4.6.1.2 RATES OF CHEMICAL REACTIONS Flashcards
this topic has appeared every year in the exam (12 cards)
what factors affect the rates of chemical reactions and how?
factors: the concentrations of reactants in solution, the pressure of reacting gases, the surface area of solid reactants, the temperature and the presence of catalysts.
how: increasing these factors will increase the rate of reaction, as it will take less time for the reaction to take place. It is the same when a catalyst is present.
what happens if concentration and pressure increase?
- there are more reactant particles per unit volume (i.e. the reactant particles become more crowded)
- there is a greater chance of the particles colliding, which leads to more successful collisions per second
- the rate of reaction increases
what happens if temperature increases?
- the reactant particles move more quickly
- they have more energy
- the particles collide successfully more often
- the rate of reaction increases
- this is due to more particles having energy greater than or equal to the activation energy
how do you increase surface area?
cutting the substance into small pieces, or by grinding it into a powder
do larger pieces or smaller pieces/powder have a large surface area?
smaller pieces/powder have a larger surface area
what happens when the surface area of the reactant increases?
- more particles are exposed to the other reactant
- there is a greater chance of particles colliding, which leads to more successful collisions per second
- the rate of reaction increases
what is a catalyst?
A catalyst is a substance which changes the rate of reaction but is unchanged at the end of the reaction
why is a catalyst specific to a particular reaction?
- different catalysts catalyse different reactions
- not all reactions have suitable catalysts
how much of a catalyst is needed to increase the rate of reaction between large amounts of reactants?
Only a very small amount of catalyst is needed
what does an iron catalyst catalyse in a reaction?
Making ammonia from nitrogen and hydrogen
what does a platinum catalyst catalyse in a reaction?
Making nitric acid from ammonia
what does a Vanadium(V) oxide catalyst catalyse in a reaction?
Making sulfuric acid