6 - Lasers Flashcards Preview

CHEM2302 - Molecular Spectroscopy > 6 - Lasers > Flashcards

Flashcards in 6 - Lasers Deck (22):

What properties do the stimulating and stimulated photons share?

Frequency/wavelength, direction of travel and phase.


What is population inversion?

The cascade movement of electrons from their excited state to the lower state resulting in the laser light emission.


What are the three components of a laser?

Active medium, Pump, Optical resonator.


What is an active medium?

A luminescent material which stores the excited population and can be stimulated to emit it in a cascade.


What is an pump?

The source of energy used to excite the molecules of the active medium.


What kinds of optical pump exist?

Optical pump - light such as a flash lamp that uses photon absorption to excite the active medium.

Electrical pump - energises the active medium through means such as electrical discharge.


What is an optical resonator?

The housing of the active medium which essentially comprises of two highly reflective mirrors at either end, one of which is partially non-reflecting.


Why must the length of the optical resonator/laser cavity be carefully controlled?

It must be an integer multiple of the wavelength to ensure that all waves stay in phase (coherence) so as not to cause destructive interference.


Which of the stimulated photons contribute to the lasing?

Those that propagate along the axis between the mirrors. Others are absorbed by the unmirrored surfaces.


What are the two kinds of laser?

3-level and 4-level.


Describe the sequence of events in a 3-level laser.

Optical pump irradiates the active medium with photons whose energy corresponds to an excitation to an unpopulated level.
Electrons partially relaxed non-radiatively to a slightly lower metastable state.
Spontaneous emission from the metastable state creates a cascade.


What is the main disadvantage of a 3-level laser?

The spontaneous and stimulated emission from the metastable state is to the ground state, hence the photons compete to be re-absorbed to re-populate the state. This makes them very inefficient.


What is the requirement for population inversion in a 3-level laser?

At least half the molecules in the active medium must be excited to the metastable state.


How do 4-level lasers solve the re-absorption competition problem?

The metastable state electron emits a photon to move down to an unstable state (second lasing level) that rapidly decays non-radiatively to the ground state, so the photons emitted are no longer the right energy for re-absorption.


Why is the metastable state stable?

Because the difference in energy between it and the first excited state mean that emission cannot be stimulated by the pumping.


What is different about the pumps that can be used in 4-level lasers?

They can be continuously pumped.


What are the advantages of 4-level lasers?

Much easier to achieve and maintain population inversion, less pumping required.
Laser can be operated continuously as continuous pumping is possible.
Conversion efficiencies much higher.


What is the advantage to using solute organic dyes as an active medium?

They possess many closely spaced vibrational energy levels in the lower lasing level, allowing the frequency to be very finely tuned using a diffraction grating.


What special requirements are there for organic dye active mediums?

Effective stirring and cooling, as the second non-radiative relaxation generally produces heat by collision with the solvent.


What range of frequencies are organic dye lasers largely limited to?

UV to IR


What are the basic properties of laser light?

Highly monochromatic (esp w/ diffraction grating).
Coherent (ie same phase).
Highly parallel, so can be focused on a small area to produce huge local power density.


What are pulsed lasers used for?

Ones such as ruby lasers are able to emit in 10^-15s pulses, allowing for femtosecond spectroscopy that can probe molecule's bond vibration.