1.6.1 & 1.6.2: Reversible Reaction and industrial processes Flashcards

1
Q

As the reactants get used up…

A

The forward reaction slows down

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2
Q

As more product is formed…

A

The reverse reaction speeds ups

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3
Q

When it seems like nothing is happening…

A

the reaction is in dynamic equilibrium

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4
Q

Dynamic equilibrium

A

the concentrations of reactants and products stay constant

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5
Q

Closed system

A

nothing can get in or out

dynamic equilibrium occurs in a closed system

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6
Q

Le Chatelier’s principle

A

If a reaction at equilibrium is subjected to a change in concentration,pressure or temperature, the position of equilibrium will move to counteract the change.

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7
Q

Position of equilibrium moves to the left…

A

More reactants formed

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8
Q

position of equilibrium moves to the right…

A

More products formed

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9
Q

Homogeneous equilibria

A

Reactions where every species is in the same state

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10
Q

Conditions that affect equilibria

3

A

temperature
concentration
pressure

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11
Q

Increase in concentration of reactant or product

A

equilibrium shifts to the opposite side to remove the extra product or reactant

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12
Q

Pressure only affects substances in which state

A

equilibria involving gases

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13
Q

Increasing pressure

A

shifts equilibrium to the side with less gas molecules

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14
Q

Increasing the temperature

A

equilibrium shifts in the endothermic direction to absorb this heat

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15
Q

Decreasing the temperature

A

equilibrium shifts in the exothermic direction to produce more heat

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16
Q

If the forward reaction is endothermic…

A

the reverse reaction is exothermic

vice versa

17
Q

In industry the reaction conditions are…

A

a compromise

18
Q

Companies consider cost results in

A

compromise conditions

19
Q

Example of Compromise

A
ethene and steam produce ethanol
65atm
300 degrees C
phosphoric acid catalyst
forward reaction = exo. 
lower temp favours exo but means low ROR 
so compromise temp.
high pressure = expensive equipment needed 
so compromise pressure