2.7 Alcohols and Carboxylic Acids Flashcards

1
Q

Alcohol

A

Is a homologous series containing -OH as the functional group

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2
Q

Fermentation

A

Is an enzyme- catalysed reaction that converts sugars to ethanol

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3
Q

What are the two main process used to produce ethanol on an industrial scale?

A

Hydration of ethene
Fermentation

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4
Q

What is the optimal temperature for producing ethanol via hydration of ethene?

A

300°C

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5
Q

Would a higher or lower temperature produce a higher yield in the hydration of ethene?

A

A lower temperature since the forward reaction is exothermic

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6
Q

What is the optimal pressure used to produce ethanol via hydration of ethene?

A

60-70 atm

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7
Q

Would a higher or a lower pressure produce a higher yield in the hydration of ethene?

A

A high pressure since two moles are converted into one mole

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8
Q

Under normal conditions of hydration of ethene, how much % is normally converted into ethanol?

A

5%, the remaining ethene is recycled back into the reaction chamber

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9
Q

How is fermentaion normally carried out?

A

By dissolving sugar in water, adding yeast and leaving the mixture in a warm place

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10
Q

Is water part of the reaction during fermentation?

A

No, It is needed for the reaction to happen but otherwise it isn’t included in the reaction

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11
Q

Biofuel

A

Is a fuel that has been produced using a biological source

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12
Q

Carbon neutral

A

Is a process where there is no net transfer of carbon dioxide to or from the atmosphere

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13
Q

Advantages of Biofuels: (3)

A

Renewable
Overall production of carbon dioxide is reduced
Economic and political security, countries without oil fields can now grow plants that can be turned into biofuels

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14
Q

Disadvantages of Biofuels: (3)

A

Land use, growing the plants requires large amounts of fields
Use of resources, Growing crops suitable for biofuel production requires large amounts of water and fertilisers
Carbon neutrality, all of the fumes produced during the production of the biofuel can be argued to make it non carbon neutral

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15
Q

What are the two most common dehydrating agents?

A

Concentrated sulfuric acid
Heated aluminium oxide

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16
Q

What kind of reaction is the dehydration of alcohols?

A

Elimination, since a double bond is produced by the removal of OH from one carbon atom and of H from an adjacent carbon atom

17
Q

Classification of alcohols

A

Into primary, secondary or tertiary according to their structure

18
Q

Primary alcohols

A

The -OH is joined to a carbon that is itself joined to no more than one carbon atom

19
Q

Secondary alcohols

A

The -OH is joined to a carbon that is itself joined to two other carbon atoms

20
Q

Tertiary alcohols

A

The -OH is joined to a carbon that is itself joined to three other carbon atoms

21
Q

Aldehyde

A

Is an homologous series containing -CHO as the functional group

22
Q

Carboxylic acid

A

Is a homologous series containing -COOH as the functional group

23
Q

Ketone

A

Is a homologous series containing a C=O group within the carbon chain

24
Q

What is used to oxidise alcohols?

A

Heated Acidified potassium dichromate, and sulfuric acid as a source of H+ ions

25
Q

How is an oxidation agent shown in reactions?

A

[O]

26
Q

What is the suffix used for the aldehyde functional group?

A

-al

27
Q

What are the three kinds of oxidation?

A

Loss of electrons
Gain of an electron
Loss of hydrogen atoms

28
Q

Oxidising ethanol fully forms

A

Ethanoic acid

29
Q

Oxidising ethanol partially forms

A

Ethanal

30
Q

Oxidising propan-2-ol fully forms

A

Propanone

31
Q

Can you oxidise a tertiary alcohol?

A

No

32
Q

What is Ethanoic acid present in?

A

Vinegar

33
Q

What is Methanoic acid present in

A

Venom from ant bites

34
Q

Carboxylic acids react with bases, carbonates and hydro carbonates like …

A

Strong acids

35
Q

ABSW

A

acid + base —> salt + water

36
Q

ACSCW

A

acid + carbonate —> salt + carbon dioxide + water

37
Q

When carboxylic acids react with alcohols they produce?

A

An ester and water