Rate Equations & Arrhenius Flashcards

1
Q

How do you find the individual order of something eg A

A

Look where A changes and the other things stay the same. Then compare A with rate

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2
Q

What’s the units for rate

A

Moldm^-3 s^-1

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3
Q

What’s the units for [A] eg

A

Moldm^-3

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4
Q

How do you know what species is the catalyst

A

it will be in the rate equation but not the overall equation

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5
Q

What is 0 order

A

No effect on ROR

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6
Q

What is 1st order

A

The same as ROR

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7
Q

What is 2nd order

A

The ROR is the [conc] squared ^2

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8
Q

How does temperature effect the rate constant (K)

A

As temperature increases the rate constant increases

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9
Q

Define the rate constant (k)

A

a number that connects the concentration of reactants in a reaction to the rate of that reaction

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10
Q

Define order of reaction

A

the power to which the concentration of that reactant is raised in the rate equation

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11
Q

How do you work out activation energy (Ea) in the Arrhenius equation

A
  1. RT(In A - In K)
  2. Then divide by 1000
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12
Q

How do you work out T in the Arrhenius equation

A

Activation energy/ R(In A - In k)

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13
Q

In the Arrhenius equation what units must activation energy be in

A

Joules. So if in kJ then multiply by 1000 to get in J

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14
Q

What will the units of A (Arrhenius constant) be the same as

A

The units of the rate constant

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15
Q

How do you work out the Arrhenius constant

A

K divided by e to the power of (-Ea/RT)

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16
Q

How would you know if iodine has all reacted

A

It would go from brown to colorless

17
Q

How do you work out the rate equation from 2 or more reaction mechanisms

A

rate equation for a reaction includes all reactants which appear before and during the slowest step (rate determining step) in the mechanism
Intermediates are ruled out