17A: Chirality Flashcards

1
Q

optical isomerism

A

form of steroisomerism
occurs in molecules where a C atom has 4 different groups attached to it
amino acids are optically active as they have a chiral centre

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2
Q

enantiomers

A

the two isomers
non super imposable
enantiomers are named L-____ and D-_____
cannot tell which is which by lookinh at strctures of molecules

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3
Q

polarimetry

A

molecules that show optical isomeirsm (enantiomers) have the ability to rotate plane polarised light (optically active)
D isomer rotates clockwise
L isomer rotates anti clockwise
solutions of d and l isomers of the same conc rotate light by equal and opposite amounts

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4
Q

racemic mixture

A

an equimolar misxture of enantiomers - has no overall effect on rotation as they cancel each other out

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5
Q

L-isomers

A

all amino acids that are used in cells

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