Unit 3day 4 Flashcards

(57 cards)

1
Q

Write formula for partial pressure of blue

Using ideal gas law

A

Pblue = nblueRT/ V

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2
Q

Formula for total pressure of blue and green

A

Ptotal = Pblue + Pgreen

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3
Q

Write formula for P total

Using ideal gas law

A

P tot= ntotRT/ V

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4
Q

Write formula , for partial pressure of blue gas

Using mol fraction

A

Pblue = mole fraction(X) blue * Ptot

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5
Q

Write formula for mole fraction(X) of blue

Using moles

A

n blue/ n total

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6
Q

Equation for tank valve problems ( one has O2, one has N2)

A

PO2V1 = P’O2Vtot

PN2V2 = P’N2Vtot

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7
Q

Write the formula for total pressure for the tank valve problem

Gases are O2 and N2

A

Ptot= P’O2 + P’N2

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8
Q

Which ballon will have the most efficient reaction? Loudest bang?

A

The one with the most equal mole fraction to molecular formula (empirical)

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9
Q

Ideal gas descriptions

A

TEAR

Tiny- small discrete, far apart
Elastic/Energy - no energy lost or gained
Asexual- not attracted to each other
Random - molecules are constant, random , straight line motion, until they hit a wall

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10
Q

When ranking samples form highest to lowest average KE consider

A

ONLY consider temp

High temp has higher KE

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11
Q

Rank samples from highest to lowest velocity CONSIDER

A

consider both smallest particle(those will be faster) and temp, then use equation if different temp and contradicting different size particles

High temp small particles are faster

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12
Q

Equation for KE of gases with ideal gas law

A

KE = 3/2RT

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13
Q

What does R equal for KE formula with ideal gas law

A

R = 8.314 J/ mol K

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14
Q

Regular formula for KE

A

KE= 1/2m(v^2)

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15
Q

What are the units for the regular KE formulas

A

M (mass) is in Kg
v (velocity) is In m/s(meters per sec)

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16
Q

Which molecule is the lightest for probability density graphs

A

The one that has the flattest most spread out graphs, reaches the highest speed

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17
Q

Which molecule is the heaviest for probability density graphs

A

The molecule that has the highest peak and spreads the least over the x axis, lowest speeds

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18
Q

How does cold molecule graph look

A

Narrow distribution

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19
Q

How does hot molecule graph look

A

Wide distribution

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20
Q

Root mean square velocity , Vrms FORMULA

A

square root of (3RT/mm)

mm in kg/mol

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21
Q

What unit is the mass in for Vrms

Root mean square velocity

A

The molar mass of the element converted to Kg

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22
Q

Diffusion

A

Intermingling of gases due to their random motion

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23
Q

Effusion

A

Escape of gas particles through tiny holes

24
Q

Write mole fraction(X) for blue using pressure

A

Pblue/P total

25
What units does Vrms equation give you
M/s
26
What size of particles effuse the best
Small particles effuse faster
27
If there’s a solid formed between 2 gases in a tube, where will the precipitate form close to?
Next to the gas aight he greater radius because it effuses slower
28
Grahams law With velocity
Va/Vb = sq rt ( mmb/ mma)
29
When to use grahams law with velocity
When there’s the same temp and it’s the same molecule you’re comparing
30
Grahams law with temperature
Rate a/ rate b = sq rt(Ta/Tb)
31
When to use grahams law with temp(rates)
Diff temps same molecule
32
If Z is greater than 1, what are the interactions between gas particles
Repulsions
33
If Z is less than 1, what are the interactions between gas particles
Attractions
34
How do repulsion’s affect pressure
There are more collisions, higher pressure
35
How do attractions affect pressure
Less collisions, lower pressure
36
If the experimental pressure is greater than the ideal pressure what does that mean for the interactions between the gas particles
Repulsions
37
If the experimental pressure is LESS than the ideal pressure what does that mean for the interactions between the gas particles
Attractions
38
Gases behave most ideally at?
High temp and low pressure
39
Why do gases behave most ideally at high temp and low pressure
A lot of space, so less collisions, and ideally, gases are hot because they come as a result of boiling
40
What rules are not followed for real gases
T- Gases are not spaced far apart A- gases are not asexual because they are not spaced far apart^, they are attracted to each other
41
What does Z equal for an ideal gas
1
42
What does Z less than 1, mean for IMFs?
High attraction forces if Z < 1 so strong IMFs
43
Hard square Model equation
P(V-nb)= nRT
44
What does v equal in hard square model ?
Volume of container
45
What does nb equal in hard square model
Space occupied by gas
46
Van der Waals Equation
(P +a*(n^2)/(v^2))*(v-nb) =nRT
47
What does a equal in van der waals equation (Include units)
Attractive forces Atm*L^2/ mol^2
48
What does b equal in hard square model Include units
Size factor L/mol
49
How do IMFS impact a in van der waals equation
Strong IMFS means large a
50
How does size impact b in hard square model
Large size(radius) means large b
51
When you think of diffusion think of
Mizing
52
When you think of effusion think of
Escape
53
The rate of effusion or diffusion equation
Va/vb = sq rt(mm a/mm b)
54
What do mol fractions and ONLY mol fractions add to?
1
55
What is the unit produced by the standard KE formula
Joules
56
What is v in KE = 1/2mv^2
Velocity
57
How many mL is 1cm^3
1 mL