexose

360
Q

glucose is also a

A

aldohexose

361
Q

[fats, oils, waxes] fatty acid glycerides that are solid at room temp.

A

fats

362
Q

[fats, oils, waxes] fatty acid glycerides that are liquid at room temp.

A

oil

363
Q

[fats, oils, waxes] esters of long-chain acids and alcohols

A

waxes

364
Q

building blocks of protein

A

amino acids

365
Q

[other organic compounds] contains surfactants that consists of il soluble parts and water soluble parts

A

detergents

366
Q

[other organic compounds] derived from saponification of fats and oils

A

soaps

367
Q

[additional] indicator: benedicts solution

A

simple carbohydrates turns brick red for positive

368
Q

[additional] indicator: iodine solution

A

complex carbohydrates turns black if positive

369
Q

[additional] indicator: biuret solution

A

protein, turns violet black if positive

370
Q

[additional] indicator: sudan IV

A

lipids, turns reddish-orange if positive

371
Q

[additional] examples of non-polar amino acids

A

glycine, alanine, valine, leucine, isoleucine, methionine, tryptophan, phenylalanine, proline

372
Q

[additional] examples of polar amino acids

A

serine, threonine, cysteine, tyrosine, asparagine, glutamine

373
Q

[additional] examples of polar charged amino acids

A

acidic: aspartic acid, glutamic acid; basic: lysine, arginine, histidine