goodbye forever chemistry!!!!!!!!!!! Flashcards

(47 cards)

1
Q

Potable water what is it

A

safe to drink

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2
Q

3 conditions for potable water

A

-low levels of dissolved substances
-ph 6.5-8.5
-no microorganisms

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3
Q

where do you get potable warter - limitations of surface warer

A

-fresh water e.g. rain collects as surface (e.g. lake/river) /ground (e.g. aquifer) water
surface water benefit - easy access, replaced by rain
but can dry if hot and sunny
OR
-de salination

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4
Q

how is fresh water treated? 3 steps

A
  1. pass through wire mesh - filter big things out
  2. pass through bed of sand and gravel - filter smaller solids
  3. sterilise - kill harmful microbes
    -bubble chlorine gas
    -expose to ozone
    -expose to UV
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5
Q

Desalination problems

A

requires loads of energy and expensive

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6
Q

How is water desalinated by simple distillation?

A

water vapour collected and condensed

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7
Q

How is water desalinated by reverse osmosis?

A

passed through membrane - only allow water through
-ions and larger molecules trapped and separated

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8
Q

3 main sources of waste water

A
  1. domestic - household e.g. showers, sinks, toilets - sewers, sewage treatment plants
  2. Agriculture - nutrient run off - animal waste
  3. Industrial - factories that make and use chemicals
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9
Q

What must be done to waste water before disposal?

A

treatment to make it safe

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10
Q

How is domestic and agricultural waste water treated to make it safe

A

Remove any organic matter and harmful microbes which could pollute fresh water and make people ill.

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11
Q

How is industrial waste water treated to make it safe

A

Extra steps needed to remove harmful waste chemicals

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12
Q

How does sewage treatment work? - 3 general steps

A
  1. screening - pass through mesh, anything large filtered out
  2. let sewage sit in settlement tank - undergo sedimentation - heavy solids sink to form sludge, lighter effluent part left at top
    then separate into 2 tanks - sludge and effluent
  3. breakdown of organic matter - biological breakdown by microorganisms - effluent - aerobic - pump air in
    sludge - anaerobic - tank sealed
    so microbes break down organic matter in effluent tank by aerobic digestion but organic matter in sludge - anaerobic
    eventually, effluent water is safe and can be released back into the envuironment.
    sludge - anaerobic produces methane - captured and burned as energy source. remaining digested waste used as fertiliser as its rich in nutrients
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13
Q

What additional stages remove toxic substances

A
  • adding chemicals
  • UV radiation
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14
Q

Why do some countries rely on waste water for their drinking supplies?

A

Much cheaper than desalination

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15
Q

What is haber process

A

industrial preoduction of ammonia from nitrogen and hydrogen

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16
Q

what is the ammonia from haber process used for?

A

nitrogen based fertilisers - allow us to grow enough food.

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17
Q

How we aquire nitrogen and hydrogwen for haber process

A

nitrogen - in air
hydrogen - make it from hydrocarbons

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18
Q

Is the haber process reaction exothermic, reversible or both?

A

both

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19
Q

How does the Haber Process work?

A
  • nitrogen and hydrogen fed into top left of machine, where they mix
  • in the reaction vessel, conditions are kept at 450 degrees C and 200 atmoapheres pressure
  • gases free to pass over iron catalyst
  • under the conditions in the reaction vessel, some of the nitrogen and hydrogen will react to form ammonia but as the reaction is reversible, there will still be nitrogen and hydrogen too.
  • to separate ammonia, pass entire mixture through pipe into condenser (much cooler)
  • ammonia has a low b.p.t so condenses whilst hydrogen and nitrogen stay gaseous and are recycled back to the reactant mixture
20
Q

Why 450 deg and 200 atm for haber

A

temp:
exothermic so need low temp to favour forward for high percentage yield.
but need high temp for higher rate of reaction as particles need enough kinetic energy to react
450 deg is a compromise
higher temp also too costly

pressure - high pressure for high percentage yield as fewer molecules of gaseous product than reactant and high pressure shifts equilibrium to the left.
high pressure - more frequent collisions so higher rate of reaction
so oly thing limiting how hogh pressure is are cost and safety
maintaining high pressure is expensive and dangerous if something goes wrong
200 atm is a compromise - best overall

21
Q

what is a fertiliser?

A

a substance that is applied to soil, in order to supply plants with nutrients.

22
Q

How are fertilisers made - past, now

A

In the past, fertilisers were usually made from animal waste such as cow manure. Now though, we tend to use formulated fertilisers, which are made in factories.

23
Q

what is a formulated fertiliser

A

A formulation is a mixture that has been designed as a useful product. So if we make fertilisers by combining certain chemicals in a specific ratio, then we would call it a formulated fertiliser.

24
Q

3 key parts of formulated fertilisers

A

The three main elements that plants needs from the soil are are nitrogen (N), phosphorus (P), and potassium (K). For this reason, fertilisers normally consist mainly of nitrogen, phosphorus, and potassium compounds.

This is why we sometimes call them NPK fertilisers. NPK fertilisers are formulations of various salts containing appropriate percentages of these three elements.

25
Producing nitrogen for NPK fertilisers
- Nitrogen is important to plants as it is required to make amino acids and hence proteins, which are essential for growth. - The main source of nitrogen in fertilisers is ammonia, which remember is made in the Haber process. - You need to know how ammonia can be used to make nitric acid and ammonium salts: 1. Ammonia can react with oxygen and water in a series of reactions to make nitric acid. 2. Ammonia can also react with acids (including nitric acid) to form ammonium salts. - How scientists carry out these reactions is different depending on whether they're done in industry or in a lab. You may be asked to compare these in an exam, but you will be given the information required.
26
Producing phosphorus for NPK fertilisers
- Phosphate can be mined from the ground as phosphate rock. - However, because the phosphate salts in the rock are insoluble, plants can’t use them as nutrients, and so they can't be used directly in fertilisers. - Instead, we have to react the phosphate rocks with acids to produce soluble salts: 1. Reaction with nitric acid produces phosphoric acid and calcium nitrate. 2. Reaction with sulfuric acid produces calcium sulfate and calcium phosphate (this mixture is known as single superphosphate). .3 Reaction with phosphoric acid only produces calcium phosphate (also called triple superphosphate).
27
Producing potassium for use in NPK fertilisers
Potassium chloride and potassium sulphate can be both be mined from the ground and then used directly in fertilisers.
28
what is a hydrocarbon
compound containing only carbon and hydrogen atoms
29
1st 4 alkanes
methane - CH4 ethane - C2H6 propane C3H8 butane - C4H8
30
group of organic compounds e.g. alkanes is called a
homologous series - similar properties - react in a similar way
31
general formula for alkanes
CnH2n+2
32
what does saturated mean
all single bonds
33
are all alkanes saturated?
yes
34
What is an isomer?
molecules that have the same molecular formula, but different structural formulas, this means they are made of the same atoms, but the atoms are arranged differently.
35
Properties and trends of alkanes- 4
- as length of carbon chain increases, so does boiling point (1st 4 are gases at room temp) - shorter alkanes are more volatile( evaporate more easily due to low b.p.t) - longer alkane - more viscous (thick and sticky) - shorter alkanes are more flammable - easier to ignite
36
combustion of alkanes
A main use of hydrocarbons is fuel sa they release loads of energy when burned with oxygen If enough oxygen available - complete combustion: hydrocarbon + oxygen = carbon dioxide + water exothermic - releases loads of energy. hydrogen and carbon being oxidised
37
crude oil is a mixture of ........
hydrocarbons
38
crude oil is formed from the remains of.........
dead plants and animals, esp. plankton which were buried millions of years ago in the mud. High temps and pressures turned organic biomass to crude oil which soked into rock - can extract through drilling.
39
is crude oil finite
yeah. yeah it is.
40
what kind of reaction is cracking
thermal decomposition
41
catalytic cracking
heat long chain hydrocarbons and vaporise them - hot, powdered aluminium oxide catalyst. - pass hydrocarbon vapour over powder - as long chain hydrocarbons come into contact with catalyst, split into 2 smaller hydrocarbons
42
steam cracking
heat long chain hydrocarbons and vaporise them - mix them with steam - heat them to very high temp so long chain splits into shorter ones
43
products of cracking
shorter alkane and an alkene
44
alkene general formula
CnH2n
45
are alkenes saturated?
No, they have a double bond so are unsaturated
46
alkene properties compared to alkanes
more reactive so can react with bromine If you add bromine water to a solution of alkenes, they'll decolourise the bromine water from orange to colourless can also be added together to form polymers as the double bond can break to form 2 bonds so can bond with adjacent molecules
47
test for alkenes
If you add bromine water to a solution of alkenes, they'll decolourise the bromine water from orange to colourless