Reactions Of Alkenes Flashcards

1
Q

Which are more reactive: alkenes or alkanes?

A

Alkenes

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2
Q

Why are alkenes more reactive than alkanes?

A

This is because they contain a Pi bond and therefore the electrons in the Pi bond are more exposed. The Pi bond therefore breaks easily.

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3
Q

Which is weaker the sigma bond or the Pi bond?

A

The Pi bond.

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4
Q

What type of reactions do alkenes undergo?

A

Addition reactions

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5
Q

Name four addition reactions of alkenes?

A

Hydrogen in the presence of a nickel catalyst
Halogens
Hydrogen halides
Steam in the presence of an acid catalyst

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6
Q

What is formed from a hydrogenation reaction?

A

An alkane

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7
Q

What is the alkene mixed with in a hydrogenation reaction?

A

Hydrogen

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8
Q

Where is the hydrogen atom added in hydrogenation?

A

Across a double bond.

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9
Q

At what temperature does hydrogenation occur?

A

432K

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10
Q

In what type of reaction are the reactants passed over a nickel catalyst?

A

Hydrogenation

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11
Q

How many bonds are hydrogenated in a hydrogenation reaction.

A

All of them so long as there is enough hydrogen molecules.

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12
Q

How many hydrogen atoms are added to the double bond during hydrogenation?

A

2 atoms are added (so 1 molecule)

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13
Q

What is the product of the halogenation of alkenes?

A

Haloalkane

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14
Q

At what temperature does halogenation take place?

A

Room temperature

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15
Q

What does bromine water test for?

A

Unsaturation

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16
Q

What will happen to the bromine water if added to an alkene?

A

It will become colourless.

17
Q

Why does the bromine water turn colourless if added to an alkene?

A

Bromine is added across the double bond.

18
Q

What colour is unreacted bromine water?

A

Orange

19
Q

What happens if bromine water is added to an alkane?

A

Nothing- no bromine is added to the compound and so the bromine water stays orange.

20
Q

How should bromine water be added to a solution?

A

Dropwise

21
Q

What is the product of a reaction involving an alkene and a gaseous hydrogen halide?

A

A haloalkane

22
Q

What happens in the reaction of alkenes and halogen halides if the alkene is a liquid?

A

The hydrogen halide is bubbled through it.

23
Q

What does two liquid hydrogen halides can be reacted with an alkene to form a haloalkane?

A

Concentrated hydrochloric acid
Concentrated hydrobromic acid
These are essentially solutions of the hydrogen halides in water.

24
Q

In the reaction of alkenes and hydrogen halides, what state is the hydrogen halide usually in?

A

Gaseous unless it is concentrated HCl or concentrated HBr.

25
Q

What is formed in a hydration reaction?

A

Alcohols

26
Q

What catalyst is used in hydration?

A

Phosporic acid

27
Q

What is the formula of phosphoric acid?

A

H3PO4

28
Q

What is the alkene reacted with in hydration reactions?

A

Steam

29
Q

Where is the steam added?

A

Across the double bond.

30
Q

What reaction is used widely in industry?

A

Hydration- ethanol is produced from ethane.

31
Q

How many possible products are there in hydration reactions and reactions involving hydrogen halides?

A

There are many possible reactions.