6.2.4 - 6.2.7 The effect of changing conditions on equilibrium Flashcards
(13 cards)
What does the relative amounts of all the reactants and products at equilibrium depend on?
The conditions of the reaction
If a system is at equilibrium and a change is made to any of the conditions, what does the system do?
Responds to counteract the change.
How can the effects of changing conditions on a system be predicted?
Using Le Chatelier’s Principle
What is Le Chatelier’s principle?
The idea that if you change the conditions of a reversible reaction at equilibrium, the system will try to counteract the change
What is Le Chatelier’s principle used for?
To predict the effect of any changes you make to a reaction system.
How does the system respond if concentration of reactants or products is changed?
The system will no longer be at equilibrium, so it responds to bring itself back to equilibrium again.
What happens if you increase the concentration of reactants?
The system tries to decrease it by making more products until equilibrium is reached again.
What happens if you decrease the concentration of products?
The system tries to increase it by reducing the amount of reactants until equilibrium is reached again.
What is the only type of equilibrium affected by changing pressure?
An equilibrium involving gases
What happens if you increase the pressure?
The equilibrium tries to reduce it - it moves towards the direction where there are fewer molecules of gas.
What happens if you decrease the pressure?
The equilibrium tries to increase it - it moves towards the direction where there are more molecules of gas.
What happens if you decrease the temperature?
The equilibrium will move in the exothermic direction to produce more heat, meaning you’ll get more products for the exothermic reaction and fewer for the endothermic reaction.
What happens if you increase the temperature?
The equilibrium will move in the endothermic direction to try and decrease it, meaning you’ll get more products for the endothermic reaction and fewer products for the exothermic reaction.