6.4 Flashcards

(48 cards)

1
Q

What are two other words for the electrochemical cell

A

voltaic cell or galvanic cell

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2
Q

What is an electrochemical cell

A

A portable source of electricity produced by a redox reaction

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3
Q

What is the role of the salt bridge

A

make both beaker’s contents neutral to prevent electron flow to go backwards.

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4
Q

Oxidation occurs at the _____

A

anode

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5
Q

Reduction occurs at the _______

A

cathode

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6
Q

Mass of solid on the anode side will _____ as time passes

A

diminishes

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7
Q

What is a salt bridge

A

Porous barrier allowing for ion migration to counterbalance the charge of each solution.

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8
Q

What would happen with no salt bridge to counter-charge the solutions

A

a charge build-up would occur, the reduction half-cell would become negative and the oxidation half-cell would become positive. Electron flow would stop.

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9
Q

In the salt bridge, anions migrate towards the:

A

anode

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10
Q

In the salt bridge, cations migrate towards the:

A

cathode

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11
Q

When is an inverted tube used in the electrode

A

when the anode or cathode is not a solid, so you can pump gas or liquid into the solution.

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12
Q

How do you calculate the overall voltage of the cell

A

Add the half-cell potential for the reduction reaction to the inverse of the half-cell potential of the oxidation reaction

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13
Q

The combined voltage will always be ____

A

positive

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14
Q

What should you never do to the values of the reduction table

A

multiply them by any coefficient

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15
Q

What is the voltage when equilibrium is reached

A

0.00 V

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16
Q

in an electrochemical cell, the cathode is the site of

A

reduction

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17
Q

in an electrochemical cell, the anode is the site of

A

oxidation

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18
Q

electrons flow from _____ to _____

A

anode to cathode

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19
Q

In a salt bridge, anions flow to the

A

anode

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20
Q

in a salt bridge, cations flow to the

21
Q

How do you calculate the overall voltage of a cell

A

add the reduction voltage to the reverse of the oxidation voltage to determine the overal

22
Q

What is the most common inert

A

Pt (platinum)

23
Q

Which substances can’t act as electrodes?

A

a gas, liquid Hg, Group 1 or 2 metal

24
Q

in an electrochemical cell, the cathode is the site of

25
in an electrochemical cell, the anode is the site of
oxidation
26
electrons flow from _____ to _____
anode to cathode
27
In a salt bridge, anions flow to the
anode
28
in a salt bridge, cations flow to the
cathode
29
How do you calculate the overall voltage of a cell
add the reduction voltage to the reverse of the oxidation voltage to determine the overal
30
What is the most common inert
Pt (platinum)
31
Which substances can't act as electrodes?
a gas, liquid Hg, Group 1 or 2 metal
32
What can be used in place of a salt bridge
a porous disk
33
What do you call the oxidation of metals
corrosion
34
What happens when a metal is oxidized?
a metal atom loses electrons to become a metal cation
35
what do you call the corrosion of iron (Fe)
rust
36
What two species are required to corrode a metal
oxygen and water
37
What are the two regions of a water droplet
anode region (bottom) and cathode region (top)
38
During corrosion, the metal cations move where
to the cathode portion of the water droplet
39
What reaction takes place on the outer surface of the droplet
the reduction of oxygen
40
What is the equation for the reduction of oxygen
1/2O2 (g) + H20 + 2e- => 2OH-
41
Once migrated to the outer part of the drop, the metal cation joins with what?
joins with OH- from the reduction equation
42
What are the three methods of corrosion prevention
1. Isolation of metal 2. Electrochemical principles (cathodic protection) 3. lowering [H+]
43
How does the isolation of metal work
By not allowing the metal to come into contact with water and oxygen
44
What are some examples of the isolation of metal
A protective layer of paint or plastic, or attaching a tin layer to oxidize into a protective coating.
45
How does cathodic protection work
A substance is protected from oxidation by being connected to a substance with a greater tendency to oxidize.
46
What is the sacrificial anode
the metal with a greater tendency to oxidize used to prevent corrosion of a different metal.
47
What is an example of a sacrificial anode
zinc
48
Why does lowering the [H+] prevent corrosion
Because if the solution is basic it will favour the reduction of water (less water).